Nd-Fe-B Magnet Coercivity via Heavy Rare Earth Diffusion
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Solution Overview
Problem
Existing methods for increasing the coercivity of sintered Nd—Fe—B permanent magnets, such as introducing heavy rare earth elements, face challenges like high costs, low production efficiency, waste of materials, and inconsistent magnetic properties due to the use of vapor deposition, electrophoretic deposition, and coating processes, which also lead to a decrease in remanence and introduction of impurities.
Innovation Solution
A method involving an organic film with a thickness of 5 μm to 50 μm, where a powder containing heavy rare earth elements is uniformly deposited on its surfaces and applied to a sintered Nd—Fe—B magnet block, allowing close contact and diffusion under a vacuum or inert gas environment, followed by aging, to enhance coercivity while minimizing rare earth usage and preventing impurities.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Strength
If heavy rare earth elements are introduced into the main phase crystal grains, then coercivity is improved, but remanence decreases
Solution Approach 1:
The patent applies local quality by concentrating heavy rare earth elements specifically at the grain boundary phase rather than distributing them throughout the main phase crystal grains. This localized approach allows the heavy rare earth elements to harden the Nd2Fe14B main phase at the grain boundaries where they are most effective, while preventing their harmful effects on the remanence of the bulk material. The grain boundary phase acts as a localized region where the harmful effects are confined.
2Strength
If vapor deposition process is used to introduce heavy rare earth elements, then coercivity is improved, but production efficiency decreases and cost increases
Solution Approach 1:
The patent replaces the complex vapor deposition mechanical system with a simpler direct diffusion method. Instead of using expensive vapor deposition equipment that requires precise control of deposition parameters, the invention uses a straightforward thermal diffusion process where heavy rare earth elements are introduced through the grain boundary phase during aging treatment. This substitution dramatically simplifies the manufacturing system while maintaining effective coercivity improvement.
3Productivity
If electrophoretic deposition process is used, then production efficiency is improved, but heavy rare earth materials are wasted and remanence decreases
Solution Approach 1:
The patent extracts the heavy rare earth element introduction process from the bulk material treatment and confines it to the grain boundary phase. By taking out the diffusion process and limiting it to the grain boundary region through controlled aging treatment, the method prevents unnecessary deposition on all surfaces that would occur with electrophoretic deposition. This extraction approach eliminates material waste while preserving production efficiency.
4Strength
If coating process with organic solvent is used, then coercivity is improved, but magnetic properties become inconsistent due to solvent volatility
Solution Approach 1:
The patent replaces the problematic organic solvent-based coating system with a disposable solid lubricant film approach. Instead of using volatile organic solvents that cause inconsistent deposition ratios over time, the invention uses solid lubricants that are applied as thin films and then removed after serving their purpose during diffusion. This disposable approach eliminates the precision problems associated with solvent volatility while maintaining effective heavy rare earth element introduction.
5Productivity
If heat resistant mesh is used as diffusion source carrier, then production efficiency is improved, but close contact is difficult to maintain and impurities are introduced
Solution Approach 1:
The patent replaces the heat resistant mesh carrier with a direct solid lubricant film copying method. Instead of using a mesh structure that creates gaps and prevents close contact, the invention copies the heavy rare earth elements directly onto the magnet surface through the lubricant film. This copying approach ensures intimate contact between the diffusion source and the magnet surface, eliminating the uniformity problems caused by mesh structures while maintaining high production efficiency.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
This method effectively increases coercivity without significantly reducing remanence and minimizes the introduction of impurities, improving the utilization of heavy rare earth elements and maintaining consistent magnetic properties.
Implementation Method 1
the heavy rare earth elements such as Dy or Tb, diffused through a grain boundary phase, hardens the Nd2Fe14B main phase forming a large core-shell structure thereby significantly improves the coercivity
Implementation Method 2
depositing the diffusion source on at least one of the block surface of the sintered Nd—Fe—B magnet block with the powder being in abutment relationship with the at least one of the block surfaces
Data Source
AI summary
A method of increasing coercivity of an Nd—Fe—B sintered permanent magnet includes a step of providing an organic film. A powder, containing at least one heavy rare earth elements, is uniformly deposited on the organic film forming a diffusion source. Then, a sintered Nd—Fe—B magnet block having a pair of block surfaces extending perpendicular to a magnetization direction is provided. Next, the diffusion source is deposited on at least one of the block surfaces with the powder being in abutment relationship with at least one of the block surfaces. After depositing the diffusion source, the sintered Nd—Fe—B magnet block containing the diffusion source is pressed allowing the powder of the diffusion source to be in close contact with the block surface. The diffusion source is then diffused into the sintered Nd—Fe—B magnet block to produce a diffused magnet block. Next, the diffused magnet block is aged.

