Non-Destructive Epitaxial Lift-Off for Substrate Reuse

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Solution Overview

Problem

The high cost and difficulty of fabrication limit the widespread commercial application of compound semiconductors and inorganic light-emitting diodes (LEDs) for display technology, particularly due to high substrate costs and production challenges.

Innovation Solution

A method for making thin-film electronic devices involves using a growth substrate with an epitaxial protective layer, transferring the device layer to a secondary substrate through non-destructive epitaxial lift-off (ND-ELO), and reusing the growth substrate, allowing for the preservation of its thickness and maintaining performance without the need for damaging polishing processes.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Loss of substance

If traditional substrate reuse methods are used, then substrate cost is reduced, but substrate thickness and performance are degraded due to damaging polishing processes

Engineering Contradiction:
Improvesubstrate costVSAvoidsubstrate thickness
Core Design Contradiction:
Loss of substanceVSManufacturing precision

Solution Approach 1:

The patent segments the substrate system into three distinct components: the reusable growth substrate, the sacrificial protective layer, and the device layer. This segmentation allows the substrate to be separated from the device while the protective layer sacrificially absorbs the damage from removal processes, preserving the substrate's integrity and thickness for repeated reuse.

Inventive Principle:
Principle #1Segmentation

Solution Approach 2:

The protective layer acts as an intermediary between the growth substrate and the device layer. It provides a sacrificial interface that can be selectively removed to release the device layer while leaving the substrate intact, thereby mediating the separation process without damaging the substrate's critical thickness and surface properties.

Inventive Principle:
Principle #24Intermediary (Mediator)

2Reliability

If high-performance compound semiconductors are used, then device performance is improved, but production cost and fabrication difficulty increase

Engineering Contradiction:
Improvedevice performanceVSAvoidproduction cost
Core Design Contradiction:
ReliabilityVSEase of manufacture

Solution Approach 1:

The growth substrate serves itself by being reused across multiple device fabrication cycles. The sacrificial protective layer enables this self-service by being selectively removed to release device layers while regenerating the substrate surface for subsequent growth cycles, eliminating the need for expensive substrate replacement and reducing overall production costs.

Inventive Principle:
Principle #25Self-service

Solution Approach 2:

The protective layer is deliberately discarded through selective removal to enable device layer release, while the expensive growth substrate is recovered and reused. This selective discarding and recovery strategy transfers the sacrificial role to the less costly protective layer, preserving the high-value substrate for continuous reuse.

Inventive Principle:
Principle #34Discarding and recovering

3Illumination intensity

If inorganic LEDs are used for display technology, then brightness, efficiency, and longevity are improved, but production cost and fabrication difficulty remain high

Engineering Contradiction:
ImprovebrightnessVSAvoidproduction cost
Core Design Contradiction:
Illumination intensityVSEase of manufacture

Solution Approach 1:

The growth substrate achieves multi-functionality by serving as a universal platform for fabricating multiple different device layers across numerous production cycles. The standardized substrate with its sacrificial protective layer interface can repeatedly accommodate different inorganic LED device designs, enabling high-performance displays while reducing per-unit production costs through substrate reuse.

Inventive Principle:
Principle #6Universality (Multi-functionality)

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the cost-effective production of high-performance inorganic thin-film electronic devices, such as LEDs and transistors, for flexible and lightweight display panels, with no observable degradation in device performance across multiple reuse cycles, and allows for the fabrication of multi-color LED arrays and other optoelectronic devices.

Implementation Method 1

providing a growth substrate having a thickness and a surface suitable for epitaxial growth

Methodology Applied
Scientific EffectEpitaxy: Epitaxy

Implementation Method 2

removing at least a portion of the epitaxial protective layer from the growth substrate to form a new surface suitable for epitaxial growth

Methodology Applied
Scientific EffectSelective etching:

Implementation Method 3

cold-weld bonding the growth substrate to the secondary substrate before releasing the device layer from the growth substrate

Methodology Applied
Scientific EffectCold-weld bonding:

Data Source

PatentUS10964732B2Fabrication of thin-film electronic devices with non-destructive wafer reuse
Publication Date: 2021.03.30 THE RGT UNIV OF MICHIGAN
  • US10964732B2 patent drawing
  • US10964732B2 patent drawing
  • US10964732B2 patent drawing

AI summary

Thin-film electronic devices such as LED devices and field effect transistor devices are fabricated using a non-destructive epitaxial lift-off technique that allows indefinite reuse of a growth substrate. The method includes providing an epitaxial protective layer on the growth substrate and a sacrificial release layer between the protective layer and an active device layer. After the device layer is released from the growth substrate, the protective layer is selectively etched to provide a newly exposed surface suitable for epitaxial growth of another device layer. The entire thickness of the growth substrate is preserved, enabling continued reuse. Inorganic thin-film device layers can be transferred to a flexible secondary substrate, enabling formation of curved inorganic optoelectronic devices.