Nanoparticle Bonding for Low-Temperature Flip-Chip Joints

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

The challenge in microelectronic packaging is the difficulty in achieving uniform and reliable flip-chip interconnections due to the reduced volume of solder, which can lead to brittle inter-metallic compounds and increased risk of joint failure, especially with high contact density and differential thermal expansion between chip and substrate.

Innovation Solution

The method involves forming conductive nanoparticles on the surfaces of conductive elements using electroless or electrolytic plating, allowing for metallurgical joints to form at lower temperatures, which compensates for non-coplanarity and accommodates thermal expansion differences between components.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Quantity of substance

If solder volume is reduced to accommodate high contact density, then contact density is improved, but joint reliability deteriorates due to formation of brittle inter-metallic compounds

Engineering Contradiction:
Improvecontact densityVSAvoidjoint reliability
Core Design Contradiction:
Quantity of substanceVSReliability

Solution Approach 1:

The patent changes the material parameters by replacing traditional solder with nanoparticle-based conductive paste, altering the physical and chemical properties of the bonding material to achieve both high contact density and joint reliability through controlled nanoparticle sintering

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses composite materials by combining nanoparticles with organic vehicles and additives to create a conductive paste that provides both mechanical compliance for high-density contacts and controlled metallurgical bonding for reliable joints

Inventive Principle:
Principle #40Composite materials

2Volume of moving object

If stand-off height is reduced to minimize package size, then package size is improved, but thermal expansion compensation capability deteriorates

Engineering Contradiction:
Improvepackage sizeVSAvoidthermal expansion compensation
Core Design Contradiction:
Volume of moving objectVSAdaptability or versatility

Solution Approach 1:

The patent employs a flexible organic vehicle matrix that can deform and accommodate differential thermal expansion between chip and substrate, providing compliance without requiring large stand-off heights

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent changes the mechanical properties of the bonding material by using nanoparticle paste with controlled rheology and compliance characteristics, enabling thermal expansion compensation at reduced stand-off heights

Inventive Principle:
Principle #35Parameter changes

3Ease of manufacture

If traditional soldering process is used, then manufacturing process is simple, but thermal stress on components is high

Engineering Contradiction:
Improveprocess simplicityVSAvoidthermal stress
Core Design Contradiction:
Ease of manufactureVSTemperature

Solution Approach 1:

The patent changes the bonding mechanism from high-temperature solder melting to low-temperature nanoparticle sintering, reducing the processing temperature from typical solder melting points (>180°C) to below 150°C while maintaining joint integrity

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent utilizes controlled phase transitions of nanoparticles during sintering, where controlled heating activates diffusion and bonding mechanisms at lower temperatures compared to traditional solder melting

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the formation of reliable and uniform metallurgical joints with reduced thermal stress, improving the mechanical and electrical integrity of the connections while reducing fabrication costs and complexity.

Implementation Method 1

forming conductive nanoparticles on the surfaces of conductive elements using electroless or electrolytic plating

Methodology Applied
Scientific EffectElectroless plating: Electroplating

Implementation Method 2

forming conductive nanoparticles on the surfaces of conductive elements using electroless or electrolytic plating

Methodology Applied
Scientific EffectElectrolytic plating: Electroplating

Implementation Method 3

elevating a temperature at least at interfaces of the juxtaposed first and second conductive elements to a joining temperature at which the conductive nanoparticles cause metallurgical joints to form

Methodology Applied
Scientific EffectMetallurgical joining: Diffusion Welding

Data Source

PatentUS11710718B2Structures and methods for low temperature bonding using nanoparticles
Publication Date: 2023.07.25 ADEIA SEMICON TECH LLC
  • US11710718B2 patent drawing
  • US11710718B2 patent drawing
  • US11710718B2 patent drawing

AI summary

A method of making an assembly can include juxtaposing a top surface of a first electrically conductive element at a first surface of a first substrate with a top surface of a second electrically conductive element at a major surface of a second substrate. One of: the top surface of the first conductive element can be recessed below the first surface, or the top surface of the second conductive element can be recessed below the major surface. Electrically conductive nanoparticles can be disposed between the top surfaces of the first and second conductive elements. The conductive nanoparticles can have long dimensions smaller than 100 nanometers. The method can also include elevating a temperature at least at interfaces of the juxtaposed first and second conductive elements to a joining temperature at which the conductive nanoparticles can cause metallurgical joints to form between the juxtaposed first and second conductive elements.