Nano-FET Gate Stack Structure for Fluorine-Stable Threshold Voltage

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Solution Overview

Problem

As semiconductor devices continue to shrink in size, issues arise from uneven fluorine distribution in the work function metal layers of transistor gate stacks, leading to instability in threshold voltage (Vt) and reduced performance in nano-FETs.

Innovation Solution

Incorporating a barrier layer between the fill metal and underlying work function metal layers during deposition to prevent fluorine diffusion, using fluorine-free precursors, thereby maintaining uniform fluorine distribution and improving Vt stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If minimum feature size is reduced to improve integration density, then more components can be integrated into a given area, but uneven fluorine distribution in work function metal layers occurs leading to threshold voltage instability

Engineering Contradiction:
Improveintegration densityVSAvoidthreshold voltage stability
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

A barrier layer is introduced as an intermediary between the fill metal and the work function metal layers. This barrier layer prevents fluorine diffusion from the fill metal into the work function metal, thereby maintaining uniform fluorine distribution and ensuring threshold voltage stability even as feature sizes are reduced to improve integration density.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Area of stationary object

If feature size is reduced to improve integration density, then manufacturing area is optimized, but fluorine diffusion becomes more problematic causing performance degradation

Engineering Contradiction:
Improvemanufacturing areaVSAvoidfluorine diffusion
Core Design Contradiction:
Area of stationary objectVSObject-generated harmful factors

Solution Approach 1:

The barrier layer serves as a mediator that blocks fluorine diffusion pathways. By placing this intermediate layer between the fill metal and work function metal, the harmful fluorine diffusion is prevented while maintaining the reduced feature size geometry needed for high integration density.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Ease of manufacture

If conventional deposition is used to fill gate structures, then manufacturing process is simple, but fluorine contamination occurs in work function metal layers

Engineering Contradiction:
Improvedeposition process simplicityVSAvoidfluorine distribution uniformity
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The gate structure is segmented into distinct layers with the barrier layer positioned between the fill metal and work function metal. This segmentation allows the fill metal to be deposited using conventional simple processes while the barrier layer prevents fluorine contamination of the work function metal, thereby maintaining both manufacturing simplicity and fluorine distribution uniformity.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

Enhances Vt stability and control in nano-FETs by preventing uneven fluorine distribution, ensuring consistent performance and reliability in smaller feature sizes.

Implementation Method 1

Incorporating a barrier layer between the fill metal and underlying work function metal layers during deposition to prevent fluorine diffusion

Methodology Applied
Scientific EffectDiffusion barrier: Diffusion Barrier

Implementation Method 2

semiconductor devices are typically fabricated by sequentially depositing insulating or dielectric layers, conductive layers, and semiconductor layers of material

Methodology Applied
Scientific EffectPhysical vapor deposition: Physical Vapour Deposition

Data Source

PatentUS12417920B2Transistor gate structure and method of forming
Publication Date: 2025.09.16 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US12417920B2 patent drawing
  • US12417920B2 patent drawing
  • US12417920B2 patent drawing

AI summary

A device includes a first nanostructure; a second nanostructure over the first nanostructure; a high-k gate dielectric around the first nanostructure and the second nanostructure, the high-k gate dielectric having a first portion on a top surface of the first nanostructure and a second portion on a bottom surface of the second nanostructure; and a gate electrode over the high-k gate dielectric. The gate electrode comprises: a first work function metal around the first nanostructure and the second nanostructure, the first work function metal filling a region between the first portion of the high-k gate dielectric and the second portion of the high-k gate dielectric; and a tungsten layer over the first work function metal, the tungsten layer being free of fluorine.