Nano-catalyst Production via Metal Ion Complexation

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Solution Overview

Problem

Current methods for producing nanostructures face challenges in achieving sufficient quantity, purity, and uniformity of morphology, making it difficult to manufacture nanomaterials effectively.

Innovation Solution

A method involving the use of complexing agents to bind metal ions to metal powders or substrates, followed by reduction in a specific atmosphere to form nano-catalysts as metal nanoparticles, which can be used to fabricate nanostructures and nanomaterials efficiently.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional methods are used to produce nanostructures, then production quantity can be increased, but manufacturing precision and uniformity of morphology deteriorate

Engineering Contradiction:
Improveproduction quantityVSAvoiduniformity of morphology
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent applies preliminary action by pre-coating metal powder particles with a controlled layer of metal ions before reduction. The metal ions are deposited on the surface of the metal powder in advance, creating a standardized precursor structure that ensures uniform morphology during subsequent nanostructure growth. This pre-preparation step establishes consistent nucleation sites that guide uniform nanostructure formation while enabling scalable production.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent employs parameter changes by controlling the concentration, distribution, and density of metal ions on the metal powder surface. By adjusting parameters such as ion deposition time, ion solution concentration, and reduction conditions, the method achieves precise control over nanostructure size, shape, and uniformity. This parameter optimization enables simultaneous improvement of production quantity and morphological consistency.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If conventional methods are used to produce nanostructures, then production speed can be increased, but manufacturing precision and purity deteriorate

Engineering Contradiction:
Improveproduction speedVSAvoidpurity
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent uses metal ions as an intermediary substance between the metal powder substrate and the final nanostructure product. The metal ions serve as a controllable intermediate layer that can be precisely deposited and then reduced to form nanostructures. This intermediary approach allows for purer, more controlled nanostructure formation while maintaining production speed, as the ion layer acts as a template that guides uniform growth without requiring complex post-processing purification steps.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Manufacturing precision

If complexing agents are used to bind metal ions to metal powder, then manufacturing precision improves, but device complexity increases

Engineering Contradiction:
Improvecontrol over nanostructure formationVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent employs disposable complexing agents that are used in the metal ion deposition step and then removed or degraded in subsequent processing. These complexing agents facilitate precise metal ion binding to metal powder surfaces during deposition but are not retained in the final product. This approach achieves high manufacturing precision through controlled complexation while avoiding long-term process complexity, as the agents are consumed in a single-use manner and do not require complex recovery or recycling systems.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of nano-catalysts that can be used to grow nanostructures in situ, enhancing the formation of nanostructure-bearing composite materials with improved catalytic properties and efficiency.

Implementation Method 1

contacting a metal powder with a first solution comprising a complexing agent to produce a complexed metal powder

Methodology Applied
Scientific EffectComplexation: Chemical Bonding

Implementation Method 2

contacting the metal ions bound to the complexed metal powder with a reducing atmosphere to form the nano-catalyst as metal nanoparticles on the metal powder

Methodology Applied
Scientific EffectReduction: Reduction

Data Source

PatentUS9878307B2Method of producing catalytic material for fabricating nanostructures
Publication Date: 2018.01.30 CONSOLIDATED NUCLEAR SECURITY LLC
  • US9878307B2 patent drawing
  • US9878307B2 patent drawing
  • US9878307B2 patent drawing

AI summary

Methods of fabricating nano-catalysts are described. In some embodiments the nano-catalyst is formed from a powder-based substrate material and is some embodiments the nano-catalyst is formed from a solid-based substrate material. In some embodiments the substrate material may include metal, ceramic, or silicon or another metalloid. The nano-catalysts typically have metal nanoparticles disposed adjacent the surface of the substrate material. The methods typically include functionalizing the surface of the substrate material with a chelating agent, such as a chemical having dissociated carboxyl functional groups (—COO), that provides an enhanced affinity for metal ions. The functionalized substrate surface may then be exposed to a chemical solution that contains metal ions. The metal ions are then bound to the substrate material and may then be reduced, such as by a stream of gas that includes hydrogen, to form metal nanoparticles adjacent the surface of the substrate.