Functionalized Nanomotor Patterning for High-Speed Microstructures

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Solution Overview

Problem

Current techniques for surface microstructure patterning, such as Dip Pen Nanolithography, are labor-intensive and limited by slow patterning speed and small area coverage, lacking the ability to macroscopically address and manipulate individual nanostructures effectively.

Innovation Solution

Functionalized nanomotors are used for localized material deposition during predefined motion, enabling the creation of defined nanostructures through controlled motion and reaction along predetermined paths, eliminating the need for scanning probe tips and allowing simultaneous patterning of multiple lines and varying heights.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If Dip Pen Nanolithography is used for surface microstructure patterning, then manufacturing precision is improved, but productivity deteriorates due to labor-intensive operation and slow patterning speed

Engineering Contradiction:
Improvepatterning precisionVSAvoidpatterning speed
Core Design Contradiction:
Manufacturing precisionVSProductivity

Solution Approach 1:

The patent employs self-propelled nanomotors that autonomously navigate and deposit materials without external manipulation. The nanomotors convert chemical energy from fuel decomposition into mechanical motion, enabling autonomous movement along predefined paths for material deposition, thereby eliminating labor-intensive scanning probe operations while maintaining patterning precision.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent replaces the mechanical scanning probe system with chemically-propelled nanomotors. Instead of mechanically moving a probe tip across the surface, the system uses nanomotors that self-propel through chemical reactions, substituting mechanical actuation with chemical energy conversion to achieve faster patterning speeds.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Manufacturing precision

If Dip Pen Nanolithography is used for surface microstructure patterning, then manufacturing precision is improved, but area coverage deteriorates due to limited small area patterning capability

Engineering Contradiction:
Improvepatterning precisionVSAvoidpatterning area coverage
Core Design Contradiction:
Manufacturing precisionVSArea of stationary object

Solution Approach 1:

The patent uses multiple independent nanomotors that can simultaneously operate across the substrate surface. Each nanomotor functions as an independent patterning unit, enabling parallel processing and expansion of the total patterned area while maintaining the high precision of individual nanomotor deposition.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The nanomotors are designed with universal functionality to perform both navigation and material deposition tasks. They can be functionalized with various reagents and catalysts, allowing them to pattern different materials and structures across large areas while maintaining consistent precision through their standardized self-propelled mechanism.

Inventive Principle:
Principle #6Universality (Multi-functionality)

3Device complexity

If traditional patterning methods are used, then device complexity is reduced, but adaptability deteriorates due to inability to macroscopically address and manipulate individual nanostructures

Engineering Contradiction:
Improvesystem complexityVSAvoidnanomachine manipulation capability
Core Design Contradiction:
Device complexityVSAdaptability or versatility

Solution Approach 1:

The nanomotors are functionalized with specific reagents and catalysts at their surfaces, creating localized functional properties. This enables them to selectively interact with specific substrates and perform targeted material deposition, providing adaptability to manipulate individual nanostructures while maintaining relatively simple overall system architecture.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The system achieves adaptability by changing the chemical parameters of the nanomotor surface through functionalization with different reagents. By modifying the chemical composition and catalytic properties of the nanomotor surface, the system can address and manipulate different types of nanostructures and substrates without increasing mechanical or structural complexity.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach provides a versatile and powerful route for creating microstructures over large areas with high resolution and speed, surpassing traditional methods by enabling rapid and precise patterning of diverse materials and complex patterns.

Implementation Method 1

a self-powered gold (Au)/platinum (Pt) or Au/nickel (Ni) bimetal nanowire motor can be powered by the catalytic decomposition of hydrogen peroxide fuel to oxygen and water

Methodology Applied
Scientific EffectCatalytic decomposition: Catalysis

Implementation Method 2

Such electrochemically-grown nanowires can effect autonomous movements in the axial direction

Methodology Applied
Scientific EffectElectrochemical reaction: Redox Reactions

Implementation Method 3

The nanomotor can include a ferromagnetic component connected to the anode component to magnetically control movement of the nanomachine

Methodology Applied
Scientific EffectMagnetic control: Magnetic Field

Implementation Method 4

functionalizing a nanomotor with a catalytic reagent... to induce a localized deposition or precipitation of a product onto a surface of a substrate

Methodology Applied
Scientific EffectCatalysis: Catalysis

Implementation Method 5

to induce a localized deposition or precipitation of a product onto a surface of a substrate

Methodology Applied
Scientific EffectPrecipitation: Precipitation

Implementation Method 6

an anode component that includes a metallic oxidizing catalyst to oxidize at least one electron donor substance in a solution

Methodology Applied
Scientific EffectOxidation: Oxidation

Implementation Method 7

The nanomotor can include a non-metallic redox catalyst functionalized to at least one of the anode component and the cathode component to increase a rate of a redox reaction in the solution

Methodology Applied
Scientific EffectRedox reaction: Redox Reactions

Implementation Method 8

a cathode component connected to the ferromagnetic component that includes a metallic reducing catalyst to reduce at least one electron acceptor substance in the solution

Methodology Applied
Scientific EffectReduction: Reduction

Data Source

PatentUS9352963B2Nanomotor-based patterning of surface microstructures
Publication Date: 2016.05.31 RGT UNIV OF CALIFORNIA
  • US9352963B2 patent drawing
  • US9352963B2 patent drawing
  • US9352963B2 patent drawing

AI summary

Among other things, methods, systems and apparatus are described for implementing nanomotor-based micro- and nanofabrication. In one aspect, a method of fabricating nanoobjects comprises functionalizing a nanomotor with a reagent. The method also includes controlling a movement of the functionalized nanomotor in a solution containing material to react with the reagent to induce a localized deposition or precipitation of a product onto a surface of a substrate or etching of the substrate.