Nano-clay Cement Sheath Gas Migration

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Well cement compositions face challenges such as structural failure due to shear stresses, gas migration, and corrosion from exposure to corrosive fluids like CO2, which affect the integrity and permeability of the cement sheath in subterranean formations.

Innovation Solution

Incorporating nano-clay, specifically nano-bentonite, into cement compositions to enhance mechanical properties, reduce permeability, and improve resistance to corrosive environments, with nano-clay present in amounts ranging from 0.1% to 25% by weight of the hydraulic cement, and having dimensions between 1 nanometer and 1 micron, forming a plate-type structure.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If traditional cement compositions are used to form the cement sheath, then the cementing process is simple and cost-effective, but the cement sheath suffers structural failure due to shear stresses from pipe movements and high fluid pressures

Engineering Contradiction:
Improvecompressive strengthVSAvoidstructural integrity
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent applies composite materials by combining conventional cement with nanoscale additives (nanosilica, nanoclay, or nanoxide particles sized 1-100 nm). This composite approach enhances the cement sheath's compressive strength and structural integrity while maintaining workability, directly resolving the contradiction between strength and reliability.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the physical parameters of the cement composition by incorporating nanoparticles with specific size ranges (1-100 nm) and aspect ratios. These parameter changes at the nanoscale level improve the cement's mechanical properties and resistance to shear stresses, addressing the structural failure issue while keeping the base cement composition relatively simple.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the cement composition is made more permeable to allow fluid flow during setting, then the cement sets properly, but gas migration occurs through the cement sheath compromising zonal isolation

Engineering Contradiction:
Improvezonal isolationVSAvoidcement setting process
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent changes the permeability parameter of the cement sheath by incorporating nanoparticles that refine the pore structure. The nanoscale particles (1-100 nm) fill voids and create a tighter matrix, reducing overall permeability to prevent gas migration while maintaining adequate fluid flow during the setting process through proper mix design and water-to-cement ratios.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes controlled porous structures by incorporating nanoparticles that create a refined pore network. This controlled porosity allows sufficient fluid flow for proper setting while preventing gas migration, as the nanoparticle-filled matrix creates pathways that are permeable to setting fluids but impermeable to gas under reservoir conditions.

Inventive Principle:
Principle #31Porous materials

3Reliability

If the cement sheath is made less permeable to prevent gas migration, then zonal isolation is improved, but the cement becomes more susceptible to corrosion from corrosive fluids like CO2

Engineering Contradiction:
Improvezonal isolationVSAvoidcorrosion resistance
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies composite materials by combining cement with corrosion-resistant nanoparticles (nanosilica, nanoclay, or nanoxide). This composite structure reduces permeability to prevent gas migration while the nanoparticle matrix provides barrier protection against corrosive fluids like CO2, simultaneously addressing both zonal isolation and corrosion resistance.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the chemical and physical parameters of the cement sheath by incorporating nanoparticles that modify both permeability and chemical resistance. The nanoscale additives create a denser, less permeable structure that blocks gas migration pathways while also providing a barrier against corrosive fluid penetration, thus improving both zonal isolation and corrosion resistance.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If high amounts of cement are used to ensure adequate zonal isolation, then the cementing process is robust, but the cost and complexity of the cementing operation increases

Engineering Contradiction:
Improvezonal isolationVSAvoidcementing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials to enhance the performance of the cement sheath, allowing adequate zonal isolation to be achieved with optimized (rather than maximized) cement volumes. The nanoparticle-enhanced cement provides superior isolation properties per unit volume, reducing the need for excessive cement quantities and simplifying the overall cementing process.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the performance parameters of the cement composition by incorporating nanoparticles, which improve the cement's isolation effectiveness. This allows the cementing process to achieve reliable zonal isolation with optimized cement volumes and simplified procedures, rather than requiring high amounts of traditional cement and complex operations.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of nano-clay in cement compositions enhances compressive strength, reduces permeability, and improves resistance to corrosive environments, thereby maintaining the structural integrity and zonal isolation of the cement sheath, reducing susceptibility to gas migration and corrosion.

Implementation Method 1

Reducing the permeability of the cement sheath generally may reduce flow paths for the acid, thus reducing the exposure of the cement sheath to potentially damaging acid

Methodology Applied
Scientific EffectPermeability reduction through nanoparticle incorporation: Porosity

Implementation Method 2

The present invention relates to well treatment methods utilizing nano-clay

Methodology Applied
Scientific EffectStrength enhancement through nanoparticle reinforcement:

Implementation Method 3

improve resistance to corrosive environments, thereby maintaining the structural integrity and zonal isolation of the cement sheath, reducing susceptibility to gas migration and corrosion

Methodology Applied
Scientific EffectCorrosion resistance through nanoparticle barrier:

Data Source

PatentEP2480620B1Method of cementing
Publication Date: 2020.01.08 HALLIBURTON ENERGY SERVICES INC

AI summary

The present invention includes well treatment fluids and methods utilizing nano- particles. An embodiment of a method of the present invention may comprise introducing a treatment fluid comprising nano-clay into a subterranean formation. The treatment fluid may be selected from the group consisting of a cement composition, a drilling fluid, a spacer fluid, and a lost circulation control composition. Another embodiment of the present invention may comprise a method of cementing. The method of cementing may comprise introducing a cement composition comprising a hydraulic cement, nano-clay, and water into a subterranean formation. The method further may comprise allowing the cement composition to set in the subterranean formation. Yet another embodiment of the present invention may comprise a treatment fluid, the treatment fluid comprising nano-clay. The treatment fluid may be selected from the group consisting of a cement composition, a drilling fluid, a spacer fluid, and a lost circulation control composition.