Nanoencapsulation of Reflective Core Particles for Structural Color

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Solution Overview

Problem

The existing methods for forming multilayer thin film structures are time-consuming and costly, requiring multiple deposition steps and high-vacuum processes, which are difficult to maintain and expensive, and result in complex processes for producing omnidirectional structural color.

Innovation Solution

A nanoencapsulation method that directly deposits layers onto a reflective core particle, reducing the number of steps to three: depositing a dielectric layer, an absorber layer, and an outer layer, using techniques like ALD or PVD, to form a multilayer thin film structure with a hue shift of less than 30° in the Lab color space when viewed at angles from 0° to 45°.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If traditional high vacuum deposition processes are used to form multilayer thin film structures, then the structural color and optical properties can be achieved, but the production time and cost increase significantly

Engineering Contradiction:
Improveoptical propertiesVSAvoidproduction time
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent segments the multilayer thin film structure into discrete layers (dielectric layer, absorber layer, outer layer) that can be deposited sequentially using ALD/PVD techniques. This segmentation allows each layer to be optimized independently for optical performance while reducing the total number of deposition steps compared to traditional methods, thereby improving both manufacturing precision and productivity

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent changes the deposition parameters by using atomic layer deposition (ALD) and physical vapor deposition (PVD) techniques with controlled thickness parameters (e.g., dielectric layer 50-500 nm, absorber layer 1-50 nm). These parameter changes enable precise control over optical properties while reducing production time through optimized deposition rates and fewer processing steps

Inventive Principle:
Principle #35Parameter changes

2Manufacturing precision

If multiple distinct deposition steps are used to deposit seven layers, then precise layer control is achieved, but the process complexity and cost increase

Engineering Contradiction:
Improvelayer thickness controlVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent merges multiple deposition steps into a unified ALD/PVD process sequence where the dielectric layer, absorber layer, and outer layer are deposited in three integrated steps rather than seven distinct steps. This merging maintains precise thickness control through ALD's atomic-layer precision while significantly reducing process complexity and equipment requirements

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent employs universal ALD and PVD deposition techniques that can deposit multiple different materials (dielectrics, metals, oxides) using the same equipment and process framework. This multi-functionality allows precise control of various layer thicknesses and compositions without requiring separate specialized equipment for each material type, reducing overall process complexity

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Manufacturing precision

If high vacuum is maintained during lengthy deposition, then quality thin films are formed, but the operational difficulty and cost increase

Engineering Contradiction:
Improvefilm qualityVSAvoidvacuum maintenance difficulty
Core Design Contradiction:
Manufacturing precisionVSEase of operation

Solution Approach 1:

The patent implements continuous ALD/PVD deposition processes where layers are deposited sequentially without breaking vacuum or interrupting the process flow. This continuity maintains high film quality through consistent deposition conditions while reducing operational difficulty by eliminating repeated vacuum pumping and chamber venting cycles that would increase complexity and cost

Inventive Principle:
Principle #20Continuity of useful action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method significantly reduces production time and cost by simplifying the deposition process, achieving efficient and cost-effective formation of multilayer thin film structures with omnidirectional structural color, similar to those with many more layers, while maintaining precise control over layer thickness and optical properties.

Implementation Method 1

directly depositing an absorber layer to encapsulate a dielectric layer

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Implementation Method 2

depositing an outer layer to encapsulate the absorber layer

Methodology Applied
Scientific EffectPhysical Vapour Deposition: Physical Vapour Deposition

Data Source

PatentUS12066595B2Nanoencapsulation methods for forming multilayer thin film structures and multilayer thin films formed therefrom
Publication Date: 2024.08.20 TOYOTA JIDOSHA KK
  • US12066595B2 patent drawing
  • US12066595B2 patent drawing
  • US12066595B2 patent drawing

AI summary

A multilayer thin film structure having a reflective core particle, a dielectric layer directly encapsulating the reflective core particle, an absorber layer directly encapsulating the dielectric layer; an outer layer encapsulating the absorber layer. The multilayer thin film structure has a hue shift of less than 30° in the Lab color space when viewed at angles from 0° to 45°.