Nanoparticle-Coated Phase Change Material Particles for Heat Storage

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Solution Overview

Problem

Existing phase change materials (PCMs) in microencapsulated form face challenges such as leakage due to thin encapsulating layers, reduced thermal conductivity, and increased production costs, as well as difficulties in handling and transporting due to high friction and limited gas flow for heating and cooling.

Innovation Solution

A method and device for storing heat using particles comprising a core of phase change material coated with an outer layer of smaller particles, where the particles have a largest size of 1-1000 μm and the smaller particles have a largest size of 1-500 nm, comprising materials like graphite, graphite oxide, graphene, or graphene oxide, which improves heat conduction and reduces leakage risks.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If microencapsulated phase change materials are used with thin encapsulating layers, then heat transfer is improved, but leakage risk increases

Engineering Contradiction:
Improveheat transfer efficiencyVSAvoidleakage resistance
Core Design Contradiction:
TemperatureVSReliability

Solution Approach 1:

The patent uses a composite structure where the phase change material core is coated with hydrophobic nanoparticles. This composite approach provides both good heat transfer properties and effective leakage prevention, as the nanoparticle coating acts as a barrier while maintaining thermal conductivity.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The encapsulating layer has different properties at different locations: the outer surface provides leakage protection through hydrophobic nanoparticle packing, while the inner surface maintains good thermal contact with the phase change material core. This local differentiation resolves the contradiction between heat transfer and leakage resistance.

Inventive Principle:
Principle #3Local quality

2Ease of operation

If conventional microencapsulated PCMs are used, then portability is improved, but thermal conductivity is reduced

Engineering Contradiction:
ImproveportabilityVSAvoidthermal conductivity
Core Design Contradiction:
Ease of operationVSTemperature

Solution Approach 1:

The patent incorporates hydrophobic nanoparticles into the encapsulating layer, creating a composite material that combines the portability benefits of microencapsulation with enhanced thermal conductivity. The nanoparticles act as thermal conductive pathways while maintaining the physical containment benefits.

Inventive Principle:
Principle #40Composite materials

3Temperature

If nanoparticles are used to improve thermal conductivity, then heat conduction is enhanced, but production cost increases

Engineering Contradiction:
Improvethermal conductivityVSAvoidproduction cost
Core Design Contradiction:
TemperatureVSEase of manufacture

Solution Approach 1:

The patent optimizes the nanoparticle size parameters and concentration in the coating layer to achieve effective thermal conductivity enhancement at lower costs. By controlling nanoparticle dimensions in the nanometer range and adjusting coating thickness, the system achieves performance improvement without excessive material costs.

Inventive Principle:
Principle #35Parameter changes

4Quantity of substance

If phase change material particles are used for heat storage, then energy storage capacity is improved, but friction during handling increases

Engineering Contradiction:
Improveenergy storage capacityVSAvoidhandling ease
Core Design Contradiction:
Quantity of substanceVSEase of operation

Solution Approach 1:

The outer surface of the particles is coated with hydrophobic nanoparticles that provide low friction properties, while the inner core maintains high energy storage capacity through phase change material. This local differentiation allows easy handling without compromising energy storage performance.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The solution enhances heat conduction between the phase change material and its surroundings, reduces the risk of leakage, lowers production costs, and facilitates easier handling and transport due to reduced friction and increased gas flow for efficient heating and cooling.

Implementation Method 1

a method of storing heat energy in a phase change material

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

storing heat energy in a phase change material

Methodology Applied
Scientific EffectLatent heat: Latent Heat

Implementation Method 3

improves heat conduction between the phase change material and its surroundings

Methodology Applied
Scientific EffectHeat conduction: Conduction (thermal)

Data Source

PatentUS12320594B2Heat storage using phase change material coated with nanoparticles
Publication Date: 2025.06.03 SALTX TECH AB

AI summary

There is provided a method for heat storage comprising charging by raising the temperature of a phase change material (PCM) above its melting temperature and discharging by lowering the temperature below its melting temperature, wherein the phase change material (PCM) is provided in particles (P) comprising a core (CPCM), said core (CPCM) comprising at least one phase change material (PCM), said core (CPCM) being coated with an outer layer (LPSMALL) of smaller particles (PSMALL) comprising at least one from graphite, graphite oxide, graphene, and graphene oxide. The particles (P) can be made smaller giving an efficient heat exchange. Their manufacture is easy and cost efficient. The flexible outer layer allows the core to expand and shrink. Corrosion is prevented allowing less expensive materials to be used in devices. The particles can be made self-lubricating.