Transparent Conductive Nanorods for Light-Emitting Devices

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Solution Overview

Problem

Conventional light-emitting devices with metal thin film electrodes suffer from decreased luminous efficiency due to light absorption, thermal instability, and non-uniform current transfer, especially as device size increases, and organic electroluminescent devices face inefficiencies due to light reflection and absorption by the electrode.

Innovation Solution

A light-emitting device utilizing transparent conductive nanorods grown from materials like ZnO or ITO as electrodes, which reduce total internal reflections and enhance current injection, allowing for improved light transmission and luminous efficiency, even in larger devices.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of energy

If metal thin film electrodes are used, then electrical conductivity is improved, but light absorption increases and luminous efficiency decreases

Engineering Contradiction:
Improveluminous efficiencyVSAvoidlight absorption by electrode
Core Design Contradiction:
Loss of energyVSObject-affected harmful factors

Solution Approach 1:

The patent extracts the harmful metal layer from the electrode structure and replaces it with transparent conductive nanorods made of oxide materials (such as ITO, ZnO, or TiO2). This extraction removes the light-absorbing component while maintaining electrical conductivity through the nanorod structure, directly resolving the contradiction between conductivity and light absorption.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the physical and chemical parameters of the electrode material from metallic (opaque, high conductivity) to oxide-based nanorods (transparent, moderate conductivity). By adjusting the material composition, crystal structure, and nanorod dimensions, the electrode achieves optimal balance between transparency and conductivity, improving luminous efficiency while maintaining electrical performance.

Inventive Principle:
Principle #35Parameter changes

2Power

If device size is increased, then luminance output is improved, but current uniformity deteriorates due to high resistance of p-type GaN

Engineering Contradiction:
Improveluminance outputVSAvoidcurrent uniformity
Core Design Contradiction:
PowerVSManufacturing precision

Solution Approach 1:

The patent segments the electrode into an array of discrete nanorods rather than using a continuous metal film. This segmentation creates multiple current injection pathways through the high-resistance p-type GaN layer, allowing uniform current distribution across large device areas. Each nanorod acts as an independent current channel, preventing current crowding and maintaining uniformity as device size increases.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent transitions from a two-dimensional planar electrode to a three-dimensional nanorod array structure. The vertical nanorods penetrate through the p-type GaN layer, creating additional current pathways in the vertical dimension. This dimensional change enables efficient current injection across large horizontal areas while maintaining uniformity, as the nanorods distribute current vertically through the high-resistance layer.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

3Object-affected harmful factors

If transparent conductive material is used, then light transmission is improved, but contact resistance increases and device efficiency decreases

Engineering Contradiction:
Improvelight absorptionVSAvoidcontact resistance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent employs nanorod arrays with controlled porosity and surface area. The high surface-to-volume ratio of the nanorods provides extensive contact area with the semiconductor layer, compensating for the moderate conductivity of transparent materials. This porous nanorod structure reduces contact resistance through increased interface area while maintaining optical transparency, resolving the contradiction between transparency and electrical contact quality.

Inventive Principle:
Principle #31Porous materials

4Adaptability or versatility

If organic electroluminescent device is used, then device flexibility is improved, but light escape efficiency deteriorates due to refractive index and reflection

Engineering Contradiction:
Improvedevice flexibilityVSAvoidlight reflection and absorption
Core Design Contradiction:
Adaptability or versatilityVSLoss of energy

Solution Approach 1:

The patent utilizes the curved surface geometry of the nanorod tips and the overall dome-shaped microcavity structure to control light propagation. The curved interfaces reduce total internal reflection at the electrode-light interface, enabling more efficient light extraction. This curvature-based design addresses the light trapping problem inherent in planar organic LED structures while maintaining device flexibility.

Inventive Principle:
Principle #14Spheroidality (Curvature)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The use of transparent conductive nanorods as electrodes increases luminous efficiency and enables uniform current transfer, facilitating the fabrication of large, high-luminance light-emitting devices with reduced absorption and reflection issues.

Implementation Method 1

total internal reflection can drastically decrease

Methodology Applied
Scientific EffectTotal internal reflection: Total Internal Reflection

Implementation Method 2

current injection is improved

Methodology Applied
Scientific EffectElectrical conduction: Conduction (electrical)

Data Source

PatentUS8022432B2Light-emitting device comprising conductive nanorods as transparent electrodes
Publication Date: 2011.09.20 LG DISPLAY CO LTD
  • US8022432B2 patent drawing
  • US8022432B2 patent drawing
  • US8022432B2 patent drawing

AI summary

Disclosed herein is an electrical light-emitting device including a transparent conductive nanorod type electrode, in which transparent conductive nanorods grown perpendicular to a light-emitting layer are used as the electrode. Hence, light is not absorbed by the electrode, and tunneling easily occurs due to nanocontact of the nanorods, thus increasing current injection efficiency, and also, total internal reflections decrease. Thereby, the light-emitting device according to this invention has light-emitting properties and luminous efficiency superior to conventional light-emitting devices, including metal electrodes or thin film type transparent electrodes.