Nanocoated Solid Electrolytic Capacitor for Humidity Resistance

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Solution Overview

Problem

Conventional solid electrolytic capacitors are prone to increased leakage current and capacitance loss due to silver ion migration when exposed to high humidity environments, especially at elevated temperatures.

Innovation Solution

A solid electrolytic capacitor design featuring a sintered porous anode body, dielectric, and solid electrolyte, encapsulated in a casing material with nanocoatings applied to the capacitor element, casing, and terminations, utilizing vapor-deposited polymers to reduce moisture sensitivity and maintain electrical properties in humid conditions.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional solid electrolytic capacitors are used in high humidity environments, then they provide basic capacitance function, but silver ions migrate through the electrolyte causing increased leakage current and capacitance loss

Engineering Contradiction:
Improvecapacitance retentionVSAvoidmoisture sensitivity
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

A moisture barrier coating is introduced as an intermediary layer between the external humid environment and the capacitor components. This coating acts as a mediator that blocks moisture from reaching the silver layer and electrolyte, preventing silver ion migration while maintaining the capacitor's electrical function. The coating serves as a protective interface that isolates harmful environmental factors from sensitive internal components.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The invention converts the harmful effect of moisture exposure into a beneficial protective mechanism by applying a moisture barrier coating. The coating transforms the potential damage from humidity (silver ion migration, leakage current increase) into a protected state where the capacitor maintains stable electrical properties. The barrier coating effectively reverses the harmful interaction between moisture and capacitor components.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

2Reliability

If silver layer is exposed to high humidity and temperature, then electrical connection is maintained, but silver ions form and migrate causing leakage current increase

Engineering Contradiction:
Improveleakage current stabilityVSAvoidoperating temperature in humid environment
Core Design Contradiction:
ReliabilityVSTemperature

Solution Approach 1:

The moisture barrier coating serves as a thermal and moisture intermediary that protects the silver layer from direct exposure to high temperature and humidity conditions. The coating allows the capacitor to operate at elevated temperatures while preventing the combination of heat and moisture that triggers silver ion formation and migration, thereby maintaining leakage current stability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

A thin film moisture barrier coating is applied to the capacitor components, creating a flexible protective shell that conforms to the capacitor structure. This thin film provides effective protection against moisture ingress and thermal stress, preventing silver ion migration while maintaining the capacitor's electrical performance at high operating temperatures in humid environments.

Inventive Principle:
Principle #30Flexible shells and thin films

3Reliability

If nanocoating is applied to capacitor elements, then moisture sensitivity is reduced and capacitance retention is improved, but manufacturing complexity increases

Engineering Contradiction:
Improveperformance stability in humid conditionsVSAvoidmanufacturing process complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The invention applies nanocoating with controlled thickness parameters (typically 1-100 nanometers) to achieve effective moisture protection without significantly increasing device complexity. By optimizing the coating thickness parameter, the solution provides sufficient barrier protection against moisture while maintaining manufacturing feasibility. The parameter control ensures that the coating is thin enough to avoid excessive complexity but thick enough to provide reliable protection.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The capacitor structure is enhanced with a composite material approach by integrating a nanocoating layer with the existing capacitor components. This composite structure combines the electrical properties of the original capacitor materials with the moisture-blocking properties of the nanocoating, achieving improved reliability in humid conditions without substantially increasing manufacturing complexity. The nanocoating integrates seamlessly with the existing fabrication processes.

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The capacitor exhibits low equivalent series resistance, minimal capacitance loss, and high wet-to-dry capacitance percentage, maintaining performance for extended periods at high humidity and temperature, with leakage current reduced to 50 microamps or less and capacitance retention of 80% or more.

Implementation Method 1

The nanocoating contains a vapor-deposited polymer

Methodology Applied
Scientific EffectVapor deposition: Physical Vapour Deposition

Data Source

PatentUS11257628B2Solid electrolytic capacitor containing a nanocoating
Publication Date: 2022.02.22 KYOCERA AVX COMPONENTS CORP
  • US11257628B2 patent drawing
  • US11257628B2 patent drawing
  • US11257628B2 patent drawing

AI summary

A capacitor that comprises a solid electrolytic capacitor element, a casing material that encapsulates the capacitor element, an anode termination, and a cathode termination is provided. A nanocoating is disposed on at least a portion of the capacitor element, casing material, anode termination, cathode termination, or a combination thereof. The nanocoating has an average thickness of about 2,000 nanometers or less and contains a vapor-deposited polymer.