Nano-antenna Analyte Detector with Resonance Peaks

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Solution Overview

Problem

Existing analyte detectors face limitations in distinguishing different analytes, enhancing sensitivity, and reducing the limit of detection, as they often rely on localized hot-spots of plasmonic nanoantennas which are not sufficient for comprehensive detection.

Innovation Solution

The use of nano-antennas with varying sizes, orientations, shapes, and materials to create resonant structures that interact with source light across specific wavelength ranges, enhancing the local field concentration and analyte concentration, allowing for extended spectral signature detection through overlapping resonance peaks.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional SEIRA sensing with localized hot-spots of plasmonic nanoantennas is used, then the device structure is simple, but the sensitivity and detection capability are insufficient

Engineering Contradiction:
Improvedetection capabilityVSAvoiddevice structure
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The device segments the detection function by using multiple types of nanoantennas (gold, silver, aluminum) with different resonant frequencies to detect different analytes simultaneously. Each nanoantenna type is optimized for specific wavelength ranges, dividing the broad spectral detection task into specialized segments that collectively enhance overall detection capability

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The device employs composite material structures combining different metallic nanoantennas (gold, silver, aluminum) with distinct plasmonic properties. This composite approach enables the system to leverage the unique resonant characteristics of each material to detect various analytes across different spectral ranges, thereby improving measurement precision without requiring a single complex antenna design

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If a single type of nanoantenna is used, then the device complexity is low, but the wavelength range coverage is limited

Engineering Contradiction:
Improvewavelength range coverageVSAvoidnumber of antenna types
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The device achieves multi-functionality by integrating multiple nanoantenna types (gold, silver, aluminum) that can detect different analytes across various wavelength ranges simultaneously. This universal design allows a single detector to perform multiple detection functions without requiring separate devices for each analyte type

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The device utilizes parameter changes in nanoantenna material composition (gold, silver, aluminum) to shift resonant frequencies and extend wavelength range coverage. By varying the material parameter, the system adapts to detect different spectral signatures of various analytes, thereby enhancing versatility

Inventive Principle:
Principle #35Parameter changes

3Measurement precision

If localized hot-spots are used for detection, then the field concentration is high, but the analyte concentration enhancement is insufficient

Engineering Contradiction:
ImprovesensitivityVSAvoidanalyte concentration
Core Design Contradiction:
Measurement precisionVSQuantity of substance

Solution Approach 1:

The device merges two enhancement mechanisms: optical field enhancement from plasmonic nanoantennas and analyte concentration enhancement from MOF adsorption. This combination creates a synergistic effect where both the light field and analyte concentration are simultaneously enhanced at the same location, dramatically improving detection sensitivity

Inventive Principle:
Principle #5Merging (Combining)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables improved sensitivity and detection capabilities by enhancing the interaction of source light with analytes, allowing for the identification of analytes in mixtures through extended spectral signature analysis.

Implementation Method 1

The nano-antennas comprise an antenna material forming resonant antenna structures configured to receive and resonantly interact with the source light to form a respective resonance peak

Methodology Applied
Scientific EffectPlasmonic resonance: Resonance

Implementation Method 2

The target location is provided with a sorption material for absorbing or adsorbing the target analyte to provide a locally increased analyte concentration

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Data Source

PatentUS11808698B2Analyte detector with nano-antennas
Publication Date: 2023.11.07 NEDERLANDSE ORG VOOR TOEGEPAST NATUURWETENSCHAPPELIJK ONDERZOEK TNO
  • US11808698B2 patent drawing
  • US11808698B2 patent drawing
  • US11808698B2 patent drawing

AI summary

A device for the detection of analytes comprises a substrate (10) with nano-antennas (11,12). The nano-antennas (11,12) comprise an antenna material (11m, 12m) for forming resonant antenna structures which receive and resonantly interact with source light (L0) to form respective resonance peaks (R1,R2) over a resonant wavelength range (A1,A2) overlapping respective signature wavelength (λ1,λ2) of a target analyte (A). The resonant interaction causes a locally concentrated field (Ec) of the source light (L0) in the resonant wavelength range (Λ1,Λ2). The concentrated intensity (Ic) is localized around a respective target location (T1,T2) which is provided with a sorption material (11s, 12s) that sorbs the target analyte (A). This provides a locally increased analyte concentration (Ac) of the target analyte (A) coinciding with the locally concentrated field (Ec) of the source light (L0). Accordingly, the interaction of the source light (L0) with the target analyte (A) is enhanced.