Natural Fibre Reinforced ABS Composition with Silane Coupling

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Solution Overview

Problem

Natural fibre-reinforced thermoplastics face challenges such as poor compatibility with polymeric matrices, complex injection processes, low mechanical properties, and poor surface finishes, limiting their application in producing articles with excellent surface appearance in a single processing stage.

Innovation Solution

A thermoplastic composition comprising acrylonitrile-butadiene-styrene (ABS) polymer, natural fibres, a compatibilizing polymer, and processing aids like titanium dioxide, which enables a balanced mechanical and thermal profile, suitable for extrusion, injection, and 3D printing, with improved fibre distribution and surface appearance.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If natural fibres are used as reinforcement fillers, then cost decreases and eco-friendliness improves, but compatibility with polymeric matrix deteriorates

Engineering Contradiction:
Improveeco-friendlinessVSAvoidcompatibility with polymeric matrix
Core Design Contradiction:
ReliabilityVSStability of the object's composition

Solution Approach 1:

The patent employs silane coupling agents as intermediary substances that chemically bond to both the natural fibre surfaces and the polymeric matrix. The silane treatment creates a bridging layer that improves interfacial adhesion between the hydrophilic natural fibres and the hydrophobic polymer matrix, resolving the compatibility issue while maintaining the eco-friendly benefits of natural fibre reinforcement.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Object-generated harmful factors

If natural fibre reinforced plastics are used, then CO2 production decreases and weight reduces, but surface finish deteriorates

Engineering Contradiction:
ImproveCO2 productionVSAvoidsurface finish
Core Design Contradiction:
Object-generated harmful factorsVSManufacturing precision

Solution Approach 1:

The silane coupling agent acts as an intermediary that not only improves mechanical compatibility but also enhances surface properties. By creating a controlled interfacial layer, the silane treatment prevents fibre agglomeration and improves fibre-matrix bonding, resulting in smoother surfaces and better finish quality while maintaining the low CO2 footprint advantage.

Inventive Principle:
Principle #24Intermediary (Mediator)

3Stability of the object's composition

If fibre surface treatment is implemented, then compatibility with polymeric matrix improves, but processing complexity increases

Engineering Contradiction:
Improvecompatibility with polymeric matrixVSAvoidprocessing complexity
Core Design Contradiction:
Stability of the object's compositionVSDevice complexity

Solution Approach 1:

The silane surface treatment is applied to natural fibres in advance, before the fibres are incorporated into the polymeric matrix. This preliminary modification of fibre surfaces ensures that the compatibility improvement is already in place before composite fabrication, simplifying the overall processing by eliminating the need for complex in-situ treatment procedures during composite manufacturing.

Inventive Principle:
Principle #10Preliminary action

4Weight of moving object

If natural fibres are used for injection moulding, then light weight design is achieved, but mechanical properties deteriorate

Engineering Contradiction:
ImproveweightVSAvoidmechanical properties
Core Design Contradiction:
Weight of moving objectVSStrength

Solution Approach 1:

The silane coupling agent serves as a critical intermediary that strengthens the interface between natural fibres and the polymeric matrix. By improving interfacial adhesion, the silane treatment enables effective stress transfer from the matrix to the fibres, significantly enhancing mechanical properties such as tensile strength and flexural modulus while maintaining the lightweight advantage of natural fibre reinforcement.

Inventive Principle:
Principle #24Intermediary (Mediator)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition achieves uniform fibre distribution and enhanced surface appearance, overcoming previous limitations, making it suitable for a wide range of applications, including injection moulding and 3D printing, with improved mechanical and thermal properties.

Implementation Method 1

the fibres are silane treated

Methodology Applied
Scientific EffectSilane treatment: Chemical Bonding

Implementation Method 2

a compatibilizing polymer, wherein the compatibilizing polymer is a copolymer of styrene and maleic anhydride

Methodology Applied
Scientific EffectCompatibilization: Surfactant

Implementation Method 3

processing aids like titanium dioxide, which enables a balanced mechanical and thermal profile

Methodology Applied
Scientific EffectLight scattering: Scattering

Data Source

PatentEP3170862B1Thermoplastic ABS composition reinforced with natural fibres
Publication Date: 2022.02.23 ELIX POLYMERS SL
  • EP3170862B1 patent drawingFigure 1A~1B

AI summary

The present invention relates to a thermoplastic ABS composition reinforced with natural fibres, which comprises an ABS polymer, natural fibres, a compatibilizing polymer, and processing aids comprising a lubricant and titanium dioxide. It relates also to a moulded article prepared from the thermoplastic composition and to its use in extrusion, injection, compression moulding and 3D printing.