Semiconductor Nanoparticle Agglomerate for Degradation Resistance

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Solution Overview

Problem

Semiconductor nanoparticles in existing networks are susceptible to degradation due to external influences like oxygen and water, leading to oxidation and reduced stability.

Innovation Solution

A semiconductor structure comprising discrete encapsulated nanoparticles with an encapsulation material, forming an agglomerate with discrete semiconductor free nanoparticles, providing additional protection through point-to-point connections and a concentration gradient that shields encapsulated nanoparticles from degradation.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If semiconductor nanoparticles are used in networks with fused insulator coatings, then wavelength conversion capability is achieved, but the nanoparticles are susceptible to degradation from external influences like oxygen and water

Engineering Contradiction:
Improvestability of semiconductor nanoparticlesVSAvoidexposure to oxygen and water
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies nested protection by placing semiconductor nanoparticles inside semiconductor-free nanoparticles, which are in turn enclosed within an insulator coating network. This multi-layer nesting structure creates progressive barriers that shield the core semiconductor nanoparticles from harmful external factors like oxygen and water, significantly improving their stability and reliability.

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

The patent introduces semiconductor-free nanoparticles as intermediary protective layers between the semiconductor nanoparticles and the external environment. These intermediary nanoparticles act as buffers that prevent direct contact between the harmful external factors and the sensitive semiconductor material, thereby reducing degradation.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Productivity

If semiconductor nanoparticles are thinly coated in existing networks, then wavelength conversion is enabled, but the particles remain exposed and vulnerable to oxidation

Engineering Contradiction:
Improvewavelength conversion efficiencyVSAvoidresistance to oxidation
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent implements a nested structure where semiconductor nanoparticles are placed inside semiconductor-free nanoparticles, which are then embedded in an insulator coating network. This nested arrangement provides thick, multi-layer protection without compromising the wavelength conversion efficiency of the core semiconductor particles, as the protective layers are transparent to the relevant electromagnetic radiation.

Inventive Principle:
Principle #7Nested doll (Nesting)

Solution Approach 2:

The patent creates a composite structure combining semiconductor nanoparticles, semiconductor-free nanoparticles, and insulator coating materials. This composite material system integrates the functional properties of semiconductor wavelength conversion with the protective properties of the insulator coating, achieving both high productivity and reliability.

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If semiconductor nanoparticles are placed on the outside and periphery of networks, then network formation is achieved, but the particles are left susceptible to degradation

Engineering Contradiction:
Improvenetwork formation capabilityVSAvoidexposure to external environment
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

The patent inverts the conventional approach by placing semiconductor-free nanoparticles (without the harmful semiconductor material) on the outside and periphery of the network structure, while enclosing the valuable semiconductor nanoparticles inside. This inversion maintains the network formation capability and peripheral particle distribution for ease of manufacture, but protects the sensitive semiconductor particles from external environmental factors.

Inventive Principle:
Principle #13The other way round (Inversion)

Solution Approach 2:

The patent uses semiconductor-free nanoparticles as intermediary protective elements positioned at the network periphery. These intermediary particles provide a protective barrier between the external environment and the internal semiconductor nanoparticles, reducing exposure to harmful factors while maintaining network integrity and manufacturability.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The semiconductor structure exhibits improved mechanical stability and enhanced protection against degradation, maintaining performance in harsh conditions such as high humidity and power usage.

Implementation Method 1

The encapsulation is provided, in particular, to protect the semiconductor nanoparticles from external influences like oxygen or water as these external influences can lead to an oxidation and therefore to a degradation of the semiconductor nanoparticles

Methodology Applied
Scientific EffectPhysical containment: Physical Containment

Implementation Method 2

the semiconductor nanoparticles may be used as a conversion material for converting the wavelength of electromagnetic radiation which passes through at least part of the conversion material

Methodology Applied
Scientific EffectWavelength conversion:

Implementation Method 3

wavelength converting materials absorb electromagnetic radiation of the incident radiation, convert the absorbed radiation at least partially in electromagnetic radiation of the second wavelength range

Methodology Applied
Scientific EffectAbsorption (EM radiation): Absorption (EM radiation)

Data Source

PatentUS11569421B2Semiconductor structure with nanoparticles and light emitting device having a phosphor material with nanoparticles
Publication Date: 2023.01.31 OSRAM OPTO SEMICON GMBH & CO OHG
  • US11569421B2 patent drawing
  • US11569421B2 patent drawing
  • US11569421B2 patent drawing

AI summary

A semiconductor structure, a method for producing a semiconductor structure and a light emitting device are disclosed. In an embodiment a semiconductor structure includes a plurality of discrete encapsulated semiconductor nanoparticles and a plurality of discrete semiconductor free nanoparticles, wherein the discrete encapsulated semiconductor nanoparticles and the discrete semiconductor free nanoparticles form an agglomerate.