Nano-Modified Alkali-Activated Cement for Rapid Infrastructure Repair

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Solution Overview

Problem

Current rapid repair materials for cement-based infrastructure face challenges such as short setting times, health and environmental hazards from liquid alkali activators, and temperature-dependent strength development, necessitating a dry-mix, nano-modified alkali-activated cement with improved workability and durability.

Innovation Solution

A nano-modified dry-mixed alkali-activated cementitious material comprising an aluminosilicate rich material, a solid alkali activator, and nano-modifiers like nano-silica, which can be mixed with water on-site to achieve high early strength and enhanced durability, reducing occupational hazards and transportation costs.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If liquid alkali activators are used in alkali-activated cement, then high early strength and quick-setting properties are achieved, but occupational safety hazards and environmental concerns increase due to chemical burns and VOC emissions

Engineering Contradiction:
Improveearly strengthVSAvoidoccupational safety hazards
Core Design Contradiction:
StrengthVSObject-affected harmful factors

Solution Approach 1:

The patent transforms the alkali activator from liquid form to solid powder form, fundamentally changing the physical state parameter. This eliminates the chemical burn hazards and VOC emissions associated with liquid alkali while preserving the alkali-activated cement's high early strength and quick-setting properties through the solid-liquid reaction mechanism upon water addition

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent converts the potentially harmful liquid alkali into a safe solid powder form that can be stored and transported without safety hazards. The solid alkali activator maintains its chemical reactivity to produce high early strength when activated, effectively turning a harmful substance into a safe material that retains its beneficial properties

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Strength

If liquid alkali activators are used, then chemical reaction and strength development are enhanced, but material storage convenience and transportation cost increase due to leakage risks and handling requirements

Engineering Contradiction:
Improvestrength developmentVSAvoidstorage convenience
Core Design Contradiction:
StrengthVSEase of operation

Solution Approach 1:

The patent changes the physical state of the alkali activator from liquid to solid powder, which fundamentally improves storage and transportation characteristics. Solid powder form eliminates leakage risks, reduces handling complexity, and enables standard packaging while maintaining the chemical reactivity needed for strength development

Inventive Principle:
Principle #35Parameter changes

3Strength

If ordinary Portland cement is used for rapid repair, then early strength can be achieved within 24 hours, but strength development rate decreases significantly as temperature falls

Engineering Contradiction:
Improveearly strengthVSAvoidtemperature dependence
Core Design Contradiction:
StrengthVSAdaptability or versatility

Solution Approach 1:

The patent creates a composite material system combining solid alkali activator with aluminosilicate-rich materials to form alkali-activated cement. This composite system produces high early strength through alkali activation that is less sensitive to temperature variations compared to ordinary Portland cement, improving adaptability across different environmental conditions

Inventive Principle:
Principle #40Composite materials

4Ease of operation

If dry-mix alkali-activated cement is formulated, then occupational hazards and transportation costs are reduced, but nano-modification is needed to enhance strength development and workability

Engineering Contradiction:
Improvestorage convenienceVSAvoidstrength development rate
Core Design Contradiction:
Ease of operationVSStrength

Solution Approach 1:

The patent incorporates nano-modifiers into the dry-mix alkali-activated cement formulation, creating a multi-component composite material. The nano-modifiers work synergistically with the solid alkali activator and aluminosilicate-rich materials to enhance early strength development rate and improve workability while maintaining the storage and handling advantages of dry-mix formulation

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The material achieves a 1-day compressive strength of at least 14 MPa, with significant strength enhancement and improved workability, making it suitable for rapid repair of infrastructure components while being environmentally friendly and cost-effective.

Implementation Method 1

gains strength and other mechanical properties via chemical reaction between a source of alkali (soluble base activator) and calcium and/or aluminate rich materials

Methodology Applied
Scientific EffectAlkali activation: Chemical Bonding

Implementation Method 2

Nano-modification or nano-engineering of the rapid repair material encompasses the techniques of manipulation of the material structure at the nanometer scale

Methodology Applied
Scientific EffectNano-modification: Nanocomposite

Data Source

PatentUS9802865B1Nano-modified alkali-activated cementitious materials for rapid repair
Publication Date: 2017.10.31 HONG KONG APPLIED SCI & TECH RES INST
  • US9802865B1 patent drawing

AI summary

A nano-modified dry-mixed alkali-activated cementitious, or one-part geopolymer cement (OPgC), material with high early strength is provided for rapid repair of cement-based infrastructure components. The OPgC may include an aluminosilicate rich material, an alkali material and a nano-modifier, and optionally include other functional admixtures and fibers. The OPgC can be freshly mixed with water to obtain a repairing material. The OPgC may mix with water and fine or coarse aggregate to form mortar or concrete. The OPgC can be an alternative binding matrix for the development of an environmentally friendly and cost effective rapid repair material.