Nanoimprint Resin Composition Single-Layer Etching Resistance

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Solution Overview

Problem

Existing nanoimprint methods require forming two resin layers to achieve both flexibility and etching resistance, which complicates the process and reduces production efficiency.

Innovation Solution

A composition for nanoimprint comprising a cycloolefin-based copolymer, a polymerizable monomer, and a photoinitiator is used to form a single-layered resin layer that provides both high etching resistance and flexibility, allowing for the transfer of uneven patterns from a mold.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If two resin layers are formed to achieve both flexibility and etching resistance, then both flexibility and etching resistance are improved, but the process complexity and manufacturing time increase

Engineering Contradiction:
Improveetching resistanceVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent combines the functions of flexibility and etching resistance into a single resin layer by incorporating specific additives (silane-modified polymer and metal oxide particles) into the resin composition, eliminating the need for separate functional layers while maintaining both properties

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent uses a composite resin composition containing silane-modified polymer, metal oxide particles (such as silica), and specific solvents to achieve both flexibility and etching resistance in a single layer, leveraging the synergistic effects of different materials

Inventive Principle:
Principle #40Composite materials

2Reliability

If two resin layers are formed to achieve both flexibility and etching resistance, then both flexibility and etching resistance are improved, but the production efficiency decreases

Engineering Contradiction:
Improveetching resistanceVSAvoidproduction efficiency
Core Design Contradiction:
ReliabilityVSProductivity

Solution Approach 1:

The patent merges multiple functional requirements into a single resin layer formulation, reducing the number of coating and curing cycles from two to one, thereby improving production efficiency while maintaining etching resistance

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The patent modifies the chemical composition parameters of the resin layer by adding silane-modified polymers and metal oxide particles, which fundamentally change the material properties to simultaneously provide flexibility and etching resistance without additional processing steps

Inventive Principle:
Principle #35Parameter changes

3Productivity

If a single-layered resin layer is formed, then the process is simplified and production efficiency is improved, but it is difficult to achieve both high etching resistance and flexibility

Engineering Contradiction:
Improveproduction efficiencyVSAvoidetching resistance
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent employs a composite resin system with silane-modified polymer base, metal oxide fillers for etching resistance, and specific solvents to achieve the desired balance of flexibility and etching resistance in a single layer

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent carefully controls the composition ratios and chemical parameters of the resin components to optimize the single-layer performance, ensuring both flexibility and etching resistance are achieved through precise formulation

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition enables the formation of a pattern forming layer with excellent etching resistance and flexibility, simplifying the process and ensuring reliable pattern transfer from the mold, while maintaining pattern precision and chemical resistance.

Implementation Method 1

a photoinitiator

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS10678129B2Composition for nanoimprint, cured product, pattern forming method, and article having pattern
Publication Date: 2020.06.09 TOKYO OHKA KOGYO CO LTD
  • US10678129B2 patent drawing
  • US10678129B2 patent drawing
  • US10678129B2 patent drawing

AI summary

A composition for nanoimprint including a cycloolefin-based copolymer; a polymerizable monomer; and a photoinitiator. The polymerizable monomer of the present invention may include a polyfunctional monomer, and the cycloolefin-based copolymer may include a constituent unit having a cyclic olefin and a constituent unit having an acyclic olefin.