g-C3N4 Fe2O3 MgAl2O4 Nanocomposite for Visible-Light Water Decontamination

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Solution Overview

Problem

Existing adsorption techniques for heavy metal removal in industrial wastewater suffer from low adsorption capacity, high operational costs, complex regeneration procedures, and limited selectivity, with graphite-phase carbon nitride (g-C3N4) facing issues like low specific surface area and rapid electron-hole pair recombination.

Innovation Solution

A nanocomposite comprising graphitic C3N4, Fe2O3, and MgAl2O4 is used for photodegradation of organic pollutants, with a specific mass ratio and structural properties optimized for enhanced adsorption and photocatalytic performance, avoiding the use of H2O2 or O3 and minimizing metal content.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Stability of the object's composition

If g-C3N4 is used for pollutant degradation, then visible light responsiveness and chemical stability are improved, but specific surface area is low and electron-hole pair recombination is rapid

Engineering Contradiction:
Improvechemical stabilityVSAvoidspecific surface area
Core Design Contradiction:
Stability of the object's compositionVSArea of stationary object

Solution Approach 1:

The patent creates a composite material consisting of g-C3N4 combined with metal oxide nanoparticles (such as TiO2, ZnO, Fe2O3) or semiconductor quantum dots. This composite structure allows the g-C3N4 to maintain its chemical stability and visible light responsiveness while the metal oxide or quantum dot components provide additional active sites that increase the overall specific surface area and reduce electron-hole recombination through improved charge separation.

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If g-C3N4 is used for pollutant degradation, then visible light responsiveness is improved, but electron-hole pair recombination is rapid

Engineering Contradiction:
Improvevisible light responsivenessVSAvoidelectron-hole pair recombination
Core Design Contradiction:
Illumination intensityVSLoss of energy

Solution Approach 1:

The patent introduces metal oxide nanoparticles or semiconductor quantum dots as intermediary materials that facilitate charge separation. These intermediary materials act as electron acceptors or donors, creating heterojunctions with g-C3N4 that promote efficient separation of photogenerated electron-hole pairs. The intermediaries provide additional pathways for charge transfer, reducing recombination losses while maintaining visible light absorption capabilities.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Reliability

If adsorption techniques are used for heavy metal removal, then removal efficiency is improved, but adsorption capacity is low

Engineering Contradiction:
Improveremoval efficiencyVSAvoidadsorption capacity
Core Design Contradiction:
ReliabilityVSQuantity of substance

Solution Approach 1:

The patent employs porous versions of g-C3N4 or composite materials with engineered porous structures. The porous architecture provides a dramatically increased surface area-to-volume ratio, creating numerous adsorption sites for heavy metal ions. The porous structure allows efficient diffusion of contaminants into the material interior, thereby simultaneously improving both removal efficiency and overall adsorption capacity.

Inventive Principle:
Principle #31Porous materials

4Reliability

If conventional remediation techniques are used, then heavy metal removal is achieved, but operational costs are high

Engineering Contradiction:
Improveheavy metal removalVSAvoidoperational costs
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The patent utilizes g-C3N4-based photocatalytic materials that can degrade organic pollutants and adsorb heavy metals using sunlight or visible light as the energy source. This self-service mechanism eliminates the need for expensive external energy inputs, chemical reagents, or complex operational systems. The material performs its remediation function autonomously under ambient lighting conditions, significantly reducing operational costs while maintaining effective contaminant removal.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The nanocomposite achieves improved adsorption capacity, selectivity, and regeneration potential, effectively photodegrading organic compounds and decontaminating water under visible light conditions, while being cost-effective and environmentally friendly.

Implementation Method 1

graphite-phase carbon nitride (g-C3N4)...visible light responsiveness...photodegradation of organic pollutants

Methodology Applied
Scientific EffectPhotocatalysis: Photo-oxidation

Implementation Method 2

adsorption techniques have garnered considerable attention...adsorption capacities...specific surface area

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12479743B1Photodegradation of contaminants via a nanocomposite
Publication Date: 2025.11.25 IMAM MOHAMMAD IBN SAUD ISLAMIC UNIV
  • US12479743B1 patent drawing
  • US12479743B1 patent drawing
  • US12479743B1 patent drawing

AI summary

A method of photodegrading an organic compound may include irradiating, in the presence of the organic compound, a nanocomposite comprising graphitic C3N4, Fe2O3, and MgAl2O4 in a mass relationship to each other in a range of from 5 to 15:2 to 7:75 to 95, at a temperature in a range of from 10° C. to 80° C. in a contaminated volume of water, thereby photodegrading the organic compound to partially decompose the organic compound and at least partially decontaminate the contaminated volume of water.