Natural Rubber Stabilization Before Drying for Low-Allergen Aging Resistance

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Solution Overview

Problem

Natural rubber from Hevea trees contains proteins and cellular constituents that provide aging resistance but can trigger allergies, while synthetic rubber lacks these but requires added aging stabilizers, and existing methods for producing aging-resistant natural rubber from alternative sources like dandelion and guayule are not effective.

Innovation Solution

A process where an aging stabilizer is contacted with the plant sap or its ingredients, particularly natural polyisoprenes, before drying, to produce aging-resistant natural rubber, ensuring the stabilizer is incorporated before the rubber is completely dried, thereby enhancing its stability and reducing allergenic components.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Reliability

If natural rubber is obtained from Hevea trees containing proteins and cellular constituents, then aging resistance is improved, but allergenic potential increases

Engineering Contradiction:
Improveaging resistanceVSAvoidallergenic potential
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent extracts and removes proteins and cellular constituents from natural rubber through purification processes, separating the beneficial aging-resistant polyisoprene from the harmful allergenic components. This extraction approach maintains aging resistance while eliminating allergic triggers.

Inventive Principle:
Principle #2Taking out (Extraction)

Solution Approach 2:

The patent changes the compositional parameters of natural rubber by controlling the content of proteins and cellular constituents through purification processes. By adjusting these compositional parameters, the rubber maintains adequate aging resistance while reducing allergenic potential to acceptable levels.

Inventive Principle:
Principle #35Parameter changes

2Object-affected harmful factors

If synthetic rubber is used free of proteins and cellular constituents, then allergenic potential is reduced, but aging resistance deteriorates

Engineering Contradiction:
Improveallergenic potentialVSAvoidaging resistance
Core Design Contradiction:
Object-affected harmful factorsVSReliability

Solution Approach 1:

The patent creates a composite material system by combining purified natural polyisoprene with specifically selected aging stabilizers. This composite approach provides aging resistance through the stabilizer system while maintaining the low-allergen benefit of purified natural rubber, avoiding the need for proteins and cellular constituents.

Inventive Principle:
Principle #40Composite materials

3Ease of manufacture

If aging stabilizer is added to natural rubber after drying, then processing simplicity is maintained, but stabilizer distribution and aging resistance deteriorate

Engineering Contradiction:
Improveprocessing simplicityVSAvoidaging resistance
Core Design Contradiction:
Ease of manufactureVSReliability

Solution Approach 1:

The patent applies aging stabilizers to natural rubber at an early stage during the purification process, before drying and final processing. This preliminary application ensures thorough and uniform distribution of the stabilizer throughout the rubber matrix, maximizing aging resistance while the subsequent processing steps maintain operational simplicity.

Inventive Principle:
Principle #10Preliminary action

4Stability of the object's composition

If natural rubber is completely dried before stabilizer addition, then storage stability is improved, but stabilizer incorporation and aging resistance deteriorate

Engineering Contradiction:
Improvestorage stabilityVSAvoidaging resistance
Core Design Contradiction:
Stability of the object's compositionVSReliability

Solution Approach 1:

The patent performs the stabilizer incorporation action before the drying step, when the rubber is still in a moist or semi-dried state. This timing allows the stabilizer to be effectively incorporated into the rubber matrix through mixing and distribution mechanisms that are more effective before complete drying, ensuring adequate aging resistance while maintaining storage stability.

Inventive Principle:
Principle #10Preliminary action

Solution Approach 2:

The patent controls the moisture content parameter at the time of stabilizer addition, optimizing the physical state of the rubber for maximum stabilizer incorporation efficiency. By adjusting this parameter, the process achieves both effective stabilizer distribution and subsequent storage stability.

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The process results in natural rubber with improved aging resistance and reduced allergenic potential, suitable for producing high-load-bearing elastic products like vehicle tires, with the stabilizer effectively distributed throughout the rubber before drying, enhancing its durability and longevity.

Implementation Method 1

an aging stabilizer is contacted with the plant sap obtained or its ingredients (which have been optionally removed beforehand and optionally already purified), in particular with the natural polyisoprenes, before the natural rubber has been (completely) dried

Methodology Applied
Scientific EffectAbsorption: Absorption (physical)

Implementation Method 2

this polymer-containing sap or at least its ingredients, in particular the natural polyisoprenes, is obtained from the plant material (also referred to here as extraction)

Methodology Applied
Scientific EffectExtraction:

Implementation Method 3

before the natural rubber has been (completely) dried

Methodology Applied
Scientific EffectEvaporation: Evaporation

Data Source

PatentUS20230391894A1Process for obtaining natural rubber, rubber composition containing natural rubber and use thereof
Publication Date: 2023.12.07 CONTINENTAL REIFEN DEUTSCHLAND GMBH
  • US20230391894A1 patent drawing
  • US20230391894A1 patent drawing

AI summary

The present invention relates to a process for obtaining aging-resistant natural rubber, to a rubber composition comprising the thus-obtained natural rubber and to the use of this composition for producing consumer goods.