Nanoparticle-Enhanced Ionic Liquid Heat Transfer Fluids

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Solution Overview

Problem

Conventional heat transfer fluids, such as water and ethylene glycol, lack high thermal conductivity, heat capacity, stability at high temperatures, low volatility, and compatibility with modern heat exchange systems, limiting their efficiency and capacity in heat exchange processes.

Innovation Solution

A heat transfer fluid comprising nanoparticles, specifically inorganic metal oxides, dispersed in an ionic liquid carrier, which enhances thermal conductivity and heat capacity while maintaining stability and compatibility with materials like stainless steel and aluminum.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional heat transfer fluids (water, ethylene glycol) are used, then the system is simple and compatible with existing materials, but the thermal conductivity and heat capacity are insufficient

Engineering Contradiction:
Improvethermal conductivityVSAvoidfluid composition complexity
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies composite materials by dispersing nanoparticles (such as metal oxides, carbon nanotubes, or graphite) into conventional heat transfer fluids like ethylene glycol or water-ethylene glycol mixtures. This creates a nanofluid composite that combines the base fluid's compatibility and flow properties with the nanoparticles' high thermal conductivity, thereby enhancing overall heat transfer performance while maintaining system compatibility

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the physical parameters of the heat transfer fluid by introducing nanoparticles with specific properties (high thermal conductivity, small size). This parameter change at the nanoscale level transforms the bulk fluid's thermal properties, allowing achievement of higher thermal conductivity and heat capacity without fundamentally changing the base fluid composition

Inventive Principle:
Principle #35Parameter changes

2Productivity

If the velocity of heat transfer fluid is increased to improve heat exchange efficiency, then heat transfer capacity improves, but operating expense increases

Engineering Contradiction:
Improveheat exchange efficiencyVSAvoidoperating expense
Core Design Contradiction:
ProductivityVSLoss of energy

Solution Approach 1:

Instead of changing the flow velocity parameter, the patent changes the thermal properties parameters of the fluid itself by adding nanoparticles. This allows achieving higher heat exchange efficiency through improved thermal conductivity and heat capacity of the fluid, rather than through increased flow rate, thereby avoiding the energy penalty associated with higher pumping power

Inventive Principle:
Principle #35Parameter changes

3Productivity

If the surface area for heat transfer is increased, then heat exchange capacity improves, but equipment expense increases

Engineering Contradiction:
Improveheat exchange capacityVSAvoidequipment cost
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent changes the thermal properties parameters of the existing heat transfer fluid by dispersing nanoparticles throughout the fluid. This enhances the fluid's intrinsic heat transfer capability, allowing existing heat exchanger surface areas to achieve higher heat exchange capacity without requiring additional equipment or surface area expansion

Inventive Principle:
Principle #35Parameter changes

4Reliability

If heat transfer fluid thermal conductivity is increased, then heat exchange efficiency improves, but fluid stability at high temperatures may be compromised

Engineering Contradiction:
Improvethermal conductivityVSAvoidthermal stability
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent uses conventional, well-understood base fluids (water, ethylene glycol) that have proven thermal stability, and adds small quantities of nanoparticles. The base fluid acts as a stable carrier that maintains system compatibility and thermal stability, while the nanoparticles provide the thermal conductivity enhancement. This approach leverages the stability of simple, well-characterized materials

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The composite nanofluid structure allows separation of functions: the base fluid provides thermal stability and compatibility, while the nanoparticles provide thermal conductivity enhancement. This functional division in the composite material system resolves the contradiction by allowing each component to optimize for its strength

Inventive Principle:
Principle #40Composite materials

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The nanoparticle-enhanced ionic liquids (NEILs) demonstrate improved thermal conductivity, heat capacity, and stability at high temperatures, with low viscosity and vapor pressure, effectively addressing the limitations of conventional heat transfer fluids.

Implementation Method 1

heat transfer fluids are necessary to a wide variety of processes as a means of cooling and/or heating by the transfer of energy using both thermal conduction with the fluid

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

movement of the fluid between a heat source and a heat sink

Methodology Applied
Scientific EffectConvection: Convection

Implementation Method 3

The nanoparticle-enhanced ionic liquids (NEILs) demonstrate improved thermal conductivity, heat capacity, and stability at high temperatures

Methodology Applied
Scientific EffectHeat capacity: Thermal Energy Storage

Implementation Method 4

The ionic liquid can include a cation selected from a heterocyclic compound having at least one positively charged nitrogen in its ring

Methodology Applied
Scientific EffectVapor pressure reduction: Vapour Pressure

Data Source

PatentUS8801957B2Nanoparticle enhanced ionic liquid heat transfer fluids
Publication Date: 2014.08.12 BATTELLE SAVANNAH RIVER ALLIANCE LLC
  • US8801957B2 patent drawing
  • US8801957B2 patent drawing
  • US8801957B2 patent drawing

AI summary

A heat transfer fluid created from nanoparticles that are dispersed into an ionic liquid is provided. Small volumes of nanoparticles are created from e.g., metals or metal oxides and/or alloys of such materials are dispersed into ionic liquids to create a heat transfer fluid. The nanoparticles can be dispersed directly into the ionic liquid during nanoparticle formation or the nanoparticles can be formed and then, in a subsequent step, dispersed into the ionic liquid using e.g., agitation.