Nanowire Formation via Anodic Oxidation with Protruding Structures

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Solution Overview

Problem

Current methods for forming nanowires using anodic oxidation face challenges in achieving uniform oxide growth and high aspect ratios, leading to inconsistent nanowire formation and limited control over nanowire dimensions.

Innovation Solution

The process involves immersing a cathode and anode electrode in an electrolytic solution, with the anode electrode featuring protruding structures that undergo anodic oxidation, allowing for controlled oxide growth and formation of nanowires with specific dimensions by managing electric field distribution and resistance changes during the oxidation process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Manufacturing precision

If anodic oxidation is performed to form nanowires, then nanowire formation is achieved, but uniform oxide growth and high aspect ratios are difficult to achieve

Engineering Contradiction:
Improvenanowire dimension controlVSAvoidoxide growth uniformity
Core Design Contradiction:
Manufacturing precisionVSReliability

Solution Approach 1:

Protruding structures are formed on the anode electrode surface before the anodic oxidation process. These pre-formed protrusions serve as controlled nucleation sites that guide subsequent oxide growth, ensuring uniform nanowire formation with consistent dimensions and high aspect ratios.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The anode electrode surface is engineered with localized protruding structures that create non-uniform electric field distribution during anodic oxidation. This localized structural modification enables controlled oxide growth at specific locations, achieving uniform nanowire dimensions and high aspect ratios through spatially differentiated growth conditions.

Inventive Principle:
Principle #3Local quality

2Manufacturing precision

If conventional anodic oxidation is used, then oxide growth occurs, but control over nanowire dimensions is limited

Engineering Contradiction:
Improvenanowire dimension controlVSAvoidprocess control complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The anodic oxidation process utilizes controlled variations in electrical parameters (voltage, current density, pulse duration) to precisely regulate oxide growth rates and nanowire dimensions. By dynamically adjusting these parameters during the oxidation process, consistent nanowire formation with high aspect ratios is achieved while maintaining manageable process control.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This method enables the consistent formation of nanowires with precise dimensions and high aspect ratios, overcoming previous inconsistencies and allowing for the fabrication of advanced semiconductor devices.

Implementation Method 1

Anodic oxidation includes an accelerated electrochemical oxidation process. For example, a cathode electrode and an anode electrode are immersed in an electrolytic solution and connected electrically to a power supply. Oxides can be grown at the anode electrode at room temperature.

Methodology Applied
Scientific EffectAnodic oxidation: Oxidation

Implementation Method 2

an accelerated electrochemical oxidation process. For example, a cathode electrode and an anode electrode are immersed in an electrolytic solution and connected electrically to a power supply.

Methodology Applied
Scientific EffectElectrochemical oxidation: Electrolysis

Data Source

PatentUS10868117B2Systems and methods for forming nanowires using anodic oxidation
Publication Date: 2020.12.15 TAIWAN SEMICONDUCTOR MANUFACTURING CO LTD
  • US10868117B2 patent drawing
  • US10868117B2 patent drawing
  • US10868117B2 patent drawing

AI summary

Structures, devices and methods are provided for forming nanowires on a substrate. A first protruding structure is formed on a substrate. The first protruding structure is placed in an electrolytic solution. Anodic oxidation is performed using the substrate as part of an anode electrode. One or more nanowires are formed in the protruding structure. The nanowires are surrounded by a first dielectric material formed during the anodic oxidation.