Carbon Nanotube Layer Thinning for Aligned Gate Formation

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Solution Overview

Problem

As semiconductor manufacturing continues to shrink feature sizes, challenges arise in integrating and aligning carbon nanotubes for high-density, pure layers in semiconductor devices, requiring efficient deposition and alignment methods to enhance integration density and device performance.

Innovation Solution

A vacuum system with a filter and electrostatic field is used to deposit and align carbon nanotubes, employing a combination of passive and active electrostatic field generation and surfactant introduction to align and purify the nanotubes, followed by controlled thinning processes to form high-density, pure layers for semiconductor device fabrication.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If conventional lithography and deposition methods are used to shrink feature sizes, then integration density can be improved, but manufacturing precision and alignment quality deteriorate

Engineering Contradiction:
Improveintegration densityVSAvoidalignment quality
Core Design Contradiction:
ProductivityVSManufacturing precision

Solution Approach 1:

The patent replaces conventional mechanical lithography and deposition systems with a vacuum-based system that uses electrostatic fields and surfactant-mediated self-assembly to position carbon nanotubes. This substitution enables precise alignment and high-purity layer formation without the limitations of traditional mechanical approaches, simultaneously achieving high integration density and manufacturing precision

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent changes the physical and chemical parameters of the nanotube deposition process by controlling vacuum pressure, electrostatic field strength, and surfactant concentration. These parameter changes enable precise control over nanotube alignment, spacing, and layer purity, resolving the contradiction between integration density and manufacturing precision

Inventive Principle:
Principle #35Parameter changes

2Productivity

If carbon nanotubes are deposited to achieve high integration density, then productivity is improved, but purity and alignment quality worsen

Engineering Contradiction:
Improveintegration densityVSAvoidpurity
Core Design Contradiction:
ProductivityVSReliability

Solution Approach 1:

The patent introduces surfactant molecules as intermediaries that mediate between the carbon nanotubes and the substrate. These surfactants enable high-density nanotube deposition while maintaining purity by preventing aggregation and ensuring uniform distribution, thus resolving the contradiction between integration density and purity

Inventive Principle:
Principle #24Intermediary (Mediator)

Solution Approach 2:

The patent replaces conventional mechanical deposition methods with a vacuum-based electrostatic field approach that inherently provides better purity control. The electrostatic fields enable precise positioning of individual nanotubes, achieving high integration density while maintaining high purity levels

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method achieves high-purity, aligned carbon nanotube layers with precise control over spacing and thickness, improving semiconductor device integration density and performance, addressing the challenges of shrinking feature sizes and enhancing yield beyond the 2 nm node.

Implementation Method 1

A vacuum system with a filter and electrostatic field is used to deposit and align carbon nanotubes

Methodology Applied
Scientific EffectVacuum: Vacuum

Implementation Method 2

A vacuum system with a filter and electrostatic field is used to deposit and align carbon nanotubes

Methodology Applied
Scientific EffectElectrostatic field: Electrostatics

Implementation Method 3

employing a combination of passive and active electrostatic field generation and surfactant introduction to align and purify the nanotubes

Methodology Applied
Scientific EffectSurfactant: Surfactant

Data Source

PatentUS11749528B2Method of manufacturing semiconductor devices including the steps of removing a plurality of spacers that surrounds each of the plurality of nanotubes into a layer of nanotubes, and forming gate dielectric and/or gate electrode
Publication Date: 2023.09.05 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US11749528B2 patent drawing
  • US11749528B2 patent drawing
  • US11749528B2 patent drawing

AI summary

A semiconductor device and method of manufacturing using carbon nanotubes are provided. In embodiments a stack of nanotubes are formed and then a non-destructive removal process is utilized to reduce the thickness of the stack of nanotubes. A device such as a transistor may then be formed from the reduced stack of nanotubes.