2D Nanosheet Gas Sensor for High Sensitivity Humidity Detection

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Solution Overview

Problem

Existing devices for touchless positioning interfaces lack sufficient spatial sensitivity and rapid response times, particularly due to limitations with materials like zinc oxide, which cannot be produced as ultrathin, planar 2D structures with large surface areas, making them unsuitable for advanced electronic devices.

Innovation Solution

A device comprising multiple layers of active nanosheets that randomly overlap, exhibiting changes in size, resistance, refractive index, or combinations thereof in response to environmental changes such as humidity, allowing for high sensitivity and fast response times, particularly using phosphatoantimonic acid Sb3P2O14 nanosheets in a thin film configuration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional materials like zinc oxide are used in humidity sensors, then the device structure is simple and manufacturing is easy, but the spatial sensitivity is insufficient and response time is too long

Engineering Contradiction:
Improvespatial sensitivityVSAvoiddevice structure complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent segments the active material into individual nanosheets with thicknesses of 1-10 nm, creating a layered structure that dramatically increases surface area to volume ratio. This segmentation enables rapid response times and high spatial sensitivity while maintaining manufacturing simplicity through solution-based processing of the nanosheet assemblies

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent transitions from bulk 3D materials to 2D nanosheet structures, creating ultrathin planar configurations with lateral dimensions of micrometers to millimeters. This dimensional change provides large surface areas for environmental interaction while maintaining simple device architectures suitable for touchless positioning interfaces

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Speed

If ultrathin 2D structures with large surface area are produced, then sensitivity and response time improve, but manufacturing complexity and cost increase

Engineering Contradiction:
Improveresponse timeVSAvoidmanufacturing complexity
Core Design Contradiction:
SpeedVSEase of manufacture

Solution Approach 1:

The patent controls nanosheet thickness parameters at 1-10 nm and lateral dimensions at micrometer to millimeter scales, optimizing the balance between surface area for rapid response and manufacturability. These parameter ranges enable fast response times while remaining compatible with solution-based fabrication techniques

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite structures by assembling multiple nanosheets into layered configurations, combining the advantages of ultrathin dimensions for sensitivity with the mechanical stability of multi-layer assemblies. This composite approach maintains ease of manufacture through solution processing while achieving the desired response characteristics

Inventive Principle:
Principle #40Composite materials

3Measurement precision

If ultrathin 2D structures with large surface area are produced, then sensitivity and response time improve, but device complexity and production difficulty increase

Engineering Contradiction:
Improvespatial sensitivityVSAvoidproduction difficulty
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent segments the active material into individual nanosheets that can be independently processed and assembled, enabling simple solution-based fabrication methods to produce complex high-sensitivity structures. The segmented nanosheet architecture achieves superior spatial sensitivity without requiring complex manufacturing equipment or processes

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The patent optimizes nanosheet dimensions with thicknesses of 1-10 nm and lateral sizes of micrometers to millimeters, creating a parameter regime where high surface area to volume ratio provides excellent sensitivity while the overall device structure remains simple and amenable to standard fabrication techniques

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The device achieves high sensitivity with a response range of over 5 orders of magnitude in resistance, fast response and recovery times, and selective detection of humidity and other vapors, enabling effective touchless positioning and humidity sensing without the need for complex electronic circuitry.

Implementation Method 1

the active material being selected so as to experience a change (i) of at least one size dimension, (ii) of the resistance, (iii) of the resistivity, (iv) of the refractive index or (v) combinations of two or more of the foregoing, when the active material is subjected to a change in environment

Methodology Applied
Scientific EffectAdsorption: Adsorption

Implementation Method 2

exhibiting a high spatial sensitivity to the degree of environmental moisture... with a response range of over 5 orders of magnitude in resistance

Methodology Applied
Scientific EffectResistivity change: Electrical Resistance

Data Source

PatentEP3210000B1Gas and vapor sensing devices based on 2d nanosheet material
Publication Date: 2021.09.08 MAX PLANCK GESELLSCHAFT ZUR FOERDERUNG DER WISSENSCHAFTEN EV
  • EP3210000B1 patent drawingFigure 1~3
  • EP3210000B1 patent drawingFigure 4a~4c
  • EP3210000B1 patent drawingFigure 5a~5d

AI summary

The present invention relates to a device, comprising at least one layer of an active material having a first optical thickness, the active material being selected so as to experience a change (i) of at least one size dimension, (ii) of the resistance, (iii) of the refractive index or (iv) combinations of two or more of the foregoing, when the active material is subjected to a change in environment, wherein at least one and preferably all of the layers of the at least one layer of the active material is composed of at least two nanosheets of the active material, with the at least two nanosheets randomly overlapping one another. The invention further relates to a nanosheet of active material and to a use of the nanosheet of the material.