Nd-Fe-B Powder Coating for Higher-Coercivity Sintered Magnets
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Solution Overview
Problem
Existing methods for manufacturing Nd-Fe-B permanent magnets face challenges in improving coercivity while reducing the total amount of rare earth and heavy rare earth content, leading to increased production costs and decreased magnetic properties.
Innovation Solution
A manufacturing method involving mechanical mixing of Nd-Fe-B powder with nanoparticulate powder under inert conditions to form a coating layer, followed by sintering and heat treatment, which enhances grain boundary phase distribution and improves coercivity.
Engineering Contradictions & Design Principles
Engineering Contradiction Analysis
1Force
If heavy rare earth elements like Dy or Tb are added into the magnet alloy to enhance coercive force, then coercivity is improved, but magnetic remanence decreases and production costs increase
Solution Approach 1:
The patent applies local quality by concentrating heavy rare earth elements specifically at the grain boundaries through diffusion processes, rather than uniformly distributing them throughout the alloy. This localized approach enhances coercivity at the grain boundaries where it is most needed, while minimizing the overall amount of heavy rare earth elements required, thereby preserving magnetic remanence and reducing costs.
Solution Approach 2:
The patent employs composite materials by creating a multi-phase structure where heavy rare earth elements form a distinct grain boundary phase separate from the main Nd2Fe14B matrix. This composite structure allows the heavy rare earth elements to function specifically at the grain boundaries for coercivity enhancement, while the bulk material maintains its high magnetic remanence properties.
2Force
If heavy rare earth elements like Dy or Tb are added into the magnet alloy to enhance coercive force, then coercivity is improved, but production costs increase
Solution Approach 1:
The patent applies local quality by concentrating heavy rare earth elements specifically at the grain boundaries through diffusion processes, rather than uniformly distributing them throughout the alloy. This localized approach enhances coercivity at the grain boundaries where it is most needed, while minimizing the overall amount of heavy rare earth elements required, thereby preserving magnetic remanence and reducing costs.
Solution Approach 2:
The patent applies partial action by using a low melting point alloy powder as a diffusion source that partially releases heavy rare earth elements during the heat treatment process. This controlled partial diffusion allows sufficient coercivity enhancement without requiring excessive amounts of heavy rare earth elements, thus reducing material costs while achieving the desired magnetic properties.
3Force
If a grain boundary diffusion process with heavy rare earth metals is used to improve coercive force, then coercivity is improved, but the process complexity increases
Solution Approach 1:
The patent introduces a low melting point alloy powder as an intermediary diffusion source that contains the heavy rare earth elements. This intermediary material simplifies the process by providing a controlled, gradual release of heavy rare earth elements during heat treatment, avoiding the need for direct coating and complex multi-stage grinding processes while achieving effective grain boundary diffusion.
Solution Approach 2:
The patent utilizes parameter changes by controlling the melting and diffusion behavior of the low melting point alloy powder during heat treatment. By adjusting the heat treatment temperature and time parameters, the heavy rare earth elements are controlled to diffuse appropriately into the grain boundaries, achieving the desired coercivity improvement through controlled parameter manipulation rather than complex process steps.
4Force
If nanosized particulates are added to the alloy powder to improve magnetic properties, then coercivity is improved, but the manufacturing process complexity increases
Solution Approach 1:
The patent merges the addition of nanosized particulates with the low melting point alloy powder approach, combining multiple functionality into a single additive material. This integrated approach simultaneously provides grain boundary diffusion, particle rounding, and microstructure optimization, achieving improved coercivity without requiring separate manufacturing steps for each function, thus reducing overall process complexity.
Applied Scientific Principles
This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.
Function Achieved in This Case
The method results in higher coercive force and magnetic properties of the Nd-Fe-B magnets by evenly distributing nanoparticulate powder on the surface of Nd-Fe-B powder, forming a coating layer that strengthens grain boundaries and improves magnetic coupling.
Implementation Method 1
modification of the powder mixture obtained in step B) by applying mechanical energy under inert conditions in a mechanofusion device such that the particles of the Nd-Fe-B powder are rounded and the nanoparticulate powder adheres to the particle surface of the Nd-Fe-B powder
Implementation Method 2
align pressing the modified Nd-Fe-B powder into a green body, sintering the green body
Implementation Method 3
sintering the green body, and aging of the obtained sintered Nd-Fe-B magnet
Data Source
Figure 1~2
AI summary
The present invention refers to a preparation method for improving the coercive force of a sintered Nd-Fe-B magnet and comprises in the order the steps of: A) preparing Nd-Fe-B alloy flakes by a strip casting process, followed by hydrogen decrepitation of the Nd-Fe-B alloy flakes and jet milling to obtain an Nd-Fe-B powder; B) mixing Nd-Fe-B powder and an amount of 0.1 to 5wt. % of a nanoparticulate powder in a powder mixing machine to obtain a powder mixture; C) modification of the powder mixture obtained in step B) by applying mechanical energy under inert conditions in a mechanical mixing equipment such that the particles of the Nd-Fe-B powder are rounded and the nanoparticulate powder adheres to the particle surface of the Nd-Fe-B powder; D) mixing in a lubricant to the modified Nd-Fe-B powder in a powder mixing machine; and E) align pressing the modified Nd-Fe-B powder into a green body, sintering the green body, and aging of the obtained sintered Nd-Fe-B magnet.