Nanocrystal Waveguide Outcoupling via Periodic Cladding

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Solution Overview

Problem

Existing optical waveguides face challenges in efficiently coupling light with nanocrystals for emission, as the confined optical field within the waveguide limits the propagation and outcoupling of emission wavelengths, leading to low outcoupling efficiencies and potential re-absorption of nanocrystal luminescence.

Innovation Solution

Incorporating semiconductor nanocrystals on the surface of optical waveguides, with a periodic variation in the waveguide structure to restrict propagation of emission wavelengths, allowing for enhanced coupling and emission of light, and using a combination of nanocrystals and downconverting elements to achieve efficient light distribution and spectral tuning.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If nanocrystals are placed on the waveguide surface for optical coupling, then light emission efficiency is improved, but propagation restriction of emission wavelengths causes loss of light along the waveguide

Engineering Contradiction:
Improvelight emission efficiencyVSAvoidlight propagation loss
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

The waveguide structure is segmented into periodic modulation regions that create spatially varying optical properties. This segmentation allows different regions to serve different functions: some regions couple light efficiently to nanocrystals while other regions allow emission wavelengths to propagate, thereby resolving the contradiction between efficient coupling and minimizing propagation loss.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The waveguide is designed with non-uniform local properties through periodic modulation of the cladding layer thickness or refractive index. This local quality variation enables selective interaction with different wavelengths: the excitation wavelength experiences strong coupling in nanocrystal regions while emission wavelengths experience reduced propagation restriction, simultaneously achieving high emission efficiency and reduced energy loss.

Inventive Principle:
Principle #3Local quality

2Productivity

If periodic variation is introduced to restrict emission wavelength propagation, then outcoupling efficiency is improved, but waveguide structure complexity increases

Engineering Contradiction:
Improveoutcoupling efficiencyVSAvoidwaveguide structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The waveguide employs a composite structure combining the core waveguide material with a periodically modulated cladding layer. This composite design achieves the periodic variation needed for high outcoupling efficiency while maintaining structural simplicity through a single-layer modulation approach rather than multiple complex layers or components.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The cladding layer thickness or refractive index is varied periodically along the waveguide length with a specific spatial frequency. This periodic action creates the necessary bandgap structure for restricting emission wavelengths while maintaining a simple, manufacturable structure that can be implemented through standard fabrication techniques without excessive complexity.

Inventive Principle:
Principle #19Periodic action

3Use of energy by moving object

If excitation light is distributed through the waveguide to nanocrystals, then lighting efficiency is improved, but re-absorption of nanocrystal luminescence occurs

Engineering Contradiction:
Improvelighting efficiencyVSAvoidre-absorption loss
Core Design Contradiction:
Use of energy by moving objectVSLoss of energy

Solution Approach 1:

The emission wavelengths generated by nanocrystals are extracted from the waveguide propagation mode through the periodic cladding modulation. This extraction removes the emitted light from the guided mode before it can be re-absorbed by downstream nanocrystals, thereby maintaining high lighting efficiency while eliminating re-absorption losses.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The periodically modulated cladding layer acts as an intermediary between the nanocrystals and the external environment. It facilitates efficient energy transfer from excitation light to nanocrystals while simultaneously providing a pathway for emission wavelengths to escape the waveguide, preventing re-absorption and maintaining high overall lighting efficiency.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach significantly enhances outcoupling efficiency, allowing for over 90% of nanocrystal-emitted light to be released from the optical structure, overcoming previous limitations of low outcoupling and re-absorption, and enabling broad spectral tunability and long-lasting photoluminescence for lighting applications.

Implementation Method 1

a nanocrystal capable of emitting light at an emission wavelength when excited by an excitation wavelength

Methodology Applied
Scientific EffectPhotoluminescence: Photoluminescence

Implementation Method 2

Optical waveguides, such as fibers and planar waveguides, which take advantage of total internal reflection

Methodology Applied
Scientific EffectTotal internal reflection: Total Internal Reflection

Data Source

PatentUS9910215B2Optical structures including nanocrystals
Publication Date: 2018.03.06 MASSACHUSETTS INST OF TECH
  • US9910215B2 patent drawing
  • US9910215B2 patent drawing
  • US9910215B2 patent drawing

AI summary

An optical structure can include a nanocrystal on a surface of an optical waveguide in a manner to couple the nanocrystal to the optical field of light propagating through the optical waveguide to generate an emission from the nanocrystal. The structure can be configured to restrict propagation of the emission from the nanocrystal along the waveguide.