Nanoporous Superabsorbent Particles for Rapid Fluid Absorption

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Solution Overview

Problem

Conventional superabsorbent materials exhibit slow initial absorption rates when coming into contact with fluids, necessitating a material with faster absorption capabilities without compromising total absorbent capacity.

Innovation Solution

Development of superabsorbent particles with a median size of 50 to 2,000 micrometers and nanopores of 10 to 500 nanometers, featuring a high porosity and specific surface area, which enables rapid fluid absorption characterized by a Vortex Time of 80 seconds or less and sustained high Absorption Rates.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional superabsorbent materials are used, then total absorbent capacity is maintained, but initial absorption rate is slow

Engineering Contradiction:
Improveinitial absorption rateVSAvoidtime to reach absorption equilibrium
Core Design Contradiction:
ProductivityVSLoss of time

Solution Approach 1:

The patent applies porous materials by creating a nanoporous structure within the superabsorbent particles, where pores with average cross-sectional dimensions of 10 to 500 nanometers are formed throughout the particle matrix. This porous structure provides numerous pathways for rapid fluid penetration and absorption, dramatically increasing the initial absorption rate while maintaining total absorbent capacity through the high surface area to volume ratio created by the nanopores.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent applies parameter changes by modifying the physical and chemical parameters of the superabsorbent material, specifically controlling the particle size (50 to 2,000 micrometers median size) and pore dimensions (10 to 500 nanometers). These parameter optimizations enable the material to achieve fast absorption rates with a Vortex Time of 80 seconds or less while preserving high absorbent capacity through careful control of these critical parameters.

Inventive Principle:
Principle #35Parameter changes

2Productivity

If nanopores are introduced to increase absorption rate, then initial absorption rate improves, but particle structure complexity increases

Engineering Contradiction:
Improveabsorption rateVSAvoidparticle structure complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent applies porous materials by creating a nanoporous structure within the superabsorbent particles, where pores with average cross-sectional dimensions of 10 to 500 nanometers are formed throughout the particle matrix. This porous structure provides numerous pathways for rapid fluid penetration and absorption, dramatically increasing the initial absorption rate while maintaining total absorbent capacity through the high surface area to volume ratio created by the nanopores.

Inventive Principle:
Principle #31Porous materials

Solution Approach 2:

The patent applies preliminary action by pre-forming the nanoporous structure during the manufacturing process before the material is put into service. The nanopores are created through controlled polymerization or post-synthesis treatment, establishing the absorption pathways in advance. This preliminary structuring eliminates the need for complex in-service modifications and ensures consistent high absorption performance.

Inventive Principle:
Principle #10Preliminary action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The particles demonstrate enhanced absorption rates while maintaining high absorbent capacity and retention, with Vortex Time of 80 seconds or less and Absorption Rates exceeding 300 g/g/ks, along with improved Centrifuge Retention Capacity and Free Swell Gel Bed Permeability.

Implementation Method 1

nanopores having an average cross-sectional dimension of from about 10 to about 500 nanometers... enables rapid fluid absorption

Methodology Applied
Scientific EffectCapillary action: Capillary Action

Implementation Method 2

high porosity and specific surface area... Absorption Rates exceeding 300 g/g/ks

Methodology Applied
Scientific EffectAdsorption: Adsorption

Data Source

PatentUS12194435B2Nanoporous superabsorbent particles
Publication Date: 2025.01.14 KIMBERLY CLARK WORLDWIDE INC
  • US12194435B2 patent drawing
  • US12194435B2 patent drawing
  • US12194435B2 patent drawing

AI summary

Superabsorbent particles having a median size of from about 50 to about 2,000 micrometers and containing nanopores having an average cross-sectional dimension of from about 10 to about 500 nanometers are provided. The superabsorbent particles exhibit a Vortex Time of about 80 seconds or less.