Nanoporous Ceramic Foam Thermal Shield

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Solution Overview

Problem

Traditional heat shield materials used in reentry vehicles, such as quartz/carbonphenolic systems, are too heavy and conductive, failing to prevent thermal soak-through and requiring thicker insulation, which increases weight and reduces payload capacity, while existing insulation methods like tile or blanket types cannot handle high temperatures and frictional forces.

Innovation Solution

A nanoballoon thermal protection system is developed, comprising nanoparticles with diameters between 0 and 1000 nm, fabricated using a method that includes creating a packed structure of nanoparticles, forming a porous template, and producing hollow nanoballoons, which are then consolidated into a closed cell foam coating for improved thermal insulation and reduced weight.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Temperature

If traditional quartz/carbonphenolic material systems are used to provide thermal insulation, then thermal protection is achieved, but weight increases due to increased thickness and material density

Engineering Contradiction:
Improvethermal insulation performanceVSAvoidheat shield weight
Core Design Contradiction:
TemperatureVSWeight of moving object

Solution Approach 1:

The patent employs a porous ceramic foam structure as the thermal protection system. The foam architecture provides numerous pores and cellular structures that trap air and reduce thermal conduction pathways, achieving superior thermal insulation performance. The porous structure allows for reduced material density and thickness while maintaining insulation effectiveness, directly addressing the weight reduction goal.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent utilizes composite material systems combining ceramic matrices with foam structures. This composite approach integrates the high-temperature resistance of ceramics with the lightweight insulation properties of foam, creating a material that simultaneously achieves thermal protection and weight reduction without compromising either property.

Inventive Principle:
Principle #40Composite materials

2Temperature

If traditional quartz/carbonphenolic material systems are used to prevent thermal soak-through, then thermal protection is provided, but material conductivity remains too high requiring thicker insulation

Engineering Contradiction:
Improvethermal soak-through resistanceVSAvoidheat shield thickness
Core Design Contradiction:
TemperatureVSLength of stationary object

Solution Approach 1:

The porous ceramic foam structure creates numerous internal surfaces and air-filled voids that interrupt heat transfer pathways. The cellular architecture increases thermal resistance by forcing heat to navigate complex paths through solid material and air pockets, significantly reducing thermal conductivity and preventing soak-through without requiring increased thickness.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The foam structure introduces a three-dimensional cellular architecture that transforms the thermal transport problem from simple linear conduction to complex multi-dimensional heat flow through porous media. This dimensional complexity increases thermal resistance per unit thickness, achieving better insulation without proportionally increasing thickness.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Weight of moving object

If tile or blanket type insulation is used to reduce weight, then weight is reduced, but the system cannot handle high temperatures and frictional forces

Engineering Contradiction:
Improveinsulation weightVSAvoidhigh temperature and friction resistance
Core Design Contradiction:
Weight of moving objectVSReliability

Solution Approach 1:

The patent creates a composite system where ceramic materials provide high-temperature and friction resistance while the foam structure provides lightweight insulation. This composite architecture allows the system to withstand reentry conditions while maintaining reduced weight, overcoming the limitations of traditional tile or blanket insulation.

Inventive Principle:
Principle #40Composite materials

Solution Approach 2:

The patent changes the physical and chemical parameters of the insulation material by using ceramic-based foam instead of organic blankets or tiles. This parameter change enables the material to withstand higher temperatures and mechanical stresses while maintaining lightweight properties, achieving both weight reduction and improved reliability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The nanoballoon thermal protection system provides lightweight, high-temperature insulation with reduced weight, effective thermal shock resistance, and excellent fracture toughness, allowing for thinner heat shields and increased payload capacity while withstanding harsh reentry conditions.

Implementation Method 1

fabricating a packed structure of nanoparticles; creating a porous template

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Implementation Method 2

nanoporous thermal radiant barrier coating

Methodology Applied
Scientific EffectRadiation: Radiation

Implementation Method 3

nanoporous thermal radiant barrier coating

Methodology Applied
Scientific EffectReflection: Reflection

Data Source

PatentUS9464006B2Nanoporous coating synthesis and apparatus
Publication Date: 2016.10.11 LOCKHEED MARTIN CORP
  • US9464006B2 patent drawing
  • US9464006B2 patent drawing
  • US9464006B2 patent drawing

AI summary

An example of a nanoballoon thermal protection system includes a refractory ceramic foam having carbide balloons. The foam has a closed cell structure not allowing liquid to penetrate through the foam. Each of the carbide balloons is hollow and has a diameter greater than 0 nm and less than 900 nm. Each of the carbide balloons includes a refractory carbide. In addition, a vehicle with thermal shield includes a surface and a first and second nanoballoon closed cell foam coatings. Each of the foam coatings has a melting point temperature greater than 1000° C. and a density less than 85%. Each of the foam coatings has hollow balloons having a diameter less than 900 nm. Each of the foam coatings includes a closed cell structure not allowing liquid to penetrate through the respective coating. Methods for manufacturing a nanoballoon system and a nanoballoon thermal protection system are also disclosed.