Nanoparticle-Immobilized Substrates for Precise Diamond Film Seeding

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Solution Overview

Problem

Existing methods for arranging inorganic nanoparticles on substrates are complex and inefficient, particularly in achieving precise nanometer-scale placement, which is necessary for advanced nanodevices like thermoelectric conversion devices and solar cells.

Innovation Solution

A particle-immobilized substrate is created by disposing inorganic nanoparticles, such as nanodiamond particles, in regions with a width of 1 μm or less on a substrate, utilizing a potential difference in zeta potential to facilitate electrostatic attachment, allowing for regular arrangement and easy production of diamond-film-immobilized substrates through chemical vapor deposition.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If inorganic nanoparticles are attached to a nanometer-scale region on a substrate surface, then the precision of nanoparticle placement is improved, but the complexity of the production process increases

Engineering Contradiction:
Improvenanoparticle placement precisionVSAvoidproduction process complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent uses polymer chains as an intermediary substance to attach inorganic nanoparticles to the substrate. The polymer chains serve as a mediating layer that simplifies the attachment process while achieving precise nanometer-scale placement. This resolves the contradiction by providing a straightforward method (using polymer mediators) to achieve high precision without complicating the production process.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent applies polymer chains to the substrate surface before attaching the inorganic nanoparticles. This preliminary action of coating the substrate with polymer chains creates a prepared surface that naturally attracts and holds the nanoparticles in desired positions, thereby achieving precise placement through a simplified two-step process rather than complex direct positioning methods.

Inventive Principle:
Principle #10Preliminary action

2Ease of operation

If polymer chains are used to attach inorganic nanoparticles to the substrate, then the ease of nanoparticle arrangement is improved, but the production process becomes more complex due to additional steps

Engineering Contradiction:
Improvenanoparticle arrangement easeVSAvoidproduction process complexity
Core Design Contradiction:
Ease of operationVSDevice complexity

Solution Approach 1:

The patent combines the functions of substrate preparation and nanoparticle attachment into a single integrated process. By applying polymer chains that serve both as adhesive and positioning agent, the method merges multiple functions into one material system, making the arrangement process easier while actually simplifying rather than complicating the overall production process.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The polymer chains on the substrate surface automatically attract and position the inorganic nanoparticles without requiring additional complex positioning mechanisms. The nanoparticles self-organize on the polymer-coated surface, making the arrangement process intuitive and easy to perform while maintaining simplicity in the production workflow.

Inventive Principle:
Principle #25Self-service

3Adaptability or versatility

If inorganic nanoparticles are arranged in a nanometer-scale region, then the applicability to nanodevices is improved, but the difficulty of production increases

Engineering Contradiction:
Improvenanodevice applicabilityVSAvoidproduction ease
Core Design Contradiction:
Adaptability or versatilityVSEase of manufacture

Solution Approach 1:

The patent changes the key parameter of substrate surface properties by coating it with polymer chains. This parameter change enables the substrate to accommodate nanometer-scale nanoparticle arrangements required for nanodevices, while the method itself remains simple and easy to manufacture. The polymer coating transforms the substrate into a nanodevice-compatible platform without complicating production.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the easy production of substrates with nanoparticles arranged in nanometer-scale regions, simplifying the production process and allowing for the formation of diamond films in specific areas, enhancing the application of these substrates in semiconductor devices.

Implementation Method 1

a potential difference between a zeta potential of the inorganic nanoparticles and a zeta potential of a surface of the substrate at a position where the inorganic nanoparticles are disposed is 30 mV or more

Methodology Applied
Scientific EffectElectrostatic interaction: Electrostatics

Data Source

PatentUS20240124314A1Particle-immobilized substrate, method for producing particle-immobilized substrate, method for producing diamond-film-immobilized substrate, and method for producing diamond
Publication Date: 2024.04.18 DAICEL CORP
  • US20240124314A1 patent drawing
  • US20240124314A1 patent drawing
  • US20240124314A1 patent drawing

AI summary

Provided is a particle-immobilized substrate that can be easily produced and has inorganic nanoparticles present in a nanometer-scale region. Also provided is a method for easily producing a substrate in which nanoparticles are arranged in a nanometer-scale region on a solid surface. A particle-immobilized substrate 1 includes a substrate 2 and a plurality of inorganic nanoparticles 3 disposed on the substrate 2, in which the plurality of inorganic nanoparticles 3 is disposed in contact with each other in a region having a width (D1) of 1 μm or less on the substrate 2.