Nano-particle reinforced well cement for shear stress resistance

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Solution Overview

Problem

Well cement compositions face structural failure due to shear stresses from pipe movements and environmental conditions, leading to leakage and loss of bond integrity, and require accelerators to counteract excessive set times.

Innovation Solution

Incorporating particulate nano-silica, nano-alumina, nano-zinc oxide, or nano-iron oxide into well cement compositions to enhance mechanical properties and accelerate set times, with the option of encapsulating nano-particles for improved handling and timed release.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of operation

If conventional cement compositions are used to cement pipe strings in well bores, then the cement composition can be easily applied, but the cement sheath suffers structural failure due to shear stresses from pipe movements and environmental conditions

Engineering Contradiction:
Improveease of cement applicationVSAvoidstructural integrity of cement sheath
Core Design Contradiction:
Ease of operationVSReliability

Solution Approach 1:

The patent utilizes a composite material system consisting of cement matrix combined with steel fibers and micro-silica particles. This composite structure provides both the ease of application characteristics of conventional cement and the enhanced mechanical properties (tensile strength, flexural strength, and durability) needed to resist shear stresses and maintain structural integrity under thermal and mechanical loading conditions.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the chemical and physical parameters of the cement composition by incorporating specific ratios of steel fibers (0.5-2.0% by weight), micro-silica (5-20% by weight of cement), and adjusting water-cement ratios. These parameter changes enhance the cement's tensile strength, flexural strength, and resistance to thermal stress while maintaining workability and ease of placement.

Inventive Principle:
Principle #35Parameter changes

2Reliability

If the cement composition is designed to have high strength and resiliency to resist stress, then structural integrity is improved, but the formulation becomes more complex

Engineering Contradiction:
Improveresistance to shear stress and crackingVSAvoidcomplexity of cement formulation
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent achieves enhanced reliability through controlled parameter changes in the cement formulation, specifically optimizing the content ranges of steel fibers (0.5-2.0% by weight), micro-silica (5-20% by weight), and water-cement ratios. These quantified parameters provide a systematic approach to improving tensile strength, flexural strength, and stress resistance without requiring complex formulation development, as the effects are achieved through well-defined compositional adjustments.

Inventive Principle:
Principle #35Parameter changes

3Loss of time

If set accelerators are added to counteract excessive set times, then the set time is reduced, but the composition complexity increases and may affect other properties

Engineering Contradiction:
Improveset time of cementVSAvoidcomplexity of cement composition
Core Design Contradiction:
Loss of timeVSDevice complexity

Solution Approach 1:

The patent controls set time through parameter optimization of the base cement composition, water-cement ratio, and temperature conditions rather than relying on set accelerators. The micro-silica and fiber reinforcements also influence setting characteristics, allowing for balanced control of set time while maintaining composition simplicity and avoiding the need for additional chemical additives that would increase formulation complexity.

Inventive Principle:
Principle #35Parameter changes

Data Source

PatentUS7892352B2Well treatment compositions and methods utilizing nano-particles
Publication Date: 2011.02.22 HALLIBURTON ENERGY SERVICES INC

AI summary

Disclosed embodiments relate to well treatment fluids and methods that utilize nano-particles. Exemplary nano-particles are selected from the group consisting of particulate nano-silica, nano-alumina, nano-zinc oxide, nano-boron, nano-iron oxide, and combinations thereof. Embodiments also relate to methods of cementing that include the use of nano-particles. An exemplary method of cementing comprises introducing a cement composition into a subterranean formation, wherein the cement composition comprises cement, water and a particulate nano-silica. Embodiments also relate to use of nano-particles in drilling fluids, completion fluids, simulation fluids, and well clean-up fluids.