Nanorod Layer Transfer Using Sacrificial Separation for Crystal Quality

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Solution Overview

Problem

Conventional methods for producing nanorods face challenges such as high defective rates, poor crystal structure and optical characteristics, difficulty in uniform arrangement, and damage during separation from substrates due to high synthesis temperatures and heat transfer.

Innovation Solution

A method involving a growth substrate and a support substrate, where a nanomaterial layer is epitaxially grown, bonded to a sacrificial layer, and then separated using techniques like laser lift-off or chemical mechanical polishing to form high-quality nanorods with minimized defects.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional vapor method or liquid method is used to synthesize nanorods, then nanorods can be produced, but the defective rate is high and crystal structure is poor

Engineering Contradiction:
Improvenanorod qualityVSAvoidcrystal structure
Core Design Contradiction:
ReliabilityVSManufacturing precision

Solution Approach 1:

The synthesis process is divided into two independent stages: (1) epitaxial growth of nanomaterial layer on growth substrate with controlled crystal structure, and (2) transfer to support substrate for nanorod formation. This segmentation allows each stage to be optimized independently, achieving high crystal quality without defects.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The nanomaterial layer is epitaxially grown on the growth substrate first, establishing a high-quality crystal structure before transfer. This preliminary action ensures that the crystal lattice is properly formed and aligned, preventing defects that would occur during direct synthesis on the final substrate.

Inventive Principle:
Principle #10Preliminary action

2Ease of manufacture

If high heat energy is used in conventional synthesis methods, then nanorods can be formed, but thermal damage and surface cracks occur during separation

Engineering Contradiction:
Improvenanorod formationVSAvoidthermal damage
Core Design Contradiction:
Ease of manufactureVSObject-affected harmful factors

Solution Approach 1:

A sacrificial layer is introduced as an intermediary between the nanomaterial layer and the support substrate. This sacrificial layer enables easy separation through chemical etching or other non-thermal methods, eliminating thermal damage and surface cracks that occur with direct high-heat synthesis and separation.

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The separation process is changed from thermal/mechanical force (which causes damage) to chemical etching of the sacrificial layer (which causes no damage to the nanorod). This substitution replaces harmful physical separation methods with a gentle chemical process.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

3Productivity

If conventional synthesis methods are used, then nanorods can be produced, but uniform arrangement and electrode formation are difficult

Engineering Contradiction:
Improvenanorod productionVSAvoiduniform arrangement
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

By separating the growth process from the arrangement process, the nanomaterial layer can be epitaxially grown with uniform crystal structure first, then transferred and arranged on the support substrate in a controlled manner. This enables both high production quality and uniform arrangement.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The nanomaterial layer is grown in a planar epitaxial form on the growth substrate, then transferred to the support substrate where it can be arranged in the desired dimensional configuration. This dimensionality change from growth to arrangement enables precise positioning and uniform electrode formation.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method effectively minimizes the defective rate of nanorods and produces high-quality nanorods by facilitating easy separation from the substrate, improving crystal structure and optical characteristics.

Implementation Method 1

epitaxial growing a nanomaterial layer on one surface of the growth substrate

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Implementation Method 2

The nanomaterial layer may be epitaxially grown by metal organic chemical vapor deposition (MOCVD)

Methodology Applied
Scientific EffectMetal organic chemical vapor deposition: Chemical Vapour Deposition

Implementation Method 3

separating the growth substrate from the nanomaterial layer may include separating the growth substrate from the nanomaterial layer using one among a laser lift-off (LLO) method

Methodology Applied
Scientific EffectLaser lift-off: Laser Ablation

Implementation Method 4

The flattening of the nanomaterial layer may include flattening the nanomaterial layer separated from the growth substrate using chemical mechanical polishing (CMP)

Methodology Applied
Scientific EffectChemical mechanical polishing:

Implementation Method 5

separating the nanorod by removing the sacrificial layer

Methodology Applied
Scientific EffectChemical etching:

Data Source

PatentUS12074247B2Nanorod production method and nanorod produced thereby
Publication Date: 2024.08.27 SAMSUNG DISPLAY CO LTD
  • US12074247B2 patent drawing
  • US12074247B2 patent drawing

AI summary

Provided is a method of manufacturing a nanorod. The method comprising comprises the steps of: providing a growth substrate and a support substrate; epitaxially growing a nanomaterial layer onto one surface of the growth substrate; forming a sacrificial layer on one surface of the support substrate; bonding the nanomaterial layer with the sacrificial layer; separating the growth substrate from the nanomaterial layer; flattening the nanomaterial layer; forming a nanorod by etching the nanomaterial layer; and separating the nanorod by removing the sacrificial layer.