Integrated Naphtha Catalytic and Steam Cracking Process

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Solution Overview

Problem

Current methods for producing ethylene, propylene, butenes, and aromatic compounds like benzene, toluene, and xylene from naphtha are inefficient and complex, relying on traditional thermal cracking processes that are energy-intensive and limited by the availability of distillate feedstocks.

Innovation Solution

An integrated process combining catalytic cracking and steam cracking of full-range naphtha, where the naphtha is separated into intermediate streams, with catalytic cracking producing C2 to C12 hydrocarbons and steam cracking converting paraffins to olefins, allowing for efficient production of light olefins and aromatics using a single catalytic cracker and steam cracker, generating heat for the process.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Productivity

If traditional thermal cracking processes are used to produce ethylene, propylene, butenes and aromatic compounds from naphtha, then production of basic intermediate compounds can be achieved, but the process is energy-intensive and complex

Engineering Contradiction:
Improveproduction efficiency of petrochemical productsVSAvoidenergy consumption
Core Design Contradiction:
ProductivityVSUse of energy by moving object

Solution Approach 1:

The patent combines catalytic cracking and steam cracking processes into an integrated system where the effluent from catalytic cracking is fed to steam cracking. This merging allows simultaneous production of aromatics (from catalytic cracking) and light olefins (from steam cracking) from a single naphtha feedstock, improving overall productivity while optimizing energy utilization through heat integration between the two processes

Inventive Principle:
Principle #5Merging (Combining)

2Productivity

If traditional thermal cracking processes are used to produce ethylene, propylene, butenes and aromatic compounds from naphtha, then production of basic intermediate compounds can be achieved, but the processing steps become complicated

Engineering Contradiction:
Improveproduction efficiency of petrochemical productsVSAvoidprocessing complexity
Core Design Contradiction:
ProductivityVSDevice complexity

Solution Approach 1:

The patent merges catalytic cracking and steam cracking into an integrated process where the catalytic cracker produces aromatic compounds and the steam cracker processes the effluent to produce light olefins. This combination simplifies the overall processing by using a unified two-stage approach instead of separate conventional processes, reducing equipment complexity while maintaining high productivity

Inventive Principle:
Principle #5Merging (Combining)

3Productivity

If refinery fluidized catalytic cracking (FCC) processes are used to produce propylene from heavy feedstocks, then propylene production can be achieved, but the feedstocks are limited and require costly and energy intensive processing steps

Engineering Contradiction:
Improvepropylene productionVSAvoidfeedstock availability
Core Design Contradiction:
ProductivityVSAdaptability or versatility

Solution Approach 1:

The patent changes the feedstock parameter from heavy feedstocks (gas oils, residues) to naphtha, which is a lighter, more versatile and widely available feedstock. By adjusting the feedstock type and using an integrated catalytic-steam cracking process, the system achieves propylene production while expanding feedstock options and reducing processing costs

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This integrated approach enables the efficient production of high-value petrochemical products like ethylene, propylene, and BTX, reducing energy consumption and simplifying the processing steps while maximizing the use of naphtha feedstock.

Implementation Method 1

contacting the first intermediate stream with a catalyst under catalytic cracking conditions sufficient to cause cracking of hydrocarbons in the first intermediate stream

Methodology Applied
Scientific EffectCatalytic cracking: Catalysis

Implementation Method 2

subjecting at least a portion of the light intermediate stream to steam cracking conditions sufficient to convert hydrocarbons (e.g., paraffins) in the light intermediate stream to olefins

Methodology Applied
Scientific EffectThermal cracking: Pyrolysis

Implementation Method 3

The process also generates heat and/or fuel for the catalytic cracking process

Methodology Applied
Scientific EffectCombustion: Combustion

Data Source

PatentUS11851621B2Naphtha catalytic cracking process
Publication Date: 2023.12.26 SABIC GLOBAL TECHNOLOGIES BV
  • US11851621B2 patent drawing
  • US11851621B2 patent drawing

AI summary

Systems and methods for processing full range naphtha feeds to produce a light olefins stream and an aromatics stream are described. In particular, the invention concerns integration of catalytic cracking with steam cracking to maximize production of aromatics.