Nanocarbon Dispersion Liquid Storage Stability

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Solution Overview

Problem

Nanocarbon dispersion liquids, particularly those containing single-walled carbon nanotubes, suffer from aggregation and turbidity issues when stored at room temperature, leading to nonuniformity and performance deterioration due to the interaction between nanocarbon materials and surfactants.

Innovation Solution

A method involving low-temperature storage at 10° C. or lower and surfactant concentration adjustment to be less than 100 times the critical micelle concentration, ensuring stability and preventing turbidity formation in nanocarbon dispersion liquids.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If nanocarbon dispersion liquid is stored at room temperature, then storage convenience is improved, but aggregation and turbidity occur leading to nonuniformity

Engineering Contradiction:
Improvestorage convenienceVSAvoiddispersion uniformity
Core Design Contradiction:
Ease of operationVSStability of the object's composition

Solution Approach 1:

The patent changes the temperature parameter from room temperature to low temperature (10°C or lower) to prevent aggregation while maintaining dispersion uniformity. This parameter change resolves the contradiction by enabling stable storage without sacrificing too much convenience, as the low temperature storage can be implemented in standard refrigerators.

Inventive Principle:
Principle #35Parameter changes

2Duration of action of stationary object

If nanocarbon dispersion liquid is stored at room temperature for long time, then storage duration is improved, but aggregation occurs leading to performance deterioration

Engineering Contradiction:
Improvestorage durationVSAvoidelectrical characteristics
Core Design Contradiction:
Duration of action of stationary objectVSReliability

Solution Approach 1:

The patent applies temperature parameter change (storing at 10°C or lower) to simultaneously achieve long storage duration and maintain reliability. The low temperature prevents the aggregation that would otherwise occur during long-term storage, thereby preserving the electrical characteristics of the nanocarbon materials.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent performs preliminary action by adjusting the surfactant concentration to an optimal range (1-100 times the critical micelle concentration) before storage. This preliminary adjustment ensures that the dispersion remains stable during long-term storage, preventing aggregation and maintaining electrical characteristics without requiring additional interventions later.

Inventive Principle:
Principle #10Preliminary action

3Stability of the object's composition

If surfactant concentration is increased to prevent aggregation, then dispersion stability is improved, but turbidity formation occurs

Engineering Contradiction:
Improvedispersion stabilityVSAvoidturbidity
Core Design Contradiction:
Stability of the object's compositionVSObject-generated harmful factors

Solution Approach 1:

The patent precisely controls the surfactant concentration parameter within a specific range (1-100 times the critical micelle concentration). This optimized parameter setting provides enough surfactant to stabilize the dispersion and prevent aggregation, while avoiding excess surfactant that would cause turbidity formation through micelle aggregation.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses surfactant as an intermediary substance to mediate between the nanocarbon particles and the dispersion medium. By optimizing the surfactant concentration, it achieves effective stabilization of the dispersion without the harmful side effect of turbidity, as the surfactant forms appropriate micellar structures that keep particles dispersed but transparent.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Stability of the object's composition

If low temperature storage is implemented, then dispersion uniformity is improved, but storage complexity increases

Engineering Contradiction:
Improvedispersion uniformityVSAvoidstorage system complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The patent implements a modest temperature parameter change (to 10°C or lower) that can be achieved with standard refrigerator equipment. This level of temperature control improves dispersion uniformity significantly while adding minimal complexity to the storage system, as it does not require specialized cryogenic equipment or complex temperature control mechanisms.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method allows for the stable storage of nanocarbon dispersion liquids for extended periods without turbidity, maintaining electrical conductivity and ensuring the long-term usability of nanocarbon materials in electronic applications.

Implementation Method 1

storing the nanocarbon dispersion liquid at 10° C. or lower

Methodology Applied
Scientific EffectThermal energy reduction: Cooling

Implementation Method 2

adjusting a concentration of the surfactant in the nanocarbon dispersion liquid so as to be less than 100 times of a critical micelle concentration

Methodology Applied
Scientific EffectSurfactant micelle formation: Surfactant

Data Source

PatentUS11479469B2Method for storing a nanocarbon dispersion liquid
Publication Date: 2022.10.25 NEC CORP
  • US11479469B2 patent drawing

AI summary

Provided is a method for stably storing a nanocarbon dispersion liquid comprising a surfactant for a long period of time. One aspect of the present invention relates to a method for storing a nanocarbon dispersion liquid comprising a low-temperature storage step of storing the nanocarbon dispersion liquid at 10° C. or lower and/or a surfactant concentration adjustment step of adjusting a concentration of the surfactant in the nanocarbon dispersion liquid so as to be less than 100 times of a critical micelle concentration and equal to or more than the critical micelle concentration.