Diffusion Controlled Nanocomposite Inks for GRIN Optical Elements

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Solution Overview

Problem

Current inkjet printing technologies face limitations in achieving high-fidelity gradient nanocomposites due to challenges in controlling nanoparticle diffusion, which affects the refractive index gradients in GRIN optics, leading to suboptimal optical performance.

Innovation Solution

The method involves using a combination of diffusion-inhibiting and diffusion-permitting nanocomposite inks, where the diffusion-inhibiting inks prevent nanoparticle migration in high-frequency gradient areas and the diffusion-permitting inks allow for controlled nanoparticle distribution, achieved through precise deposition and curing techniques, to create a volumetric gradient refractive profile.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If nanoparticle diffusion is permitted in nanocomposite inks, then nanoparticle distribution is improved, but refractive index gradient precision deteriorates

Engineering Contradiction:
Improvenanoparticle distributionVSAvoidrefractive index gradient precision
Core Design Contradiction:
Stability of the object's compositionVSManufacturing precision

Solution Approach 1:

The patent applies local quality by creating different ink formulations with specific properties for different regions of the GRIN optical element. Diffusion-inhibiting inks are used in high-frequency gradient areas where precision is critical, while diffusion-permitting inks are used in low-frequency gradient areas where nanoparticle distribution is more important. This local differentiation resolves the contradiction by allowing both precise gradient control and adequate nanoparticle distribution in appropriate regions.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent segments the nanocomposite ink system into two distinct types: diffusion-inhibiting nanocomposite inks and diffusion-permitting nanocomposite inks. Each type serves a specific function in different regions of the optical element. This segmentation allows the system to simultaneously achieve both precise refractive index gradients (using diffusion-inhibiting inks) and proper nanoparticle distribution (using diffusion-permitting inks), thereby resolving the technical contradiction.

Inventive Principle:
Principle #1Segmentation

2Manufacturing precision

If diffusion-inhibiting inks are used in high-frequency gradient areas, then refractive index gradient precision is improved, but nanoparticle distribution uniformity deteriorates

Engineering Contradiction:
Improverefractive index gradient precisionVSAvoidnanoparticle distribution uniformity
Core Design Contradiction:
Manufacturing precisionVSStability of the object's composition

Solution Approach 1:

The patent applies local quality by matching ink types to specific spatial frequency requirements. Diffusion-inhibiting inks are strategically applied only in high-frequency gradient areas where precision is paramount, while diffusion-permitting inks are applied in low-frequency gradient areas where uniformity is more critical. This localized application strategy resolves the contradiction by ensuring each ink type operates in the region where its strengths are most needed.

Inventive Principle:
Principle #3Local quality

3Manufacturing precision

If multiple types of nanocomposite inks are used, then control over nanoparticle diffusion is improved, but manufacturing complexity increases

Engineering Contradiction:
Improvecontrol over nanoparticle diffusionVSAvoidmanufacturing complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent segments the ink system into two distinct categories with clearly defined properties and applications. This segmentation provides a systematic framework for controlling nanoparticle diffusion while maintaining manageable manufacturing complexity. The two-ink system offers sufficient control capability without requiring a complex multi-ink formulation, thereby resolving the contradiction between control precision and manufacturing simplicity.

Inventive Principle:
Principle #1Segmentation

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of high-fidelity GRIN optical elements with precise refractive index gradients, enhancing the optical performance by accurately controlling nanoparticle distribution and diffusion, thereby overcoming the limitations of existing technologies.

Implementation Method 1

nanoparticle diffusion is permitted with respect to at least another of the plurality of nanocomposite-inks

Methodology Applied
Scientific EffectDiffusion: Diffusion

Implementation Method 2

nanoparticle diffusion is inhibited with respect to another of the plurality of nanocomposite-inks

Methodology Applied
Scientific EffectDiffusion inhibition: Diffusion Barrier

Implementation Method 3

Mixing between the diffusion inhibited nanocomposite-inks is forced by advection mechanisms, for instance through droplet deposition

Methodology Applied
Scientific EffectAdvection: Advection

Data Source

PatentUS11174400B2Diffusion controlled nanocomposite-inks
Publication Date: 2021.11.16 VADIENT OPTICS LLC
  • US11174400B2 patent drawing
  • US11174400B2 patent drawing
  • US11174400B2 patent drawing

AI summary

A method of manufacturing a nanocomposite GRIN optical-element. The method comprises providing a volumetric gradient refractive profile and providing a plurality of nanocomposite-inks to form the GRIN optical-element. Each of the plurality of nanocomposite-inks have nanoparticles dispersed in an organic-matrix. The plurality of nanocomposite-inks comprising of a nanoparticle diffusion inhibiting nanocomposite-ink wherein nanoparticle diffusion is inhibited with respect to another of the plurality of nanocomposite-inks. The diffusion inhibiting nanocomposite-ink having a different dielectric property from at least one of the other plurality of nanocomposite-inks. The plurality of nanocomposite-inks also comprising a nanoparticle diffusion permitting nanocomposite-ink wherein nanoparticle diffusion is permitted with respect to at least another of the plurality of nanocomposite-inks.