Segmented Nano-Graphene Plugging Drilling Fluid for Borehole Stability

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Solution Overview

Problem

The existing drilling fluids face challenges in stabilizing boreholes during shale gas drilling due to well collapse and poor plugging efficiency in micrometer/nanometer cracks, with water-based fluids lacking sufficient plugging capacity and oil-based fluids causing contamination issues.

Innovation Solution

A strong plugging drilling fluid composition comprising water, bentonite, Na2CO3, a shale inhibitor, a filtrate reducer, an anti-collapse agent, a nanometer plugging agent, a lubricant, and a weighting agent, including modified asphalt, ultra-fine calcium carbonate, and polyethylene glycol surface-modified nano-graphene, which forms a dense blocking barrier to prevent pressure transmission and maintain well stability.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If water-based drilling fluid is used, then contamination is reduced, but plugging capacity in micrometer/nanometer cracks is insufficient

Engineering Contradiction:
ImprovecontaminationVSAvoidplugging capacity
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The plugging system is segmented into three distinct components with different particle sizes: coarse plugging agent (0.1-1mm), fine plugging agent (1-10μm), and nanometer plugging agent (10-100nm). This segmentation allows each component to target specific crack sizes, with the nanometer agent specifically addressing micrometer/nanometer cracks while the larger agents handle larger fractures, achieving comprehensive plugging capacity without contamination

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The drilling fluid employs a composite plugging system combining three types of plugging agents with different particle size distributions. This composite approach integrates the advantages of each material type: coarse agents for structural support and large crack plugging, fine agents for intermediate cracks, and nanometer agents for micrometer/nanometer cracks, achieving superior overall plugging capacity while maintaining water-based fluid benefits

Inventive Principle:
Principle #40Composite materials

2Ease of manufacture

If existing plugging materials are used, then application is simple, but particle size is too large to enter micrometer/nanometer cracks

Engineering Contradiction:
Improveapplication simplicityVSAvoidparticle size control
Core Design Contradiction:
Ease of manufactureVSManufacturing precision

Solution Approach 1:

The invention fundamentally changes the particle size parameter of plugging agents by introducing a nanometer-scale component (10-100nm) alongside fine (1-10μm) and coarse (0.1-1mm) agents. This parameter change enables the plugging materials to physically enter and fill micrometer/nanometer cracks that were previously inaccessible to conventional larger particles, while maintaining the simplicity of direct drilling fluid application

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If conventional plugging materials are used, then cost is low, but they agglomerate and increase particle size

Engineering Contradiction:
Improvematerial costVSAvoidparticle size stability
Core Design Contradiction:
Quantity of substanceVSStability of the object's composition

Solution Approach 1:

The invention introduces surface modification technology as an intermediary process, applying hydrophilic surface treatment to the nanometer plugging agent. This surface modification acts as a mediator that prevents direct agglomeration between nanometer particles and with other plugging agents, maintaining stable particle size distribution and preventing the cost-effective materials from deteriorating through agglomeration

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively blocks micrometer/nanometer cracks, reduces hydraulic fracture effects, prevents blockage collapse, and maintains well stability by forming a long-lasting, dense sealing barrier, enhancing drilling fluid performance and reducing contamination risks.

Implementation Method 1

polyethylene glycol surface-modified nano-graphene

Methodology Applied
Scientific EffectSurface modification:

Implementation Method 2

nanometer plugging agent is polyethylene glycol surface-modified nano-graphene

Methodology Applied
Scientific EffectNanoparticle plugging: Nanoporous Material

Implementation Method 3

The different anti-collapse agents and treatment agents can form a 'force chain network' at the micro-scale contact interface through reasonable compounding and particle diameter grading

Methodology Applied
Scientific EffectParticle bridging:

Implementation Method 4

form a long-lasting and dense blocking barrier at the adjacent borehole wall

Methodology Applied
Scientific EffectParticle packing: Close Packing

Data Source

PatentUS10533122B1Strong plugging drilling fluid composition and preparation method thereof, and use thereof
Publication Date: 2020.01.14 SOUTHWEST PETROLEUM UNIV

AI summary

The invention relates to the field of drilling fluid, and discloses a strong plugging drilling fluid composition and preparation method thereof, and use thereof. The strong plugging drilling fluid composition comprises water, bentonite, Na2CO3, a shale inhibitor, a filtrate reducer, a viscosity reducer, an anti-collapse agent, a nanometer plugging agent, a lubricant and a weighting agent. The shale inhibitor is modified asphalt, the anti-collapse agent is ultra-fine calcium carbonate, and the nanometer plugging agent is polyethylene glycol surface-modified nano-graphene.