Nanomaterial Composite Laminates for Impact Resistance

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Solution Overview

Problem

Current materials lack sufficient strength and adhesion properties, particularly in applications requiring high impact resistance and durability, such as hurricane-proof or bullet-resistant windows, where existing composites only offer limited enhancements.

Innovation Solution

A process involving the use of graphitic or organic/inorganic nanocomposites, specifically selecting and purifying nanomaterials like carbon nanotubes, graphene, and carbon nanofibers, mixing them with surfactants and additives, and applying them as a composite solution to enhance the strength and adhesion of materials like glass, polycarbonate, and acrylic, forming laminates with improved structural integrity and protection levels.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If conventional composite laminates are used to strengthen glass, then some strength improvement is achieved (20% increase), but the strength enhancement is insufficient for high impact resistance applications

Engineering Contradiction:
Improveglass strengthVSAvoidprotection level
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent uses carbon nanotubes (CNTs) as a reinforcing phase within the composite laminate structure. The CNTs form a three-dimensional network that bridges between glass surfaces and the laminate, creating a hybrid composite material system that combines the structural properties of glass with the high strength-to-weight ratio and impact resistance of carbon nanotubes, achieving 50% strength increase.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent applies the graphitic or organic/inorganic nanocomposite selectively at the interface between glass layers and the laminate structure. This localized application at critical stress points (where impact forces are transmitted) provides maximum strength enhancement where needed most, rather than uniformly throughout the entire structure.

Inventive Principle:
Principle #3Local quality

2Strength

If graphitic or organic/inorganic nanocomposites are applied to enhance strength and adhesion, then material properties are significantly improved, but the complexity of material selection and processing increases

Engineering Contradiction:
Improvematerial strengthVSAvoidprocessing complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent employs graphitic nanomaterials (such as carbon nanotubes, graphene, graphite) that serve multiple functions simultaneously: they provide mechanical reinforcement, enhance adhesion between layers, and offer UV radiation protection. This multi-functionality reduces the need for separate treatment layers and simplifies the overall processing procedure despite the advanced material used.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent utilizes the unique physical and chemical parameters of graphitic nanomaterials, particularly their high aspect ratio, surface area-to-volume ratio, and chemical reactivity, to achieve superior performance at very low concentrations. By changing the scale to the nanometer level, the patent obtains disproportionate benefits relative to the amount of material added and processing complexity incurred.

Inventive Principle:
Principle #35Parameter changes

3Strength

If advanced nanomaterials like carbon nanotubes are incorporated into composite laminates, then strength properties increase significantly (50% increase), but the cost and difficulty of material fabrication increases

Engineering Contradiction:
Improvecomposite laminate strengthVSAvoidfabrication ease
Core Design Contradiction:
StrengthVSEase of manufacture

Solution Approach 1:

The patent uses a polymer matrix as an intermediary medium to disperse and embed the carbon nanotubes uniformly throughout the laminate structure. This polymer carrier simplifies the fabrication process by allowing the nanomaterials to be incorporated through standard composite manufacturing techniques such as layering and curing, rather than requiring specialized nanoscale assembly processes.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent performs preliminary dispersion of carbon nanotubes in the polymer matrix before laminate assembly. This pre-mixing step ensures uniform distribution of the nanomaterials throughout the composite structure, preventing agglomeration and ensuring consistent mechanical properties throughout the final product, which simplifies subsequent manufacturing steps.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution significantly increases the strength and adhesion properties of materials, providing enhanced protection against impacts and environmental factors like UV radiation, while maintaining the original functions of the materials, and can be applied economically through a spray-on method.

Implementation Method 1

The CNT network forming between the glass surface and the composite laminates during the drying/curing process

Methodology Applied
Scientific EffectNetwork formation:

Implementation Method 2

The CNT network together with the composite is more effective to dispatch the impact stress generated by foreign projectiles

Methodology Applied
Scientific EffectStress distribution:

Implementation Method 3

The composite solution may include surfactant(s) to enhance homogeneity of the graphitic nanomaterial(s) in the solution

Methodology Applied
Scientific EffectSurfactant action: Surfactant

Implementation Method 4

The composite solution may include an adhesive, such as, but not limited to, an acetate adhesive, to aid bonding of the graphitic nanocomposite to a desired surface

Methodology Applied
Scientific EffectAdhesion: Adhesive

Implementation Method 5

for increasing protection levels of materials and strength properties; UV absorbing/blocking

Methodology Applied
Scientific EffectUV absorption: Absorption (EM radiation)

Data Source

PatentUS10053388B2Multifunctional compositions and material laminates with graphitic or other nanomaterials
Publication Date: 2018.08.21 UNIV HOUSTON SYST

AI summary

Compositions and methods for improved materials and material laminates with graphitic or inorganic/organic nanomaterials are presented. Graphitic or inorganic/organic nanomaterials, such as carbon nanotubes, carbon nanofibers, graphenes or graphene oxides, are introduced into an aqueous composition as fillers to provide a graphitic or inorganic/organic nanocomposite. Such composition may be used as laminates to improve adhesion between a film and a layer of material or between layers of materials and to increase not only strength properties, but also to provide other desired properties such as electronic properties, UV absorbing/blocking, optical-limiting, anti-reflective, fire-retardant, conducting, anti-microbial properties or pigmentation to say material. By tailoring the composite formulations with multiple graphitic or organic/inorganic nanomaterials, the resulting materials laminates become multifunctional and can be used for a variety of applications.