Semiconductor Nanorod Ink for LED Alignment

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Solution Overview

Problem

The dispersion stability of semiconductor nanorods in organic solvents is poor, leading to quick sedimentation and unsatisfactory dielectrophoretic characteristics in conventional LED manufacturing processes, which hinders the efficient alignment and patterning of ultra-small LED devices.

Innovation Solution

An ink composition is developed that includes surface-treated semiconductor nanorods with specific functional groups and a citrate-based solvent, enhancing dispersion stability and dielectrophoresis alignment characteristics by forming a metal oxide coating layer on the nanorods, thereby improving the precipitation speed and alignment precision.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If semiconductor nanorods are used in conventional organic solvents, then the manufacturing process can be simplified, but the dispersion stability deteriorates quickly leading to sedimentation

Engineering Contradiction:
Improvemanufacturing process simplicityVSAvoiddispersion stability
Core Design Contradiction:
Ease of manufactureVSStability of the object's composition

Solution Approach 1:

A surfactant is introduced as an intermediary substance between the semiconductor nanorods and the organic solvent. The surfactant molecules adsorb onto the nanorod surfaces and extend into the solvent, creating a steric barrier that prevents nanorod aggregation and sedimentation, thereby maintaining dispersion stability throughout the manufacturing process

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent creates a composite system consisting of semiconductor nanorods, organic solvent, and surfactant. This composite ink composition combines materials with different properties to achieve both ease of manufacture (through solvent choice) and dispersion stability (through surfactant mediation), resolving the contradiction between processing simplicity and composition stability

Inventive Principle:
Principle #40Composite materials

2Volume of moving object

If ultra-small LED devices are manufactured at nano-scale, then the device size is reduced for high integration, but the manual disposition and mounting capability is lost

Engineering Contradiction:
Improvedevice sizeVSAvoidmanual disposition capability
Core Design Contradiction:
Volume of moving objectVSEase of operation

Solution Approach 1:

The patent employs dielectrophoresis, a technique that uses non-uniform electric fields to manipulate and position dielectric particles (semiconductor nanorods) in a fluid medium. This hydraulic/electric field-based approach enables automated positioning of ultra-small devices without manual intervention, resolving the contradiction between miniaturization and operability

Inventive Principle:
Principle #29Pneumatics and hydraulics

Solution Approach 2:

Manual mechanical manipulation is replaced with an electric field-based dielectrophoretic system. The electric fields automatically guide and position the nanorods on electrodes, substituting the need for manual handling and enabling precise positioning of devices too small for manual operation

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Device complexity

If conventional ink compositions are used, then the processing can be performed with standard equipment, but the dielectrophoretic characteristics are unsatisfactory leading to poor alignment precision

Engineering Contradiction:
Improveequipment complexityVSAvoidalignment precision
Core Design Contradiction:
Device complexityVSManufacturing precision

Solution Approach 1:

The patent modifies the chemical parameters of the ink composition by adding surfactants and optimizing the nanorod-solvent-surfactant ratio. These parameter changes enhance the dielectrophoretic response of the nanorods, improving alignment precision under standard electric fields without requiring more complex equipment

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The ink composition achieves improved dispersion stability and dielectrophoretic characteristics, enabling efficient large-area inkjet processing and enhancing the luminance and patterning quality of ultra-small LED devices.

Implementation Method 1

an ink composition for an electrophoresis apparatus

Methodology Applied
Scientific EffectDielectrophoresis: Electrophoresis

Implementation Method 2

a citrate-based solvent, enhancing dispersion stability

Methodology Applied
Scientific EffectElectrostatic stabilization: Electrostatics

Data Source

PatentUS20230407122A1Ink composition, layer using the same, and electrophoresis apparatus, and display device comprising the same
Publication Date: 2023.12.21 SAMSUNG DISPLAY CO LTD
  • US20230407122A1 patent drawing
  • US20230407122A1 patent drawing
  • US20230407122A1 patent drawing

AI summary

Embodiments provide an ink composition, a layer manufactured using the ink composition, and an electrophoresis apparatus and a display device including the same. The ink composition includes a semiconductor nanorod including at least one functional group each independently represented by one of Chemical Formula 1-1 to Chemical Formula 1-3, and a solvent. Chemical Formula 1-1 to Chemical Formula 1-3 are explained in the specification: