Nanostructured Plastic Scintillator Photon Extraction

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Solution Overview

Problem

Plastic scintillators are less effective in detecting ionizing radiation compared to organic crystalline and inorganic scintillators due to lower light output, and existing solutions for improving sensitivity, such as optical coatings and photonic crystals, face limitations like aging and photon loss.

Innovation Solution

A nanostructured plastic scintillator with optical cavities, such as holes or pillars, is created within the radioluminescent polymer material to enhance the collection and generation of scintillation photons by guiding them along a privileged propagation axis, utilizing the Purcell effect for increased sensitivity without additional materials.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Ease of manufacture

If plastic scintillators are used, then advantages such as low cost, robustness, and short response time are achieved, but light output is reduced to around 10 photons/keV compared to 30-60 photons/keV for inorganic scintillators

Engineering Contradiction:
Improvecost and robustnessVSAvoidlight output
Core Design Contradiction:
Ease of manufactureVSQuantity of substance

Solution Approach 1:

The scintillator is segmented into multiple layers with different functions: a first scintillation layer for initial photon generation, a photonic crystal layer for directional control, and a second scintillation layer for enhanced light output. This segmentation allows each layer to be optimized for its specific function while working together to solve the overall light output problem.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The invention uses a composite structure combining plastic scintillation material with a photonic crystal layer. The photonic crystal layer, made of materials like TiO2 or SiO2 with specific refractive indices, is integrated with the plastic scintillator to enhance light extraction efficiency through controlled directional emission, thereby increasing the effective light output without sacrificing the inherent advantages of plastic scintillators.

Inventive Principle:
Principle #40Composite materials

2Quantity of substance

If reflective coatings are applied to scintillator faces, then photon collection is improved, but about 10% intensity loss occurs with each reflection

Engineering Contradiction:
Improvephoton collection efficiencyVSAvoidintensity loss per reflection
Core Design Contradiction:
Quantity of substanceVSLoss of energy

Solution Approach 1:

Instead of applying uniform reflective coatings to all scintillator faces, the invention applies different optical treatments to different faces. The exit face is equipped with a photonic crystal layer for directional photon extraction, while other faces may have reflective coatings or diffusing layers. This local differentiation optimizes photon collection while minimizing unnecessary reflections and associated losses.

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The photonic crystal layer changes the optical parameters at the scintillator exit face by creating a periodic structure with specific lattice constants and refractive index contrasts. This structure modifies the emission pattern to favor directional extraction toward the photodetector, improving collection efficiency without relying on reflective coatings that cause intensity loss.

Inventive Principle:
Principle #35Parameter changes

3Quantity of substance

If photonic crystals are deposited on scintillator surfaces, then light extraction efficiency is enhanced, but device complexity and manufacturing difficulty increase

Engineering Contradiction:
Improvelight extraction efficiencyVSAvoidmanufacturing complexity
Core Design Contradiction:
Quantity of substanceVSDevice complexity

Solution Approach 1:

The invention extracts the photonic crystal functionality from the bulk scintillator material and places it as a separate layer on the exit face. This allows the photonic crystal layer to be manufactured independently using established techniques like spin coating or dip coating, then integrated with the scintillator. This separation reduces manufacturing complexity compared to creating photonic crystals within the bulk material.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The photonic crystal layer acts as an intermediary between the scintillator bulk and the external environment (photodetector). It mediates the light extraction process by providing a transition zone with controlled optical properties, enabling efficient directional emission without requiring complex modifications to the scintillator material itself or the photodetector interface.

Inventive Principle:
Principle #24Intermediary (Mediator)

4Quantity of substance

If the scintillator structure is optimized for photon directionality, then collection efficiency improves, but manufacturing precision requirements increase

Engineering Contradiction:
Improvephoton directionalityVSAvoidstructural precision
Core Design Contradiction:
Quantity of substanceVSManufacturing precision

Solution Approach 1:

Instead of requiring perfect periodicity throughout the entire photonic crystal layer, the invention achieves sufficient directionality with a relatively thin layer (hundreds of nanometers to a few micrometers). The photonic crystal structure only needs to provide enough directional control to favor photon extraction toward the photodetector, not achieve perfect collimation. This partial action approach reduces manufacturing precision requirements while still providing significant improvement in collection efficiency.

Inventive Principle:
Principle #16Partial or excessive action

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The nanostructured scintillator improves the collection efficiency and generation of scintillation photons, leading to enhanced detection capabilities and reduced requirements for photodetector sensitivity, thereby improving the signal-to-noise ratio and reducing detector complexity and cost.

Implementation Method 1

A nanostructured plastic scintillator with optical cavities, such as holes or pillars, is created within the radioluminescent polymer material to enhance the collection and generation of scintillation photons by guiding them along a privileged propagation axis

Methodology Applied
Scientific EffectTotal internal reflection: Total Internal Reflection

Implementation Method 2

utilizing the Purcell effect for increased sensitivity without additional materials

Methodology Applied
Scientific EffectPurcell effect:

Implementation Method 3

a block of radioluminescent polymer material capable of generating scintillation photon radiation at a predetermined wavelength under the effect of ionizing radiation

Methodology Applied
Scientific EffectRadioluminescence: Radioluminescence

Data Source

PatentEP3502750B1Structured plastic scintillator
Publication Date: 2022.09.14 COMMISSARIAT A LENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES
  • EP3502750B1 patent drawingFigure 1~2
  • EP3502750B1 patent drawingFigure 3~4
  • EP3502750B1 patent drawingFigure 5

AI summary

The invention relates to the field of ionizing radiation detection using scintillation detectors. It concerns a plastic scintillator for such a detector, the structure of which is optimized for the generation and collection of scintillation photon radiation. The scintillator (30) is formed from a block of radioluminescent polymer material capable of generating scintillation photon radiation at a predetermined wavelength under the influence of ionizing radiation. According to the invention, the scintillator comprises a plurality of optical cavities (311) whose dimensions are determined as a function of the wavelength of the scintillation photon radiation. The optical cavities are formed from nanopillars or nanoholes.