Self-Assembled Metallic Nanoparticle Microstructure for Surface Plasmon Generation

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Solution Overview

Problem

Conventional methods for generating surface plasmon waves are expensive and time-consuming, and they cannot simultaneously produce Surface Plasmon Polaritons (SPP) and Localized Surface Plasmon (LSP) in an identical systematic structure, limiting the design and efficiency of surface plasmon generation structures.

Innovation Solution

A method using self-assembly to form a microstructure with a discontinuous surface, employing metallic nanoparticles in a carrier material to create two-dimensional hexagonal close-packed structures, which eliminates the need for costly Chemical Vapor Deposition (CVD) and allows for the generation of 3D complex surface plasmon waves by forming both SPP and LSP in a coupled resonance mode.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional methods (CVD, sputtering, photo masks, etching) are used to fabricate metallic nanostructures, then surface plasmon waves can be generated, but the fabrication process becomes expensive and time-consuming

Engineering Contradiction:
Improvesurface plasmon wave generationVSAvoidfabrication time
Core Design Contradiction:
ReliabilityVSLoss of time

Solution Approach 1:

The patent employs self-assembly of metallic nanoparticles to form the microstructure that generates surface plasmon waves. The nanoparticles automatically organize themselves into ordered arrays through natural forces (van der Waals forces, capillary forces, evaporation dynamics) without requiring external intervention for positioning, eliminating the need for expensive and time-consuming lithography and etching processes

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent replaces mechanical fabrication methods (photo masks, etching, sputtering) with a chemical/physical self-assembly process. Instead of using mechanical tools to deposit and pattern metals, the system uses solution-based nanoparticle deposition followed by self-organization, substituting complex mechanical manufacturing with a simpler wet chemical process

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

2Reliability

If conventional methods are used to fabricate metallic nanostructures, then surface plasmon waves can be generated, but the fabrication cost increases

Engineering Contradiction:
Improvesurface plasmon wave generationVSAvoidfabrication cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The self-assembly process eliminates the need for expensive cleanroom equipment, photolithography tools, and complex deposition systems. The metallic nanoparticles self-organize into functional structures through simple evaporation of the carrier liquid, reducing fabrication costs while maintaining reliable surface plasmon wave generation

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The patent changes the fabrication approach from high-vacuum, high-energy physical deposition to low-cost solution-based deposition. By controlling parameters such as nanoparticle concentration, carrier liquid properties, and evaporation conditions, the system achieves reliable nanostructure formation using inexpensive materials and equipment

Inventive Principle:
Principle #35Parameter changes

3Adaptability or versatility

If conventional fabrication methods are used, then metallic nanostructures can be formed, but they cannot simultaneously produce both SPP and LSP in an identical systematic structure

Engineering Contradiction:
Improvesurface plasmon generation capabilityVSAvoidstructure design flexibility
Core Design Contradiction:
Adaptability or versatilityVSDevice complexity

Solution Approach 1:

The patent creates a universal microstructure platform where metallic nanoparticles serve multiple functions simultaneously. The same nanoparticle array structure supports both Surface Plasmon Polaritons (SPP) at the substrate interface and Localized Surface Plasmons (LSP) at the nanoparticle surfaces, enabling dual plasmon generation without requiring separate structures

Inventive Principle:
Principle #6Universality (Multi-functionality)

Solution Approach 2:

The patent transitions from planar 2D metallic patterns to 3D nanoparticle assemblies with vertical dimensionality. This three-dimensional arrangement allows simultaneous excitation of SPP modes at the substrate-nanoparticle interface and LSP modes within the nanoparticles themselves, providing versatility in plasmon generation that conventional 2D structures cannot achieve

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces fabrication costs and time while enhancing the efficiency of surface plasmon wave generation, improving light emitting efficiency in LEDs and photoelectric conversion efficiency in solar cells by effectively coupling and converting light energy.

Implementation Method 1

using a carrier material to carry a plurality of metallic nanoparticles and letting the metallic nanoparticles undertake self-assembly to form a microstructure on the substrate

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Implementation Method 2

it can generate an interaction between electromagnetic waves and the metallic nanostructure and result in many novel optical characteristic

Methodology Applied
Scientific EffectSurface plasmon resonance: Resonance

Data Source

PatentEP2860152B1Method for fabricating microstructure to generate surface plasmon waves
Publication Date: 2017.03.22 TSUNG CHENG SHENG
  • EP2860152B1 patent drawing
  • EP2860152B1 patent drawing
  • EP2860152B1 patent drawing

AI summary

A method for fabricating a microstructure to generate surface plasmon waves comprises steps of: (S1) preparing a substrate (10), and (S2) using a carrier material (22) to carry a plurality of metallic nanoparticles (21) and letting the metallic nanoparticles (21) undertake self-assembly to form a microstructure on the substrate (10), wherein the metallic nanoparticles (21) are separated from each other or partially agglomerated to allow the microstructure to be formed with a discontinuous surface. The present invention fabricates the microstructure having the discontinuous surface by a self-assembly method to generate the surface plasmon waves, thus exempts from using the expensive chemical vapor deposition (CVD) technology and is able to reduce the time and cost of fabrication. The present invention also breaks the structural limitation on generation of surface plasmon waves to enhance the effect of generating the surface plasmon waves.