Nanoparticle-Modified Alloy Powder for Crack-Resistant AM Microstructures

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Solution Overview

Problem

Additive manufacturing techniques face limitations in producing certain alloys due to dendritic solidification leading to columnar grain morphology and solidification cracking, which restricts the type of microstructures that can be formed, affecting mechanical and thermal properties.

Innovation Solution

A process involving a feedstock powder with nanoparticles attached to the base powder particles, allowing for varying energy input and scan speeds within a defined process window to produce different microstructures, such as columnar, equiaxed, or mixed microstructures, thereby expanding the capabilities of additive manufacturing systems.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional additive manufacturing processes are used with standard powder, then the process is simple and well-established, but the microstructure is limited to columnar grains which causes solidification cracking and reduces reliability

Engineering Contradiction:
Improvesolidification cracking resistanceVSAvoidprocess complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent modifies the powder parameters by attaching nanoparticles to base powder particles, changing the physical and chemical properties of the feedstock. This allows the material to form equiaxed grain microstructures instead of columnar grains, eliminating solidification cracking while maintaining process feasibility

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates a composite powder structure by combining base powder particles with surface-attached nanoparticles. This composite feedstock enables control over solidification behavior and microstructure formation, allowing production of crack-free components with improved reliability

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If the process window is expanded to produce different microstructures, then microstructure control and mechanical properties are improved, but the complexity of process parameter optimization increases

Engineering Contradiction:
Improvemicrostructure controlVSAvoidprocess parameter complexity
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent systematically varies process parameters including laser power, scan speed, and nanoparticle concentration to map out an expanded process window. This enables selective production of different microstructures (columnar, equiaxed, mixed) based on desired mechanical properties, providing adaptability while establishing clear parameter guidelines

Inventive Principle:
Principle #35Parameter changes

3Use of energy by moving object

If nanoparticles are attached to base powder particles, then reflectivity and thermal conductivity are modified to improve energy absorption, but the powder preparation complexity increases

Engineering Contradiction:
Improvelaser energy absorptionVSAvoidpowder preparation complexity
Core Design Contradiction:
Use of energy by moving objectVSDevice complexity

Solution Approach 1:

The patent creates composite powder particles with base powder and surface-attached nanoparticles, where the nanoparticle layer modifies optical and thermal properties. This enhances laser energy absorption and controls heat distribution during additive manufacturing, improving process efficiency despite additional powder preparation steps

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the production of metal alloy components with desired microstructures, reducing cracking issues and enhancing mechanical properties by modifying the reflectivity and thermal conductivity of the powder, thus expanding the process window and utility of additive manufacturing systems.

Implementation Method 1

modifying the reflectivity and thermal conductivity of the powder

Methodology Applied
Scientific EffectReflectivity modification: Reflection

Implementation Method 2

exposing the feedstock powder to a predetermined power input from the laser power source

Methodology Applied
Scientific EffectLaser energy absorption: Absorption (EM radiation)

Implementation Method 3

providing an additive manufacturing system with a laser power source

Methodology Applied
Scientific EffectLaser heating: Laser

Implementation Method 4

fusing particulate to the underlying layer as an integral layer, generally through application of a high energy input

Methodology Applied
Scientific EffectThermal melting: Melting

Implementation Method 5

the adverse way in which they solidify from the molten state

Methodology Applied
Scientific EffectSolidification: Crystallisation

Implementation Method 6

Dendritic solidification that is typical for complex alloys can result in columnar grain morphology

Methodology Applied
Scientific EffectDendritic solidification:

Implementation Method 7

modifying the reflectivity and thermal conductivity of the powder

Methodology Applied
Scientific EffectThermal conductivity modification: Conduction (thermal)

Data Source

PatentUS11602791B2Method for additive manufacturing with modified powder
Publication Date: 2023.03.14 RTX CORP
  • US11602791B2 patent drawing
  • US11602791B2 patent drawing
  • US11602791B2 patent drawing

AI summary

A process for additive manufacturing of a metal alloy material is provided that includes: a) providing a feedstock powder comprising base powder particles with nanoparticles attached to surfaces of the base powder particles; b) providing an additive manufacturing system with a laser power source relatively movable at a scan speed; c) wherein the additive manufacturing system has a process window for the feedstock powder; and d) exposing the feedstock powder to a predetermined power input from the laser power source at a predetermined scan speed to produce the metal alloy material. The concentration by volume of nanoparticles within the feedstock powder is such that independent first and second microstructures may be produced within the metal alloy material.