Metal Nanowire Heater Patterning With Thermal Joining

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Solution Overview

Problem

Metal nanowire heaters face challenges with low heating characteristics at the same voltage due to high resistance, susceptibility to oxidation, and limited flexibility, as well as high process costs for substrate-specific fabrication and patterning.

Innovation Solution

A method involving the use of laser-etchable low-melting-point metal nanowires coated on flexible substrates with an ionic liquid and heat application for thermal joining, combined with a patterning process using a short-wavelength laser and an overcoating layer for enhanced durability and transmittance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Adaptability or versatility

If metal nanowires are used as heating element material, then flexibility and transmittance are improved, but resistance increases and heating characteristics deteriorate

Engineering Contradiction:
ImproveflexibilityVSAvoidheating characteristics
Core Design Contradiction:
Adaptability or versatilityVSReliability

Solution Approach 1:

The patent changes the physical and chemical parameters of metal nanowires through surface treatment, alloying, and structural modification to reduce resistance while maintaining flexibility. Specific parameters adjusted include surface roughness, composition ratios, and wire diameter to optimize both flexibility and heating performance.

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent creates composite structures by combining metal nanowires with conductive polymers, metal oxides, or other materials to form hybrid heating elements. This composite approach reduces overall resistance while preserving the flexibility advantages of nanowire structures.

Inventive Principle:
Principle #40Composite materials

2Adaptability or versatility

If metal nanowires are used as heating element material, then flexibility is improved, but oxidation resistance deteriorates

Engineering Contradiction:
ImproveflexibilityVSAvoidoxidation
Core Design Contradiction:
Adaptability or versatilityVSObject-affected harmful factors

Solution Approach 1:

The patent converts the harmful oxidation effect into a beneficial protective mechanism by applying controlled oxidation treatments that form protective oxide layers on the nanowire surfaces. These layers prevent further oxidation while maintaining electrical conductivity and flexibility.

Inventive Principle:
Principle #22Blessing in disguise (Convert harm into benefit)

Solution Approach 2:

The patent employs inert atmosphere processing during fabrication and operation to prevent oxidation. This includes using nitrogen or argon environments during deposition and creating encapsulation structures that maintain inert conditions during device operation.

Inventive Principle:
Principle #39Inert atmosphere (Inert environment)

3Adaptability or versatility

If metal nanowires are used as heating element material, then flexibility is improved, but heat resistance deteriorates

Engineering Contradiction:
ImproveflexibilityVSAvoidheat resistance
Core Design Contradiction:
Adaptability or versatilityVSTemperature

Solution Approach 1:

The patent applies flexible protective thin film coatings on metal nanowires to provide thermal protection while maintaining flexibility. These coatings act as thermal barriers that prevent wire degradation at high temperatures while allowing the structure to remain flexible and bendable.

Inventive Principle:
Principle #30Flexible shells and thin films

Solution Approach 2:

The patent creates composite structures with high-temperature resistant materials combined with flexible nanowires. This includes coating nanowires with heat-resistant ceramics or polymers that maintain structural integrity at elevated temperatures while preserving the flexible nature of the heating element.

Inventive Principle:
Principle #40Composite materials

4Manufacturing precision

If photolithography process is used for patterning, then manufacturing precision is improved, but device complexity and cost increase

Engineering Contradiction:
Improvepatterning precisionVSAvoidprocess complexity
Core Design Contradiction:
Manufacturing precisionVSDevice complexity

Solution Approach 1:

The patent replaces the complex photolithography mechanical system with simpler direct writing methods such as laser writing, inkjet printing, or robotic manipulation. These methods achieve comparable patterning precision without requiring cleanroom facilities, photomasks, and multiple development steps.

Inventive Principle:
Principle #28Mechanics substitution (Replace mechanical system)

Solution Approach 2:

The patent employs self-aligned patterning methods where the heating element pattern automatically aligns with substrate features or where subsequent layers self-align to previous layers without requiring additional alignment steps. This reduces process complexity while maintaining manufacturing precision.

Inventive Principle:
Principle #25Self-service

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach reduces the resistance of metal nanowire heaters, improves heating characteristics at lower voltages, enhances durability and flexibility, and allows for cost-effective, substrate-independent fabrication with high transmittance and heat resistance, enabling flexible and complex pattern designs.

Implementation Method 1

a thermal joining step of enhancing connection between contact parts of the metal nanowires due to a chemical and physical action occurring when an ionic liquid is phase-changed, by supplying the ionic liquid onto the coating film and applying heat from outside

Methodology Applied
Scientific EffectPhase change: Phase Change

Implementation Method 2

a thermal joining step of enhancing connection between contact parts of the metal nanowires due to a chemical and physical action occurring when an ionic liquid is phase-changed

Methodology Applied
Scientific EffectThermal joining: Sintering

Implementation Method 3

Transparent heaters have transparency and have heating characteristics based on joule heating

Methodology Applied
Scientific EffectJoule heating: Joule Heating

Implementation Method 4

a patterning process using a short-wavelength laser

Methodology Applied
Scientific EffectLaser ablation: Laser Ablation

Data Source

PatentUS11026297B2Metal nanowire heater and method of fabricating the same
Publication Date: 2021.06.01 KOREA INST OF SCI & TECH
  • US11026297B2 patent drawing
  • US11026297B2 patent drawing
  • US11026297B2 patent drawing

AI summary

Provided is a metal nanowire heater and a method of fabricating the metal nanowire heater that includes providing a substrate; coating on the substrate a nanowire film containing metal nanowires that are laser-etchable; thermally joining portions of the metal nanowires to enhance connection between contact parts of the metal nanowires and provide an enhanced nanowire film by at least one unit cycle of supplying the ionic liquid onto the nanowire film and applying heat from outside to cause the ionic liquid to change its phase; and forming electrodes on the enhanced nanowire film to provide the metal nanowire heater.