Gradient Nanoparticle Composite Coating for Shock Wave Attenuation

Resolve Bottlenecks,
Find Innovative Solutions
Generate Solutions

Solution Overview

Problem

Existing materials for mitigating shock waves, such as woven fabrics and ceramic composites, primarily rely on absorption by high mass materials, which only partially reduce the wave's amplitude and can still cause significant damage.

Innovation Solution

A shock wave attenuating material comprising a substrate layer with alternating gradient nanoparticle layers and graphitic layers, where nanoparticles of varying diameters are arranged in a gradient and carbon allotropes are suspended in a matrix, creating destructive interference to significantly reduce shock wave energy.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Object-affected harmful factors

If high mass material is used to absorb shock wave energy, then shock wave amplitude is reduced, but the material weight increases and damage is still considerable

Engineering Contradiction:
Improveshock wave amplitudeVSAvoidmaterial weight
Core Design Contradiction:
Object-affected harmful factorsVSWeight of moving object

Solution Approach 1:

The patent employs a composite material system consisting of multiple layers including gradient nanoparticle layers (with particles of varying sizes from 1-100 nm), graphitic carbon layers, polymer matrices, and ceramic components. This multi-component composite structure achieves superior shock wave attenuation through the synergistic interaction of different materials, reducing reliance on single high-mass materials while maintaining protective effectiveness.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The gradient nanoparticle layers feature a deliberate spatial variation in particle size distribution, where smaller nanoparticles (1-10 nm) are positioned in certain regions and larger particles (10-100 nm) in others, creating a gradient structure. This local quality variation optimizes energy dissipation at different depths of material penetration, allowing effective shock wave attenuation with reduced overall material mass compared to uniform high-mass structures.

Inventive Principle:
Principle #3Local quality

2Object-affected harmful factors

If high mass material is used to absorb shock wave energy, then shock wave amplitude is reduced, but the material complexity increases

Engineering Contradiction:
Improveshock wave amplitudeVSAvoidmaterial structure complexity
Core Design Contradiction:
Object-affected harmful factorsVSDevice complexity

Solution Approach 1:

The protective material is segmented into distinct functional layers: gradient nanoparticle layers for initial shock wave interaction, graphitic carbon layers for energy dissipation through structural transformations, polymer matrices for binding and flexibility, and ceramic layers for hard protection. Each layer is optimized for specific shock wave attenuation mechanisms, creating a modular structure that manages complexity through functional specialization rather than requiring a monolithic complex material.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The polymer matrix serves as an intermediary material that binds the gradient nanoparticles, graphitic carbon structures, and ceramic components together. This intermediary phase facilitates the interaction between different material components, enabling coordinated shock wave attenuation while maintaining structural integrity and simplifying the overall material architecture compared to direct integration of disparate high-performance materials.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Object-affected harmful factors

If conventional materials are used for protection, then shock wave attenuation is achieved, but flexibility and transparency are lost

Engineering Contradiction:
Improveshock wave attenuationVSAvoidmaterial flexibility
Core Design Contradiction:
Object-affected harmful factorsVSEase of operation

Solution Approach 1:

The patent incorporates thin film structures of gradient nanoparticle layers and graphitic carbon layers deposited on flexible substrate materials. These thin film configurations maintain the flexibility of the underlying substrate while providing shock wave attenuation functionality. The nanoscale thickness of the protective layers (on the order of nanometers to micrometers) allows them to conform to flexible substrates without compromising the substrate's mechanical properties, enabling flexible protective applications.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent utilizes parameter changes at the nanoscale, particularly in the gradient nanoparticle layers where particle size, concentration, and distribution are precisely controlled. By adjusting these nanoscale parameters, the material achieves optimal shock wave attenuation while maintaining transparency in the visible spectrum and flexibility through appropriate polymer matrix selection. The nanoscale dimensions of particles (1-100 nm) are specifically chosen to be smaller than the wavelength of visible light, preserving transparency, and smaller than the scale at which they would compromise substrate flexibility.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The material achieves substantial reduction of shock wave energy through destructive interference, providing enhanced protection with a lightweight, flexible, and potentially transparent coating that maintains the treated material's flexibility.

Implementation Method 1

The high mass material absorbs some of the shock wave energy, thereby resulting in a shock wave of decreased amplitude

Methodology Applied
Scientific EffectShock wave absorption: Absorption (physical)

Implementation Method 2

A plurality of shock attenuating layers is disposed on the substrate layer. Each of the plurality of shock attenuating layers includes a gradient nanoparticle layer including a plurality of nanoparticles of different diameters that are arranged in a gradient from smallest diameter to largest diameter

Methodology Applied
Scientific EffectScattering: Scattering

Implementation Method 3

creating destructive interference to significantly reduce shock wave energy

Methodology Applied
Scientific EffectDestructive interference: Interference

Data Source

PatentUS10926513B2Gradient nanoparticle-carbon allotrope-polymer composite material
Publication Date: 2021.02.23 GREENHILL ANTIBALLISTICS CORP
  • US10926513B2 patent drawing
  • US10926513B2 patent drawing
  • US10926513B2 patent drawing

AI summary

A shock wave attenuating material (100) includes a substrate layer (104). A plurality (110) of shock attenuating layers is disposed on the substrate layer (104). Each of the plurality (110) of shock attenuating layers includes a gradient nanoparticle layer (114) including a plurality of nanoparticles (120) of different diameters that are arranged in a gradient from smallest diameter to largest diameter and a graphitic layer (118) disposed adjacent to the gradient nanoparticle layer. The graphitic layer (118) includes a plurality of carbon allotrope members (128) suspended in a matrix (124).