Nanostructure Network Fabrication via Solvent Evaporation

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Solution Overview

Problem

Current methods for fabricating transparent electrodes using silver nanostructures face challenges in achieving high transmittance, efficient fabrication processes, and scalability, particularly for flexible display devices, as they often result in random nanostructure distributions that reduce transmittance and require complex patterning processes.

Innovation Solution

A method involving the preparation of a nanostructure solution dispersed in a first solvent, forming a nanostructure ink with a second solvent of higher viscosity, and coating it on a substrate, where the solvents evaporate to self-assemble into a poly-crystalline structure with defined cell shapes, optimizing transmittance and simplifying the fabrication process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If conventional methods are used to fabricate transparent electrodes using silver nanostructures, then electrical conductivity can be achieved, but transmittance is reduced due to random nanostructure distribution

Engineering Contradiction:
Improveelectrical conductivityVSAvoidlight transmittance
Core Design Contradiction:
ReliabilityVSIllumination intensity

Solution Approach 1:

The patent changes the physical-chemical parameters of the solvent system by introducing a second solvent with higher viscosity and lower vapor pressure. This parameter change controls the evaporation rate and enables poly-crystalline self-assembly of nanostructures, achieving both high conductivity and high transmittance (>80%) simultaneously

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent uses a composite solvent system comprising two different solvents with complementary properties: the first solvent (e.g., water or alcohol) provides good nanostructure dispersion, while the second solvent (e.g., glycerol or ethylene glycol) with higher viscosity controls evaporation kinetics. This composite approach enables controlled self-assembly into poly-crystalline structures that maintain both electrical conductivity and optical transparency

Inventive Principle:
Principle #40Composite materials

2Illumination intensity

If complex patterning processes are used to achieve defined nanostructure arrangements, then transmittance can be improved, but fabrication complexity and cost increase

Engineering Contradiction:
Improvelight transmittanceVSAvoidfabrication process complexity
Core Design Contradiction:
Illumination intensityVSDevice complexity

Solution Approach 1:

The patent employs self-service by allowing the nanostructures to self-assemble into poly-crystalline patterns through controlled solvent evaporation. The system automatically organizes itself into ordered structures with defined cell shapes without requiring external patterning tools, masks, or complex fabrication steps, achieving high transmittance through self-organization

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The second solvent acts as an intermediary that mediates the self-assembly process. By controlling the evaporation rate and viscosity, it enables the nanostructures to spontaneously form ordered poly-crystalline arrangements with high transmittance, eliminating the need for complex patterning processes while maintaining structural definition

Inventive Principle:
Principle #24Intermediary (Mediator)

3Productivity

If simple solvent evaporation is used, then fabrication time is reduced, but nanostructure self-assembly into poly-crystalline structure is not achieved

Engineering Contradiction:
Improvefabrication speedVSAvoidnanostructure arrangement precision
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent optimizes the evaporation parameters by selecting a second solvent with specific viscosity and vapor pressure characteristics. This parameter optimization enables the system to achieve poly-crystalline self-assembly within a reasonable time frame, balancing fabrication speed with structural precision without requiring prolonged processing

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent exploits the phase transition during solvent evaporation to drive self-assembly. As the solvent evaporates, the changing concentration and viscosity trigger the spontaneous organization of nanostructures into poly-crystalline structures with defined cell shapes, achieving precise arrangement through a natural phase change process rather than mechanical intervention

Inventive Principle:
Principle #36Phase transitions

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the formation of nanostructure networks with high transmittance (>80% in the visible light region) and flexible electrical conductivity, reducing fabrication time and cost while avoiding complex patterning, making them suitable for flexible transparent electrodes.

Implementation Method 1

forming a nanostructure network by evaporating the first solvent and the second solvent included in the nanostructure ink coated on the substrate

Methodology Applied
Scientific EffectEvaporation: Evaporation

Implementation Method 2

a nanostructure network having a poly-crystalline structure formed by self-assembly of nanostructures

Methodology Applied
Scientific EffectSelf-assembly: Self-Assembly

Data Source

PatentUS11217368B2Nanostructure network and method of fabricating the same
Publication Date: 2022.01.04 IND UNIV COOP FOUND HANYANG UNIV ERICA CAMPUS
  • US11217368B2 patent drawing
  • US11217368B2 patent drawing
  • US11217368B2 patent drawing

AI summary

Provided are a nanostructure network and a method of fabricating the same. The nanostructure network includes nanostructures having a poly-crystalline structure formed by self-assembly of the nanostructures. The method includes preparing a nanostructure solution in which nanostructures are dispersed in a first solvent, forming a nanostructure ink by adding the nanostructure solution into a second solvent having a viscosity higher than that of the first solvent, coating a surface of a substrate with the nanostructure ink, and forming a nanostructure network by evaporating the first solvent and the second solvent included in the nanostructure ink coated on the substrate.