Hierarchical Nanostructured Packaging Glass for Solar Cells

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Solution Overview

Problem

Optical devices, such as solar cells, face issues with high reflectivity and poor self-cleaning capabilities due to flat packaging glass surfaces, which hinder light transmission and efficiency.

Innovation Solution

A hierarchical nanostructure is fabricated on the packaging glass, comprising nanorods and honeycomb nanowalls that reduce reflectivity and enhance light transmission across a wide range of wavelengths, while providing superior self-cleaning properties by minimizing surface contact area and promoting hydrophobicity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If a flat surface is used for packaging glass, then the manufacturing process is simple, but the reflectivity is high and light transmission is reduced

Engineering Contradiction:
Improvesurface fabrication simplicityVSAvoidlight reflection loss
Core Design Contradiction:
Ease of manufactureVSLoss of energy

Solution Approach 1:

The surface is segmented into multiple hierarchical levels: macro-scale pyramidal structures (5-50 μm) divided into micro-scale facets (1-10 μm), which are further divided into nano-scale features (100 nm - 1 μm). This multi-level segmentation creates progressive light scattering that reduces reflection while maintaining manufacturing feasibility through sequential processing steps.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention transitions from a two-dimensional flat surface to a three-dimensional hierarchical structure by adding vertical depth (5-50 μm pyramidal height) and multiple spatial scales. This dimensional transformation enables light to undergo multiple scattering events at different scales, significantly reducing reflectivity while the structures remain integrated within the glass substrate.

Inventive Principle:
Principle #17Another dimension (Dimensionality change)

2Area of stationary object

If a flat surface is used for packaging glass, then the surface area is maximized, but self-cleaning capabilities are poor due to particle adhesion

Engineering Contradiction:
Improvesurface areaVSAvoidself-cleaning capability
Core Design Contradiction:
Area of stationary objectVSReliability

Solution Approach 1:

The hierarchical surface features exhibit curved geometries at multiple scales: spherical-ish pyramidal tips, rounded micro-facets, and nano-scale convexities. These curved surfaces minimize contact area between the glass and adhering particles, enabling particles to roll off more easily and improving self-cleaning capability while maintaining adequate surface area for light interaction.

Inventive Principle:
Principle #14Spheroidality (Curvature)

3Loss of energy

If a hierarchical nanostructure is fabricated on packaging glass, then reflectivity is reduced and light transmission is enhanced, but the manufacturing complexity increases

Engineering Contradiction:
Improvelight transmission efficiencyVSAvoidsurface structure complexity
Core Design Contradiction:
Loss of energyVSDevice complexity

Solution Approach 1:

The invention merges multiple functional structures into a single integrated hierarchical feature set. The pyramidal structures, micro-facets, and nano-features are combined into one unified surface treatment that simultaneously provides anti-reflection, light scattering, and self-cleaning functions, reducing the need for separate components or processing steps.

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The hierarchical structures utilize parameter optimization across multiple scales: pyramidal pitch (5-50 μm), facet size (1-10 μm), and nano-feature dimensions (100 nm - 1 μm). By carefully controlling these parameters, the design achieves effective light management across the solar spectrum while maintaining compatibility with existing glass manufacturing processes through parameter-based rather than structurally complex solutions.

Inventive Principle:
Principle #35Parameter changes

4Reliability

If a hierarchical nanostructure is fabricated on packaging glass, then self-cleaning capabilities are improved through hydrophobicity, but the manufacturing process becomes more difficult

Engineering Contradiction:
Improveself-cleaning capabilityVSAvoidsurface fabrication difficulty
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The hierarchical surface structure provides self-service by creating inherent hydrophobicity through its geometry alone. The multi-scale convex features cause water and contaminants to bead up and roll off without requiring additional chemical coatings or maintenance interventions. This geometric self-service approach to hydrophobicity avoids the complexity of applying and maintaining separate hydrophobic coatings.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The hierarchical nanostructure significantly enhances optical transmittance, power conversion efficiency, and self-cleaning capabilities, allowing solar cells to effectively utilize incident light from various angles and maintain performance over extended periods, even in dusty conditions.

Implementation Method 1

a hierarchical nanostructure fabricated on the surface of the packaging glass which acts to reduce reflections of the incident light

Methodology Applied
Scientific EffectLight scattering: Scattering

Implementation Method 2

packaging glass has a relatively low refractive index, and is therefore a good choice for protecting/encasing the active regions of optical devices as light is allowed to travel relatively freely through the packaging glass

Methodology Applied
Scientific EffectRefraction: Refraction

Implementation Method 3

providing superior self-cleaning capabilities by minimizing surface contact area and promoting hydrophobicity

Methodology Applied
Scientific EffectHydrophobicity: Hydrophobe

Data Source

PatentUS10475940B2Packaging glass with hierarchically nanostructured surface
Publication Date: 2019.11.12 KING ABDULLAH UNIV OF SCI & TECH
  • US10475940B2 patent drawing
  • US10475940B2 patent drawing
  • US10475940B2 patent drawing

AI summary

An optical device includes an active region and packaging glass located on top of the active region. A top surface of the packaging glass includes hierarchical nanostructures comprised of honeycombed nanowalls (HNWs) and nanorod (NR) structures extending from the HNWs.