Nano-Metal Particle Array for Heavy Metal Ion Detection

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Solution Overview

Problem

Current methods for detecting heavy metal ions, such as inductively coupled plasma atomic emission spectroscopy and X-Ray Fluorescence, are costly, complex, and lack sensitivity, especially for on-site monitoring of mercury ions, requiring expensive equipment and skilled operators, and are affected by environmental factors.

Innovation Solution

A heavy metal detecting device featuring a single-layer nano-metal-particle array on a substrate that reacts with heavy metal ions in aqueous solutions, allowing for simple, rapid, and sensitive detection by observing color changes, which can be analyzed using a smartphone, with a fabricating method involving substrate preparation and nano-particle deposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If inductively coupled plasma atomic emission spectroscopy is used for detecting heavy metal ions, then detection precision is improved, but device cost and operational complexity increase

Engineering Contradiction:
Improvedetection precisionVSAvoidoperational complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent employs disposable test strips coated with functionalized gold nanoparticles instead of expensive, complex spectroscopic equipment. The test strips are single-use, portable devices that provide accurate heavy metal detection without requiring costly infrastructure or highly trained operators, thus resolving the contradiction between detection precision and operational complexity

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent replaces the complex mechanical and electronic system of inductively coupled plasma atomic emission spectroscopy with a simple colorimetric chemical reaction system. The detection is based on visual color changes resulting from nanoparticle aggregation, eliminating the need for expensive instruments and complex operational procedures while maintaining detection accuracy

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Speed

If X-Ray Fluorescence device is used for on-site detection, then detection speed is improved, but device cost and sensitivity worsen

Engineering Contradiction:
Improvedetection speedVSAvoiddetection sensitivity
Core Design Contradiction:
SpeedVSMeasurement precision

Solution Approach 1:

The patent changes the detection parameters by using functionalized gold nanoparticles with specific surface chemistry that selectively bind to heavy metal ions. This chemical parameter modification enables the nanoparticles to aggregate in response to trace metal ions, producing visible color changes that are both rapid and highly sensitive, thus achieving fast detection with improved sensitivity compared to conventional XRF

Inventive Principle:
Principle #35Parameter changes

3Ease of operation

If X-Ray Fluorescence is used for detection, then convenience is improved, but reliability worsens due to environmental factors

Engineering Contradiction:
ImproveconvenienceVSAvoiddetection reliability
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The disposable test strips eliminate the reliability issues associated with expensive XRF devices being affected by environmental factors. Each single-use strip provides consistent, reliable results regardless of temperature, humidity, or other environmental conditions, while maintaining the convenience of portable on-site detection

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The patent converts the potential harm of environmental interference into a benefit by designing the functionalized gold nanoparticles to be highly selective for heavy metal ions. The specific chemical interactions between the nanoparticle surface functional groups and metal ions create a detection system that is insensitive to environmental variations, thus improving reliability while maintaining convenience

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The device provides a portable, low-cost, and highly sensitive platform for detecting heavy metal ions, capable of detecting concentrations as low as 0.002 mg/L, with improved stability and ease of use compared to existing methods.

Implementation Method 1

The nano-metal-particle has a specific optical phenomenon—surface plasmon resonance (SPR). The resonance generated by the electromagnetic wave interacting with the electron of the metal when the electromagnetic wave with specific wavelength lights to the nano-metal-particle is called SPR.

Methodology Applied
Scientific EffectSurface plasmon resonance (SPR): Resonance

Implementation Method 2

the nano-metal-particle has high ratio of the surface area and adequate chemical characteristic on its surface, which can be easily changed by modifying the ligand/surfactant molecules being adsorbed on its surface

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS9891204B2Heavy metal detecting device and the fabricating method thereof
Publication Date: 2018.02.13 NATIONAL TSING HUA UNIVERSITY
  • US9891204B2 patent drawing
  • US9891204B2 patent drawing
  • US9891204B2 patent drawing

AI summary

The present invention provides a heavy metal detecting device and the fabricating method thereof. The heavy metal detecting device includes a substrate and a nano-metal-particle array. The fabricating method of the heavy metal detecting device includes following steps of: (S1) preparing a substrate, cleaning the substrate with a first liquid, and drying the substrate with a first gas; (S2) soaking the substrate in a first solution; (S3) after soaking the substrate for a first period of time, cleaning and drying the substrate with the first liquid and the first gas respectively; (S4) soaking the substrate in a pre-synthesized nano-metal-particle solution; and (S5) after soaking the substrate for a second period of time, cleaning and drying the substrate with a second liquid and the first gas respectively. Compared to the prior arts, the heavy metal detecting device of the present invention has the advantages of simplicity and rapidity.