Nanoparticle-Modified Heat Transfer Fluid for Controlled Cooling

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Solution Overview

Problem

Existing methods for heat transfer in metal and non-metallic items, such as in steel making, often result in either too rapid or uncontrolled cooling, which can lead to undesirable microstructures and increased costs due to the difficulty in handling gas bubble-water mixed fluids or the inefficiency of polymeric quenchants.

Innovation Solution

A method utilizing heat transfer fluids with nanoparticles, such as graphite nanoplatelets or graphene, in specific concentrations and with dispersing agents, to achieve controlled heat transfer coefficients below or above that of water, allowing for slow and controlled cooling by adjusting the flow regime to laminar or turbulent.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Speed

If gas bubble-water mixed fluid is used for controlled cooling, then cooling rate can be reduced, but the fluid becomes difficult to handle and costs increase

Engineering Contradiction:
Improvecooling rateVSAvoidease of handling fluid
Core Design Contradiction:
SpeedVSEase of operation

Solution Approach 1:

The invention extracts the gas bubbles from the mixture and replaces them with solid nanoparticles (graphite, carbon black, or metal oxides) dispersed in the liquid quenchant. This removes the handling difficulties associated with gas-liquid mixtures while maintaining the reduced thermal conductivity effect that enables controlled cooling rates.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The invention changes the physical state of the heat transfer modification agent from gaseous (gas bubbles) to solid (nanoparticles). This parameter change maintains the ability to reduce thermal conductivity for controlled cooling while eliminating the operational difficulties of handling gas-liquid mixtures in industrial settings.

Inventive Principle:
Principle #35Parameter changes

2Speed

If polymeric quenchant is used to slow cooling, then cooling rate is reduced, but the method is less cost-effective and harder to handle

Engineering Contradiction:
Improvecooling rateVSAvoidcost-effectiveness
Core Design Contradiction:
SpeedVSEase of manufacture

Solution Approach 1:

The invention uses inexpensive inorganic nanoparticles (graphite, carbon black, metal oxides) as heat transfer modifiers instead of expensive polymeric quenchants. These nanoparticles can be easily dispersed in conventional liquid quenchants, providing cost-effective controlled cooling without the handling difficulties of polymeric systems.

Inventive Principle:
Principle #27Cheap short-living objects (Disposable)

Solution Approach 2:

The invention creates a composite heat transfer fluid by dispersing inorganic nanoparticles in a liquid quenchant base. This composite approach combines the low cost and ease of handling of conventional liquid quenchants with the thermal conductivity reduction effect of the nanoparticle dispersion, achieving controlled cooling at lower cost than polymeric alternatives.

Inventive Principle:
Principle #40Composite materials

3Reliability

If conventional heat transfer fluid is used, then heat transfer coefficient is high, but cooling is too rapid causing undesirable microstructures

Engineering Contradiction:
Improvemicrostructure qualityVSAvoidcooling rate
Core Design Contradiction:
ReliabilityVSSpeed

Solution Approach 1:

The invention changes the thermal conductivity parameter of the heat transfer fluid by adding nanoparticles with low thermal conductivity (graphite, carbon black, metal oxides). This parameter change reduces the heat transfer coefficient from the high values characteristic of conventional fluids to a range that enables controlled cooling rates for achieving desired microstructures.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The invention modifies the local thermal properties of the heat transfer fluid by dispersing nanoparticle particles throughout the liquid. This creates a non-uniform thermal conductivity distribution at the microscopic level, where the nanoparticle-laden fluid provides reduced thermal conductivity at the fluid-item interface, enabling controlled heat transfer while maintaining bulk fluid properties.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables controlled cooling rates, reducing thermal conductivity by up to 75% compared to water, allowing for the attainment of desired microstructures and mechanical properties while being more cost-effective and easier to handle than traditional methods.

Implementation Method 1

the heat transfer can be slow and controlled... reducing thermal conductivity by up to 75% compared to water

Methodology Applied
Scientific EffectThermal conduction: Conduction (thermal)

Implementation Method 2

heat transfer fluids having a heat transfer coefficient below the heat transfer coefficient of water... reducing thermal conductivity by up to 75%

Methodology Applied
Scientific EffectThermal insulation: Thermal Insulation

Implementation Method 3

heat transfer between a metallic or non-metallic item and a heat transfer fluid... allowing for slow and controlled cooling

Methodology Applied
Scientific EffectConvection: Convection

Data Source

PatentEP3394203B1A method of a heat transfer of a non-metallic or metallic item
Publication Date: 2021.10.13 ARCELORMITTAL SA
  • EP3394203B1 patent drawingFigure 1~2
  • EP3394203B1 patent drawingFigure 3~4
  • EP3394203B1 patent drawing

AI summary

The present invention relates to a method of heat treatment of non-metallic or metallic item comprising at least one step A) of heat transfer between the item and a heat transfer fluid A' comprising a fluid medium and nanoparticles having a lateral size of the nanoparticles is between 26 and 50μm, the heat transfer fluid having a heat transfer coefficient below the heat transfer coefficient of water.