Nanostructured Metal-Organic Separator for Ion Conductivity Control

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Solution Overview

Problem

Conventional battery and electrochemical cell separators lack control over ion conductivity and performance characteristics, leading to inefficiencies in ion migration and potential electrical shorting between electrodes.

Innovation Solution

A nanostructured separator made from metal-organic materials, such as metal-organic frameworks, coordination polymers, or covalent-organic frameworks, is integrated onto the electrode substrate, providing controlled ion conductivity and preventing electrical shorting while allowing for efficient ion migration.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If conventional separators are used, then the structure is simple and easy to manufacture, but the control over ion conductivity and performance characteristics is insufficient

Engineering Contradiction:
Improvecontrol over ion conductivityVSAvoidseparator structure
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent applies parameter changes by systematically varying the pore size, pore size distribution, and porosity of the separator through controlled phase separation processes. By adjusting parameters such as polymer concentration, solvent composition, and thermal treatment conditions, the separator's ion conductivity and performance characteristics can be precisely tuned to meet specific application requirements.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs composite materials by combining different polymer matrices with specific pore-forming agents and additives. This creates a multi-phase composite structure where the polymer provides mechanical integrity while the phase-separated pores provide ion transport pathways, achieving both structural simplicity and controlled ion conductivity.

Inventive Principle:
Principle #40Composite materials

2Productivity

If conventional separators are used, then the manufacturing process is simple, but ion migration efficiency is insufficient

Engineering Contradiction:
Improveion migration efficiencyVSAvoidseparator fabrication
Core Design Contradiction:
ProductivityVSEase of manufacture

Solution Approach 1:

The patent applies preliminary action by pre-forming the phase-separated pore structure during the separator manufacturing process itself, rather than attempting to modify the structure later. The controlled phase separation is performed during membrane formation, creating the optimal pore network for ion migration before the separator is assembled into the battery, thereby improving ion migration efficiency without complicating the overall manufacturing process.

Inventive Principle:
Principle #10Preliminary action

3Reliability

If conventional separators are used, then the device structure is simple, but electrical shorting prevention is insufficient

Engineering Contradiction:
Improveelectrical shorting preventionVSAvoidseparator design
Core Design Contradiction:
ReliabilityVSDevice complexity

Solution Approach 1:

The patent applies local quality by creating regions of different pore sizes and densities within the separator structure. The phase separation process generates a non-uniform pore distribution where certain regions have smaller pores for better electrical isolation while other regions have larger pores for efficient ion transport. This local variation in structure provides both reliable electrical shorting prevention and adequate ion migration pathways.

Inventive Principle:
Principle #3Local quality

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The nanostructured separator enhances the performance of batteries and electrochemical cells by offering unprecedented control over ion conductivity and stability, reducing the risk of electrical shorting and optimizing cell efficiency.

Implementation Method 1

the nanostructured separator can allow for unprecedented control over ion conductivity and related performance characteristics of batteries or electrochemical cells

Methodology Applied
Scientific EffectIon conductivity: Conduction (electrical)

Data Source

PatentUS11322801B2Nanostructured metal organic material electrode separators and methods therefor
Publication Date: 2022.05.03 KING ABDULLAH UNIV OF SCI & TECH
  • US11322801B2 patent drawing
  • US11322801B2 patent drawing
  • US11322801B2 patent drawing

AI summary

Provided herein are nanostructured electrode separators comprising metal organic materials capable of attaching to one or more electrodes and electrically insulating at least one electrode while allowing migration of ionic charge carriers through the nanostructured electrode separator. Methods of using such electrode separators include positioning a nanostructured electrode separator between two electrodes of an electrochemical cell.