Nano-Metal Binding Monomer for Conductive Polymer Composites

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Solution Overview

Problem

Conductive polymers face challenges in achieving high electrical conductivity while maintaining solubility and light transmittance, often sacrificing one property for the other.

Innovation Solution

A monomer for binding nano-metal, represented by Formula 1, is used to create a conductive polymer composite by attaching the monomer to a nano-metal rod and conjugated conductive polymer monomers, followed by polymerization with a dopant, resulting in a material with high conductivity, flexibility, and transparency.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conductive polymers are doped to increase electrical conductivity, then electrical conductivity is improved, but solubility and light transmittance deteriorate

Engineering Contradiction:
Improveelectrical conductivityVSAvoidsolubility
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent combines conductive polymer particles with insulating polymer matrix to create a composite material. The insulating polymer compensates for the loss of solubility caused by doping, while the conductive polymer provides electrical conductivity. This composite structure allows the material to maintain both electrical functionality and processability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical structure of conductive polymers by introducing soluble side chains or modifying the polymer backbone. This parameter change allows the doped conductive polymer to maintain solubility in common solvents while retaining its electrical conductivity properties, resolving the contradiction between conductivity enhancement and solubility maintenance.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If conductive polymers are doped to increase electrical conductivity, then electrical conductivity is improved, but light transmittance deteriorates

Engineering Contradiction:
Improveelectrical conductivityVSAvoidlight transmittance
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent uses transparent conducting oxides (TCO) such as ITO or IZO as the conductive component. These materials have localized conductivity properties that allow electrons to move freely in certain directions while maintaining optical transparency in the visible range. This local quality differentiation enables simultaneous achievement of high electrical conductivity and light transmittance.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the optical parameters of the conductive material by selecting TCOs with specific band gap energies that are larger than the visible light range. This parameter change allows the material to be electrically conductive while remaining optically transparent, resolving the contradiction between conductivity and light transmittance.

Inventive Principle:
Principle #35Parameter changes

3Strength

If conventional conductive polymers are used, then flexibility is maintained, but electrical conductivity is insufficient

Engineering Contradiction:
Improveelectrical conductivityVSAvoidflexibility
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent creates a composite where conductive polymer particles are dispersed in a flexible insulating polymer matrix. This structure combines the high electrical conductivity of the conductive polymer with the mechanical flexibility and processability of the insulating polymer, allowing the material to be bent and shaped while maintaining electrical functionality.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The conductive polymer composite exhibits significantly higher electrical conductivity than typical conductive polymers, maintains transparency, and allows for flexible device applications, including use in displays and electrodes, with minimized contact resistance and preserved light transmittance.

Implementation Method 1

binding the monomer for binding nano-metal to the surface of a nano-metal rod, thus forming a nano-metal-bound monomer

Methodology Applied
Scientific EffectChemical bonding: Chemical Bonding

Implementation Method 2

subjecting the mixture to heating and polymerization

Methodology Applied
Scientific EffectPolymerization: Photopolymerisation

Data Source

PatentUS9099221B2Monomer for binding nano-metal, conductive polymer composite and method of preparing the conductive polymer composite
Publication Date: 2015.08.04 SAMSUNG ELECTRONICS CO LTD
  • US9099221B2 patent drawing
  • US9099221B2 patent drawing
  • US9099221B2 patent drawing

AI summary

A monomer for binding nano-metal, which is useful for the preparation of a conductor having increased conductivity with ensuring flexibility and transparency. Polymerization of the monomer for binding nano-metal provides a conductive polymer composite including a nano-metal rod. A method of preparing the conductive polymer composite is also provided.