Negative Capacitance FET Sensors for Chemical Detection

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Solution Overview

Problem

Transistor-based chemical and biological sensors have limited sensitivity due to their sub-threshold slope, which restricts their ability to detect smaller concentrations of analytes effectively.

Innovation Solution

The integration of a negative capacitance structure using ferroelectric materials in transistor-based sensors, which lowers the subthreshold slope, allowing for larger changes in current output in response to smaller changes in voltage, thereby enhancing sensitivity.

Engineering Contradictions & Design Principles

VSEngineering Contradiction Analysis

1Measurement precision

If conventional transistor structures are used, then device simplicity is maintained, but sensitivity is limited by the sub-threshold slope

Engineering Contradiction:
ImprovesensitivityVSAvoiddevice complexity
Core Design Contradiction:
Measurement precisionVSDevice complexity

Solution Approach 1:

The patent combines a conventional transistor structure with a negative capacitance structure formed by ferroelectric materials. The ferroelectric layer is integrated into the gate stack, merging two functional elements (transistor and capacitor) into a unified device that achieves enhanced sensitivity while maintaining structural simplicity

Inventive Principle:
Principle #5Merging (Combining)

Solution Approach 2:

The invention changes the electrical parameters of the transistor by introducing ferroelectric materials with negative capacitance properties. This modifies the sub-threshold slope parameter, enabling the device to produce larger current changes in response to smaller voltage changes, thereby improving sensitivity without requiring fundamental structural redesign

Inventive Principle:
Principle #35Parameter changes

2Measurement precision

If the sub-threshold slope is reduced to improve sensitivity, then detection of lower analyte concentrations is enabled, but the voltage range for effective operation is compressed

Engineering Contradiction:
Improvedetection limitVSAvoidvoltage operating range
Core Design Contradiction:
Measurement precisionVSAdaptability or versatility

Solution Approach 1:

The ferroelectric material introduces dynamic switching behavior to the transistor gate, enabling the device to operate in distinct states (off, on, and saturation). This dynamic characteristic allows the sensor to achieve high sensitivity at low analyte concentrations while maintaining adaptability across different operating conditions through controlled switching between states

Inventive Principle:
Principle #15Dynamics

Applied Scientific Principles

This section explains which scientific principles are used to turn an abstract innovation direction into a practical engineering solution.

Function Achieved in This Case

This approach enables the detection of analytes at lower concentrations with improved sensitivity, as smaller changes in voltage or analyte concentration result in significant changes in current output, making the sensors more effective.

Implementation Method 1

The integration of a negative capacitance structure using ferroelectric materials in transistor-based sensors, which lowers the subthreshold slope

Methodology Applied
Scientific EffectNegative capacitance:

Implementation Method 2

The integration of a negative capacitance structure using ferroelectric materials in transistor-based sensors

Methodology Applied
Scientific EffectFerroelectric effect:

Implementation Method 3

A functionalized electrode is in electrical contact with the negative capacitance structure and is configured to change surface potential in the presence of an analyte

Methodology Applied
Scientific EffectSurface potential change:

Implementation Method 4

a phase change in the negative capacitance structure is triggered when the surface potential exceeds a threshold

Methodology Applied
Scientific EffectPhase change: Phase Change

Data Source

PatentUS11747296B2Sensors based on negative capacitance field effect transistors
Publication Date: 2023.09.05 INTERNATIONAL BUSINESS MACHINE CORPORATION
  • US11747296B2 patent drawing
  • US11747296B2 patent drawing
  • US11747296B2 patent drawing

AI summary

Chemical sensors and methods of forming and making the same include an input terminal and an output terminal. A negative capacitance structure is configured to control a current passing horizontally from the input terminal to the output terminal, and has a first and second metal layer that are arranged vertically with respect to one another, and a ferroelectric layer positioned between the first and second metal layers. An electrode is in electrical contact with the negative capacitance structure, and is configured to change potential, to exceed a threshold, thereby triggering a discontinuous polarization change in the negative capacitance structure.