Nano Composite Coating Shell-Simulated Multi-Arch Structure

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Solution Overview

Problem

Current bionic structure coatings for mechanical parts lack ideal performance in terms of hardness, strength, toughness, corrosion resistance, and abrasion resistance, particularly in harsh environments such as those encountered in new energy, aerospace, and marine applications, where high temperature and corrosion resistance are critical.

Innovation Solution

A nano composite coating with a shell-simulated multi-arch structure is developed, comprising a discontinuous metal seed layer and a continuous multi-arch structure layer, where arched hard nano ceramic and soft metal phase layers are alternately deposited on metal island-shaped seeds, using physical vapor deposition technology to achieve high hardness, strength, and corrosion resistance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If a bionic structure coating is applied to mechanical parts, then the coating can provide multi-functional performance, but the preparation is challenging and performances are not ideal under current environmental conditions

Engineering Contradiction:
Improvecoating performanceVSAvoidpreparation difficulty
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The coating is divided into discrete arched structure units deposited on metal island-shaped seeds, creating a segmented multi-arch structure that simulates natural nacre. This segmentation allows independent control of each unit's composition and structure, simplifying the preparation process while maintaining multi-functional performance.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The coating combines hard nano ceramic phases and soft metal phases in an alternating layered structure within each arched unit. This composite material approach enables simultaneous achievement of hardness, strength, toughness, and corrosion resistance, resolving the contradiction between performance and manufacturability.

Inventive Principle:
Principle #40Composite materials

2Strength

If hard nano ceramic phase layers are deposited to increase hardness, then abrasion resistance improves, but the coating becomes more brittle and toughness decreases

Engineering Contradiction:
ImprovehardnessVSAvoidtoughness
Core Design Contradiction:
StrengthVSStability of the object's composition

Solution Approach 1:

Within each arched structure unit, hard nano ceramic phases and soft metal phases are alternately deposited in specific layers. The soft metal phases are strategically positioned to provide toughness and ductility, while hard ceramic phases provide hardness and abrasion resistance. This local quality differentiation resolves the contradiction between hardness and toughness.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The alternating layered structure of hard ceramic and soft metal phases creates a composite material system where the soft phases act as toughening agents within the hard ceramic matrix. This composite structure enables the coating to simultaneously achieve high hardness and high toughness, preventing brittleness.

Inventive Principle:
Principle #40Composite materials

3Reliability

If soft metal phase is evenly layered to improve corrosion resistance, then corrosion protection increases, but the coating structure becomes simpler and mechanical strength decreases

Engineering Contradiction:
Improvecorrosion resistanceVSAvoidmechanical strength
Core Design Contradiction:
ReliabilityVSStrength

Solution Approach 1:

The coating uses a composite structure where soft metal phases are evenly layered with hard nano ceramic phases in alternating layers within each arched unit. This composite arrangement provides corrosion resistance through the soft metal layers while maintaining mechanical strength through the hard ceramic layers, resolving the contradiction between corrosion protection and mechanical strength.

Inventive Principle:
Principle #40Composite materials

4Reliability

If multi-arch structure layer is deposited on metal seed layer, then coating performance improves, but the deposition process becomes more complex and time-consuming

Engineering Contradiction:
Improvecoating performanceVSAvoiddeposition time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

Metal island-shaped seeds are first deposited on the substrate to serve as templates for the subsequent arched structure units. This preliminary action establishes the foundation for the multi-arch structure, enabling efficient sequential deposition of hard ceramic and soft metal phases without requiring complex real-time adjustments, thus reducing overall deposition time.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The nano composite coating exhibits enhanced breaking strength, high temperature resistance, low friction coefficient, and excellent corrosion and abrasion resistance in seawater, with potential for improved breakage and heat resistance, while being simple, controllable, and cost-effective for large-scale production.

Implementation Method 1

using physical vapor deposition technology to achieve high hardness, strength, and corrosion resistance

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS11795538B2Nano composite coating having shell-simulated multi-arch structure as well as preparation method and application thereof
Publication Date: 2023.10.24 NINGBO INST OF MATERIALS TECH & ENG CHINESE ACAD OF SCI
  • US11795538B2 patent drawing
  • US11795538B2 patent drawing
  • US11795538B2 patent drawing

AI summary

The preparation method for a nano composite coating having a shell-simulated multi-arch structure includes: constructing a discontinuous metal seed layer using a vacuum plating technology; and inducing the deposition of a continuous multi-arch structure layer utilizing the discontinuous metal seed layer, thereby realizing the controllable orientated growth of the nano composite coating having the shell-simulated multi-arch structure. The nano composite coating having the shell-simulated multi-arch structure is of a red abalone shell-simulated nacreous layer aragonite structure, meanwhile has high hardness and high temperature resistance, has excellent performances such as high breaking strength, low friction coefficient and corrosion and abrasion resistance in seawater under the condition of maintaining good breaking tenacity, is simple and controllable in preparation process and low in cost, has unlimited workpiece shapes, is easily produced on large scale, and has huge potential in the fields of new energy, efficiency power, ocean engineering, nuclear energy, and micro-electronic/optoelectronic devices.