Nano-particle Well Cement Compositions for Shear Stress Resistance

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Solution Overview

Problem

Well cement compositions face structural failure due to shear stresses from high fluid pressures and temperatures, leading to leakage and damage, and traditional completion fluids like brines are expensive, corrosive, and difficult to handle, causing environmental concerns.

Innovation Solution

Incorporating nano-particles such as nano-silica, nano-alumina, nano-zinc oxide, and nano-iron oxide into well cement compositions and completion fluids to enhance mechanical properties and reduce set time, while using encapsulation to facilitate transportation and timed release.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Strength

If traditional well cement compositions are used, then the cement can be easily manufactured and applied, but the cement suffers structural failure due to shear stresses from high fluid pressures and temperatures

Engineering Contradiction:
Improvecement strengthVSAvoidcement bond reliability
Core Design Contradiction:
StrengthVSReliability

Solution Approach 1:

The patent incorporates nano-particles (such as nano-silica, nano-alumina, nano-titanium dioxide) into traditional well cement compositions to create a composite material. This composite structure combines the binding properties of traditional cement with the enhanced mechanical strength and stress resistance of nano-particles, allowing the cement to withstand shear stresses from high fluid pressures and temperatures while maintaining manufacturability

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent modifies the physical and chemical parameters of the cement composition by adding nano-particles with specific size ranges (1-100 nanometers). These parameter changes at the nanoscale level enhance the cement's compressive strength, tensile strength, and elasticity, enabling it to resist structural failure under extreme well conditions while preserving ease of manufacture and application

Inventive Principle:
Principle #35Parameter changes

2Productivity

If traditional completion fluids like brines are used, then the fluids can effectively complete the well, but they are expensive, corrosive, and difficult to handle

Engineering Contradiction:
Improvewell completion effectivenessVSAvoidfluid handling ease
Core Design Contradiction:
ProductivityVSEase of operation

Solution Approach 1:

The patent alters the chemical composition parameters of completion fluids by incorporating nano-particles and using alternative formulations that eliminate or reduce corrosive brines. These parameter changes maintain the fluid's ability to effectively complete the well while significantly improving handling ease, reducing corrosion, and lowering costs through the use of nanotechnology-enhanced fluid properties

Inventive Principle:
Principle #35Parameter changes

3Strength

If nano-particles are incorporated into cement compositions, then the cement develops high strength and resiliency, but the composition complexity increases

Engineering Contradiction:
Improvecement strengthVSAvoidcement composition complexity
Core Design Contradiction:
StrengthVSDevice complexity

Solution Approach 1:

The patent applies the local quality principle by incorporating nano-particles specifically in regions where strength enhancement is most needed, such as at the interface between the cement sheath and pipe or formation. This localized enhancement achieves high strength and resiliency without requiring uniform complexity throughout the entire cement composition, maintaining relative simplicity in manufacturing and application procedures

Inventive Principle:
Principle #3Local quality

Data Source

PatentUS9199879B2Well treatment compositions and methods utilizing nano-particles
Publication Date: 2015.12.01 HALLIBURTON ENERGY SERVICES INC

AI summary

Disclosed embodiments relate to well treatment fluids and methods that utilize nano-particles. Exemplary nano-particles are selected from the group consisting of particulate nano-silica, nano-alumina, nano-zinc oxide, nano-boron, nano-iron oxide, and combinations thereof. Embodiments also relate to methods of cementing that include the use of nano-particles. An exemplary method of cementing comprises introducing a cement composition into a subterranean formation, wherein the cement composition comprises cement, water and a particulate nano-silica. Embodiments also relate to use of nano-particles in drilling fluids, completion fluids, simulation fluids, and well clean-up fluids.