Near-Infrared Absorbing Copper Complex Composition for Optical Distortion Reduction

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Solution Overview

Problem

Conventional near-infrared filters used in electronic devices, such as camera modules, suffer from optical distortion issues like flare phenomena due to inadequate absorption of near-infrared light, leading to image quality degradation.

Innovation Solution

A near-infrared absorbing composition comprising a copper complex with specific ligands and photo-polymerizable functional groups is developed, which forms a near-infrared absorption layer with improved absorbance in the 830-900 nm range and low visible light absorbance, minimizing optical distortion and haze.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Volume of moving object

If a thin-film optical filter is used to down-size the electronic device, then the device size is reduced and integration is improved, but flare phenomenon occurs causing optical distortion

Engineering Contradiction:
Improvedevice sizeVSAvoidoptical quality
Core Design Contradiction:
Volume of moving objectVSReliability

Solution Approach 1:

The patent changes the chemical composition parameters of the optical filter by using a copper complex with specific ligands (phosphoric acid 2-hydroxy metacryl ester and ethyl sulfonic acid) to achieve improved near-infrared absorbance while maintaining thin-film form factor, thus resolving the contradiction between miniaturization and optical quality

Inventive Principle:
Principle #35Parameter changes

Solution Approach 2:

The patent employs a composite material system consisting of copper complex coordinated with multiple ligands including phosphoric acid 2-hydroxy metacryl ester and ethyl sulfonic acid, creating a material with enhanced near-infrared absorption properties that prevents flare phenomenon while maintaining thin-film structure for device miniaturization

Inventive Principle:
Principle #40Composite materials

2Reliability

If near-infrared absorption is increased to reduce optical distortion, then optical quality is improved, but visible light absorbance and haze increase

Engineering Contradiction:
Improveoptical qualityVSAvoidvisible light absorbance and haze
Core Design Contradiction:
ReliabilityVSObject-affected harmful factors

Solution Approach 1:

The patent applies local quality by designing the copper complex to have selective absorption characteristics - the molecular structure is optimized to absorb specifically in the near-infrared region (830-900 nm) while maintaining high transparency in the visible light region, thus improving optical quality without increasing visible light absorbance or haze

Inventive Principle:
Principle #3Local quality

Solution Approach 2:

The patent changes the absorption spectrum parameters of the optical filter material by using copper complex with specific ligands, shifting the absorption peak to the near-infrared region and reducing absorption in the visible region, thereby achieving improved optical quality without harmful increase in visible light absorbance and haze

Inventive Principle:
Principle #35Parameter changes

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

The composition effectively reduces optical distortion by selectively absorbing near-infrared light, enhancing image clarity and maintaining low haze in the visible light wavelength region, thereby improving the reliability and performance of camera modules.

Implementation Method 1

a maximum absorption wavelength of about 830 nm to about 900 nm

Methodology Applied
Scientific EffectNear-infrared absorption: Absorption (EM radiation)

Implementation Method 2

the photo-polymerizable functional group may include a functional group represented by Chemical Formula 11

Methodology Applied
Scientific EffectPhotopolymerization: Photopolymerisation

Data Source

PatentUS10927131B2Near-infrared absorbing composition, optical structure, and camera module and electronic device comprising the same
Publication Date: 2021.02.23 SAMSUNG ELECTRONICS CO LTD
  • US10927131B2 patent drawing
  • US10927131B2 patent drawing
  • US10927131B2 patent drawing

AI summary

Disclosed are a near-infrared absorbing composition including a copper complex represented by Chemical Formula 1, a near-infrared absorption layer formed by using the near-infrared absorbing composition including the copper complex represented by Chemical Formula 1, an optical structure including the near-infrared absorption layer, and a camera module or an electronic device including the optical structure, wherein Chemical Formula 1 is provided below, andand in Chemical Formula 1, R1, R2, x, and y are the same as described in the detailed description.